Mg对X80管线钢夹杂物和奥氏体晶粒尺寸的影响

doi:10.13251/j.issn.0254-6051.2022.10.012

金属热处理 ›› 2022, Vol. 47 ›› Issue (10): 71-77.DOI: 10.13251/j.issn.0254-6051.2022.10.012

Mg对X80管线钢夹杂物和奥氏体晶粒尺寸的影响

田俊, 苏丽娟, 吴静, 黄圣珑, 王德永

苏州大学沙钢钢铁学院, 江苏苏州 215137

收稿日期:2022-05-22 修回日期:2022-08-17 出版日期:2022-10-25 发布日期:2022-12-15
通讯作者: 苏丽娟,实验师,硕士,E-mail:ljsu@suda.edu.cn
作者简介:田俊(1982—),男,副教授,博士,主要研究方向为钢中夹杂物和钢的组织性能调控等,E-mail:t2006j@163.com。
基金资助:
国家自然科学基金(52074186,51704200);江苏省自然科学基金(BK20150336)

Effect of Mg on inclusion and austenite grain size of X80 pipeline steel

Tian Jun, Su Lijuan, Wu Jing, Huang Shenglong, Wang Deyong

School of Iron and Steel, Soochow University, Suzhou Jiangsu 215137, China

Received:2022-05-22 Revised:2022-08-17 Online:2022-10-25 Published:2022-12-15

摘要/Abstract

摘要： 在实验室条件下,对X80钢进行了镁处理和热处理试验,分析了镁对钢中夹杂物和奥氏体晶粒尺寸的影响。结果表明,镁处理后,钢中钙铝酸盐类夹杂物含量减少,MgO·Al₂O₃夹杂物含量增加。Mg含量进一步增加,钢中会形成MgO夹杂物,导致MgO·Al₂O₃和Al₂O₃夹杂物含量减少。镁处理对钢中硫化物、碳化物和氮化物的类型和含量影响不大。镁处理可使钢中小尺寸夹杂物数量增加,夹杂物尺寸平均值减小。镁处理X80钢热处理后,钢中夹杂物主要为尺寸小于1 μm的MgO·Al₂O₃,具有钉扎晶界的作用,从而使镁处理后试样的奥氏体晶粒尺寸明显减小。

关键词: 镁处理, X80管线钢, 夹杂物, 奥氏体, 晶粒尺寸

Abstract: Magnesium treatment and heat treatment were carried out on X80 steel in a laboratory, and the effect of Mg on inclusion and austenite grain size of the steel was analyzed. The results show that the content of calcium aluminate inclusion decreases and the content of MgO·Al₂O₃ inclusion increases in the steel after magnesium treatment. With the further increase of Mg content in the steel, MgO inclusions are formed, resulting in the decrease of MgO·Al₂O₃ content and Al₂O₃ content. Magnesium treatment has a little effect on the type and content of sulfide, carbide and nitrides in the steel. After magnesium treatment, the quantity percentage of small-sized inclusion is increased and the average size of inclusion is decreased in the steel. The main inclusion is MgO·Al₂O₃ with a size of less than 1 μm in the magnesium treated X80 steel after heat treatment, which has an effect of pinning grain boundaries, and significantly reduces the austenite grain size of the steel.

Key words: magnesium treatment, X80 pipeline steel, inclusion, austenite, grain size

中图分类号:

TF03⁺1

田俊, 苏丽娟, 吴静, 黄圣珑, 王德永. Mg对X80管线钢夹杂物和奥氏体晶粒尺寸的影响[J]. 金属热处理, 2022, 47(10): 71-77.

Tian Jun, Su Lijuan, Wu Jing, Huang Shenglong, Wang Deyong. Effect of Mg on inclusion and austenite grain size of X80 pipeline steel[J]. Heat Treatment of Metals, 2022, 47(10): 71-77.

