电弧离子镀CrTiN涂层的结构及耐腐蚀性能

doi:10.13251/j.issn.0254-6051.2021.08.042

金属热处理 ›› 2021, Vol. 46 ›› Issue (8): 219-224.DOI: 10.13251/j.issn.0254-6051.2021.08.042

电弧离子镀CrTiN涂层的结构及耐腐蚀性能

王其晒¹, 张林¹, 李伯荣², 张宝荣³, 赵志勇³

1.安徽工业大学现代表界面工程研究中心, 安徽马鞍山 243002;
2.广东振华科技股份有限公司, 广东肇庆 526040;
3.山西柴油机工业有限责任公司, 山西大同 037000

收稿日期:2021-04-07 出版日期:2021-08-25 发布日期:2021-12-09
通讯作者: 张林,讲师,博士,E-mail:zhanglin_dut@163.com
作者简介:王其晒(1996—),男,硕士研究生,主要研究方向为金属表面强化,E-mail:qswang23@163.com。
基金资助:
安徽省自然科学基金(2008085QE202);安徽高校自然科学研究项目(KJ2020A0265);安徽省重点研究与开发计划(202004h07020020,202004b11020011)

Structure and corrosion resistance of CrTiN coating deposited by arc ion plating

Wang Qishai¹, Zhang Lin¹, Li Borong², Zhang Baorong³, Zhao Zhiyong³

1. Research Center of Modern Surface and Interface Engineering, Anhui University of Technology, Ma'anshan Anhui 243002, China;
2. Guangdong Zhenhua Technology Co., Ltd., Zhaoqing Guangdong 526040, China;
3. Shanxi Diesel Engine Industry Co., Ltd., Datong Shanxi 037000, China

Received:2021-04-07 Online:2021-08-25 Published:2021-12-09

摘要/Abstract

摘要： 采用电弧离子镀技术在模具钢H13表面沉积Cr_xTi_1-xN涂层,系统研究了不同Cr/Ti原子比对CrTiN合金化涂层结构、力学性能以及耐腐蚀性能的影响。结果表明:通过改变分离靶弧流实现CrTiN涂层中Cr/Ti原子比的有效调控,所制备的CrTiN涂层主要由面心立方结构(Cr, Ti)N和CrN组成,随着Cr/Ti原子比从1.1增加至1.8,涂层相结构由随机取向向(111)晶面优先生长转变。CrTiN合金化涂层显微硬度较CrN涂层得到明显提升,并随着固溶引起的晶格畸变程度变化而具有一个极大值。通过电化学阻抗谱和动电位极化曲线分析,当Cr/Ti原子比为1.4时,致密的Cr_0.59Ti_0.41N涂层具有最佳的耐腐蚀性能。

关键词: 电弧离子镀, Cr/Ti原子比, 力学性能, 耐蚀性

Abstract: Cr_xTi_1-xN coatings were deposited on H13 mould steel substrate by arc ion plating, and the influence of Cr/Ti atomic ratio on structure, mechanical properties and corrosion resistance of the as-deposited CrTiN coating was investigated. The results show that the CrTiN coating with different Cr/Ti atomic ratios is obtained by adjusting arc current. The CrTiN coating is composed of solid solution fcc-(Cr,Ti)N and CrN phases. With the increase of Cr/Ti atomic ratio from 1.1 to 1.8, the structure of the coating changes from a random orientation to (111) preferred growth. Microhardness of the CrTiN coating is improved as compared with CrN coating and has a maximum value with the change of lattice distortion caused by solid solution. According to electrochemical impedance spectroscopy and potentiometric polarization curve analysis, the dense Cr_0.59Ti_0.41N coating shows the best corrosion resistance when the Cr/Ti atomic ratio is 1.4.

Key words: arc ion plating, Cr/Ti atomic ratio, mechanical properties, corrosion resistance

中图分类号:

TB43

王其晒, 张林, 李伯荣, 张宝荣, 赵志勇. 电弧离子镀CrTiN涂层的结构及耐腐蚀性能[J]. 金属热处理, 2021, 46(8): 219-224.

Wang Qishai, Zhang Lin, Li Borong, Zhang Baorong, Zhao Zhiyong. Structure and corrosion resistance of CrTiN coating deposited by arc ion plating[J]. Heat Treatment of Metals, 2021, 46(8): 219-224.

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电弧离子镀CrTiN涂层的结构及耐腐蚀性能

Structure and corrosion resistance of CrTiN coating deposited by arc ion plating

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