Ti6Al4V合金激光熔覆Co-Ti3SiC2复合涂层的组织和摩擦学性能

doi:10.13251/j.issn.0254-6051.2021.12.032

金属热处理 ›› 2021, Vol. 46 ›› Issue (12): 199-203.DOI: 10.13251/j.issn.0254-6051.2021.12.032

Ti6Al4V合金激光熔覆Co-Ti₃SiC₂复合涂层的组织和摩擦学性能

孟祥军¹, 沈颖¹, 张少瑜¹, 许宏良¹, 汪阳², 刘秀波²

1.江苏城乡建设职业学院, 江苏常州 213147;
2.中南林业科技大学材料表界面科学与技术湖南省重点实验室, 湖南长沙 410004

收稿日期:2021-07-28 出版日期:2021-12-25 发布日期:2022-02-18
作者简介:孟祥军(1987—),男,讲师,硕士,主要研究方向为金属材料表面工程,E-mail:mengxj0819@126.com
基金资助:
常州市科技计划(CJ2020026);江苏省教育厅高校自然科学研究面上项目B类(20KJB430040);江苏城乡建设职业学院校级课题(2020KYC001)

Microstructure and tribological properties of laser clad Co-Ti₃SiC₂ composite coating on Ti6Al4V alloy

Meng Xiangjun¹, Shen Ying¹, Zhang Shaoyu¹, Xu Hongliang¹, Wang Yang², Liu Xiubo²

1. Jiangsu Urban & Rural Construction College, Changzhou Jiangsu 213147, China;
2. Hunan Province Key Laboratory of Materials Surface & Interface Science and Technology, Central South University of Forestry & Technology, Changsha Hunan 410004, China

Received:2021-07-28 Online:2021-12-25 Published:2022-02-18

摘要/Abstract

摘要： 为改善Ti6Al4V合金的摩擦学性能,分别用纯Co、Co-2%Ti₃SiC₂、Co-5%Ti₃SiC₂、Co-8%Ti₃SiC₂混合粉末为原料,在Ti6Al4V合金表面激光熔覆制备复合涂层,利用X射线衍射仪(XRD)、扫描电镜(SEM)以及摩擦磨损试验机分析物相组成、显微组织结构以及在常温下的摩擦学性能。结果表明:所有复合涂层与基体结合良好,伴有少部分微孔。纯Co涂层的主要物相为γ-Co、CoTi、CoTi₂等,而Co-Ti₃SiC₂涂层物相包括γ-Co、CoTi、CoTi₂、TiC、Ti₅Si₃和残留的Ti₃SiC₂。涂层的硬度相对基体提高了1.90~2.15倍,而耐磨性能相应提高了3.02~5.44倍。

关键词: 激光熔覆, Co-Ti₃SiC₂涂层, Ti6Al4V合金, 摩擦学性能

Abstract: To improve the tribological properties of Ti6Al4V alloy, the laser clad composite coatings were prepared on the surface of Ti6Al4V alloy using pure Co powder, Co-2%Ti₃SiC₂, Co-5%Ti₃SiC₂, and Co-8%Ti₃SiC₂ mixed powder as raw materials. The phase composition, microstructure and tribological properties of the coatings at room temperature were analyzed by means of X-ray diffraction (XRD), scanning electron microscope (SEM) and friction wear testing machine. The results show that all the composite coatings are bonded well with the substrate, with some porosities observed, and the main phases of the pure Co coating consist of γ-Co, CoTi, and CoTi₂, while the phases of the Co-Ti₃SiC₂ coatings consist of γ-Co, CoTi, CoTi₂, TiC, Ti₅Si₃ and residual Ti₃SiC₂. The hardness of the coatings is increased by 1.90-2.15 times compared with the matrix, and the wear resistance is correspondingly improved by 3.02 to 5.44 times.

Key words: laser cladding, Co-Ti₃SiC₂ coating, Ti6Al4V alloy, tribological properties

中图分类号:

TG174

孟祥军, 沈颖, 张少瑜, 许宏良, 汪阳, 刘秀波. Ti6Al4V合金激光熔覆Co-Ti₃SiC₂复合涂层的组织和摩擦学性能[J]. 金属热处理, 2021, 46(12): 199-203.

Meng Xiangjun, Shen Ying, Zhang Shaoyu, Xu Hongliang, Wang Yang, Liu Xiubo. Microstructure and tribological properties of laser clad Co-Ti₃SiC₂ composite coating on Ti6Al4V alloy[J]. Heat Treatment of Metals, 2021, 46(12): 199-203.