参考文献

[1]张圣柱, 程玉峰, 冯晓东, 等. X80管线钢性能特征及技术挑战[J]. 油气储运, 2019, 38(5): 481-495.
Zhang Shengzhu, Cheng Yufeng, Feng Xiaodong, et al. Performance characteristics and technical challenges of X80 pipeline steel[J]. Oil and Gas Storage and Transportation, 2019, 38(5): 481-495.
[2]李强, 赵家七, 蔡小锋, 等. 管线钢钙处理工艺优化[J]. 炼钢, 2019, 35(5): 37-42.
Li Qiang, Zhao Jiaqi, Cai Xiaofeng, et al. Optimization of calcium treatment process for pipeline steel[J]. Steelmaking, 2019, 35(5): 37-42.
[3]罗磊, 孙彦辉, 陈永, 等. 钙处理工艺对管线钢非金属夹杂物的影响[J]. 钢铁, 2013, 48(1): 42-45.
Luo Lei, Sun Yanhui, Chen Yong, et al. Effect of calcium treatment on the non-metallic inclusions of pipeline steel[J]. Iron and Steel, 2013, 48(1): 42-45.
[4]Li M, Li S, Ren Y, et al. Modification of inclusions in linepipe steels by Ca-containing ferrosilicon during ladle refining[J]. Ironmaking and Steelmaking, 2020, 47(1): 6-12.
[5]尹娜, 景财良, 李强, 等. X80管线钢精炼过程中夹杂物行为研究[J]. 炼钢, 2013, 29(4): 49-52, 66.
Yin Na, Jing Cailiang, Li Qiang, et al. Study on inclusion behavior in X80 pipeline steel during secondary refining process[J]. Steelmaking, 2013, 29(4): 49-52, 66.
[6]王新华, 李秀刚, 李强, 等. X80管线钢板夹杂物中串条状CaO-Al₂O₃系非金属夹杂物的控制[J]. 金属学报, 2013, 49(5): 553-561.
Wang Xinhua, Li Xiugang, Li Qiang, et al. Control of string shaped non-metallic inclusions of CaO-Al₂O₃ system in X80 pipeline steel plates[J]. Acta Metallurgica Sinica, 2013, 49(5): 553-561.
[7]Ito Y I, Nara S, Kato Y, et al. Shape control of alumina inclusions by double calcium addition treatment[J]. Tetsu to Hagane, 2007, 93(5): 355-361.
[8]杨清, 张立文, 张驰, 等. 低碳Nb-V-Ti微合金钢X70的奥氏体晶粒长大行为[J]. 金属热处理, 2019, 44(4): 1-5.
Yang Qing, Zhang Liwen, Zhang Chi, et al. Austenite grain growth behavior of low carbon Nb-V-Ti microalloyed steel X70[J]. Heat Treatment of Metals, 2019, 44(4): 1-5.
[9]乔桂英, 郭宝峰, 陈小伟, 等. 热循环对高铌管线钢焊接热影响区冲击韧性的影响[J]. 金属热处理, 2009, 34(12): 32-35.
Qiao Guiying, Guo Baofeng, Chen Xiaowei, et al. Influence of thermal cycle on impact toughness of HAZ of high-Nb pipeline steel[J]. Heat Treatment of Metals, 2009, 34(12): 32-35.
[10]陈延清, 杜则裕, 许良红. X80管线钢焊接热影响区组织和性能分析[J]. 焊接学报, 2010, 31(5): 101-104, 118.
Chen Yanqing, Du Zeyu, Xu Lianghong. Microstructure and mechanical properties of heat affected zone for X80 pipeline steel[J]. Transactions of the China Welding Institution, 2010, 31(5): 101-104, 118.
[11]雷玄威, 吴开明, 成林, 等. 改善高强韧管线钢焊接热影响区粗晶区韧性的现状与趋势[J]. 材料热处理学报, 2014, 35(5): 1-8.
Lei Xuanwei, Wu Kaiming, Cheng Lin, et al. Current status and trend on toughness improvement of coarse-grained heat-affected zone of high strength high toughness pipeline steels[J]. Transactions of Materials and Heat Treatment, 2014, 35(5): 1-8.
[12]Moon J, Lee C, Uhm S, et al. Coarsening kinetics of TiN particle in a low alloyed steel in weld HAZ considering critical particle size[J]. Acta Materialia, 2006, 54(4): 1053-1061.
[13]Moon J, Kim S, Lee J, et al. Limiting austenite grain size of TiN-containing steel considering the critical particle size[J]. Scripta Materialia, 2007, 56: 1083-1086.
[14]Fu J, Yu Y G, Wang A R, et al. Inclusion modification with Mg treatment for 35CrNi3MoV steel[J]. Journal of Materials Science and Technology, 1998, 14(1): 53-56.
[15]Yang J, Yamasaki T, Kuwabara M. Behavior of inclusions in deoxidation process of molten steel with in situ produced Mg vapor[J]. ISIJ International, 2007, 47(5): 699-708.
[16]田俊, 王德永, 屈天鹏, 等. Mg处理对X65管线钢中夹杂物的影响[J]. 炼钢, 2018, 34(5): 43-49.
Tian Jun, Wang Deyong, Qu Tianpeng, et al. Effect of magnesium treatment on inclusions in X65 pipeline steel[J]. Steelmaking, 2018, 34(5): 43-49.
[17]田俊, 王德永, 屈天鹏, 等. 钙、镁在含硫钢中硫化物变性过程中的作用[J]. 钢铁, 2017, 52(11): 27-31.
Tian Jun, Wang Deyong, Qu Tianpeng, et al. Role and distinction of Ca and Mg to sulfide modification for sulfur steel[J]. Iron and steel, 2017, 52(11): 27-31.
[18]Tsunekage N, Tsubakino H. Effects of sulfur content and sulfide-forming elements addition on impact properties of ferrite-pearlitic microalloyed steels[J]. ISIJ International, 2001, 41(5): 498-505.
[19]Maalekian M, Radis R, Militzer M, et al. In situ measurement and modelling of austenite grain growth in a Ti/Nb microalloyed steel[J]. Acta Materialia, 2012, 60(3): 1015-1026.
[20]Banerjee K, Perez M, Militzer M. Austenite grain growth kinetics during continuous heating of a microalloyed X-80 linepipe steel[J]. Materials Science Forum, 2012, 715-716: 292-296.
[21]黄源, 卫英慧. 20CrMnTi钢TiC的析出行为与奥氏体晶粒度及钢的淬透性[J]. 材料热处理学报, 1993, 14(1): 20-24.
Huang Yuan, Wei Yinghui. Influence of precipitation behavior of TiC phase on austenite grain size and hardenability in 20CrMnTi steel[J]. Transactions of Materials and Heat Treatment, 1993, 14(1): 20-24.
[22]Tomita Y, Saito N, Tsuzuki T, et al. Improvement in HAZ toughness of steel by TiN-MnS addition[J]. ISIJ International, 1994, 34(10): 829-835.
[23]Lai C T, Lai H H, Su Y, et al. The influence of Mg-based inclusions on the grain boundary mobility of austenite in SS400 steel[J]. Metals, 2019, 9(3): 370-384.
[24]Banerjee K, Militzer M, Perez M, et al. Non-isothermal austenite grain growth kinetics in the HAZ of a microalloyed X-80 linepipe steel[J]. Metallurgical and Materials Transactions A, 2010, 41: 3161-3172.
[25]Vynokur B B. Influence of alloying on the free energy of austenitic grain boundaries in steel[J]. Materials Science, 1996, 32: 306-314.