参考文献

[1]Uhlmann E,Kersting R, Klein T B, et al. Additive manufacturing of titanium alloy for aircraft components [J]. Procedia CIRP, 2015, 35: 55-60.
[2]张琪, 罗丽蓉, 刘涛, 等. 船舶海水管系TC4钛合金的表面涂层与耐蚀性能[J]. 金属热处理, 2019, 33(1): 185-189.
Zhang Qi, Luo Lirong, Liu Tao, et al. Surface coating and corrosion resistance of TC4 titanium alloy in marine tube system for ship[J]. Heat Treatment of Metals, 2019, 33(1): 185-189.
[3]易镓, 彭如恕. TC4钛合金表面激光合金化涂层的组织与耐磨性能[J]. 金属热处理, 2020, 45(2): 225-230.
Yi Jia, Peng Rushu. Microstructure and wear resistance of laser alloying coating on TC4 titanium alloy surface[J]. Heat Treatment of Metals, 2020, 45(2): 225-230.
[4]刘家奇, 宋明磊, 陈传忠, 等. 钛合金表面激光熔覆技术的研究进展[J]. 金属热处理, 2019, 44(5): 87-96.
Liu Jiaqi, Song Minglei, Chen Chuanzhong, et al. Research progress of laser cladding technology on surface of titanium alloy[J]. Heat Treatment of Metals, 2019, 44(5): 87-96.
[5]Li N, Xiong Y, Xiong H, et al. Microstructure, formation mechanism and property characterization of Ti+SiC laser cladded coatings on Ti6Al4V alloy[J]. Materials Characterization, 2018, 148: 43-51.
[6]Weng F, Yu H J, Chen C Z, et al. Microstructures and wear properties of laser cladding Co-based composite coatings on Ti-6Al-4V[J]. Materials and Design, 2015, 80(5): 174-181.
[7]童文辉, 张新元, 刘玉坤, 等. 激光功率对TiC增强Co基合金激光熔覆层组织及性能的影响[J]. 热加工工艺, 2021, 50(16): 96-98.
Tong Wenhui, Zhang Xinyuan, Liu Yukun, et al. Effects of laser power on microstructure and properties of TiC reinforced laser cladding layer of Co-based alloy[J]. Hot Working Technology, 2021, 50(16): 96-98.
[8]于静, 刘延川, 于洪飞. 超音频感应熔覆钴基涂层的组织与摩擦磨损性能[J]. 材料保护, 2021, 54(9): 1-6.
Yu Jing, Liu Yanchuan, Yu Hongfei. Microstructure and wear properties of Co-based alloy coatings fabricated by ultrasonic induction cladding[J]. Materials Protection, 2021, 54(9): 1-6.
[9]Nelson M, Agne M T, Anasori B, et al. Synthesis and characterization of the mechanical properties of Ti₃SiC₂/Mg and Cr₂AlC/Mg alloy composites[J]. Materials Science and Engineering A, 2017, 705: 182-188.
[10]Ghosh N C, Harimkar S P. Microstructure and wear behavior of spark plasma sintered Ti₃SiC₂ and Ti₃SiC₂-TiC composites[J]. Ceramics International, 2013, 39(4): 4597-4607.
[11]El Saeed M A, Deorsola F A, Rashad R M. Influence of SPS parameters on the density and mechanical properties of sintered Ti₃SiC₂ powders[J]. International Journal of Refractory Metals and Hard Materials, 2013, 41: 48-53.
[12]Zhou Y, Sun Z. Electronic structure and bonding properties in layered ternary carbide Ti₃SiC₂[J]. Journal of Physics: Condensed Matter, 2000, 12(28): L457.
[13]Adesina O S, Mthisi A, Popoola A P I. The effect of laser based synthesized Ti-Co coating on microstructure and mechanical properties of Ti6Al4V alloy[J]. Procedia Manufacturing, 2017, 7: 46-52.
[14]Liu H, Hao J, Han Z, et al. Microstructural evolution and bonding characteristic in multi-layer laser cladding of NiCoCr alloy on compacted graphite cast iron[J]. Journal of Materials Processing Technology, 2016, 232: 153-164.
[15]Liu Xiubo, Meng Xiangjun, Liu Haiqing et al. Development and characterization of laser clad high temperature self-lubricating wear resistant composite coatings on Ti-6Al-4V alloy[J]. Materials and Design, 2014, 55: 404-409.

Ti6Al4V合金激光熔覆Co-Ti₃SiC₂复合涂层的组织和摩擦学性能

Microstructure and tribological properties of laser clad Co-Ti₃SiC₂ composite coating on Ti6Al4V alloy

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