Mg对X80管线钢夹杂物和奥氏体晶粒尺寸的影响

Effect of Mg on inclusion and austenite grain size of X80 pipeline steel

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	程茹, 田勇, 宋超伟, 王昊杰. 真空低压渗碳对304与316L奥氏体不锈钢组织和性能的影响[J]. 金属热处理, 2022, 47(9): 1-5.
[2]	苏长珠, 吴润, 李钊, 吴腾, 秦金柱. 配分时间对低碳热轧F-Q&P钢组织和性能的影响[J]. 金属热处理, 2022, 47(9): 27-30.
[3]	陈琦, 周扬, 付健辉. 固溶处理对低膨胀GH2909高温合金奥氏体晶粒长大的影响[J]. 金属热处理, 2022, 47(9): 87-91.
[4]	季德静, 杨维宇, 白雅琼. 高强韧工程机械用钢Q690D的淬火工艺优化[J]. 金属热处理, 2022, 47(9): 108-112.
[5]	田伟, 潘伟, 钟庆元. 0Cr16Ni5Mo马氏体不锈钢δ-铁素体含量及奥氏体晶粒度的控制[J]. 金属热处理, 2022, 47(9): 194-201.
[6]	周丽娜, 刘明, 高翔, 王文雪, 童锐. 奥氏体化过程对Cr14Mo4V高温轴承钢微观组织的影响[J]. 金属热处理, 2022, 47(8): 7-15.
[7]	张迪, 包喜荣, 陈林, 王晓东, 赵文倩, 宋冉. Mn-Cr-Mo系贝氏体轨钢连续冷却转变的原位观察[J]. 金属热处理, 2022, 47(8): 34-39.
[8]	张存帅, 刘吉猛, 李皓, 赵定国, 王书桓, 倪国龙. 固溶温度及时间对高氮不锈钢耐蚀性能的影响[J]. 金属热处理, 2022, 47(8): 141-147.
[9]	李慧东, 张覃轶, 刘伟, 孙伟, 伍冬. 深冷处理对440C马氏体不锈钢组织和耐蚀性的影响[J]. 金属热处理, 2022, 47(8): 152-157.
[10]	刘麟, 徐海卫, 李红斌, 韩赟, 田亚强, 郑小平, 陈连生. 两相区连续退火均热温度对Q&P980钢组织性能的影响[J]. 金属热处理, 2022, 47(8): 177-181.
[11]	李向川, 杨吉春, 白国君, 樊志明. 热处理对U76CrRE稀土重轨钢夹杂物和微观组织的影响[J]. 金属热处理, 2022, 47(8): 200-210.
[12]	王思超, 徐海卫, 徐勇, 韩赟, 郑小平, 李红斌, 田亚强, 陈连生. ART退火后冷却方式对0.1C-7.2Mn钢加工硬化行为的影响[J]. 金属热处理, 2022, 47(7): 58-62.
[13]	付锡彬, 孟少博, 刘文胜, 张可, 李昭东, 曹燕光, 章小峰, 雍岐龙. 固溶处理对Fe-30Mn-10Al-1C低密度钢组织及力学性能的影响[J]. 金属热处理, 2022, 47(7): 114-119.
[14]	樊志明, 杨吉春, 张滢, 李向川, 朱君. 保温时间对U75V重轨钢中夹杂物的影响[J]. 金属热处理, 2022, 47(6): 33-38.
[15]	冯树明, 万德成, 胡进朋, 李杰. 配分温度对0.2C-2.96Mn-1.73Si钢组织和力学性能的影响[J]. 金属热处理, 2022, 47(6): 54-58.