镍在低碳钢表面的扩散机理与规律

doi:10.13251/j.issn.0254-6051.2023.05.020

金属热处理 ›› 2023, Vol. 48 ›› Issue (5): 121-128.DOI: 10.13251/j.issn.0254-6051.2023.05.020

镍在低碳钢表面的扩散机理与规律

张士宪¹, 徐鸣悦², 赵晓萍¹, 李运刚³

1.河北工业职业技术大学, 河北石家庄 050091;
2.唐山钢铁集团有限责任公司, 河北唐山 063000;
3.华北理工大学冶金与能源学院, 河北唐山 063009

收稿日期:2022-11-30 修回日期:2023-03-20 出版日期:2023-05-25 发布日期:2023-06-21
通讯作者: 李运刚,教授,博士,E-mail: lyg@ncst.edu.cn
作者简介:张士宪(1982—),男,副教授,博士,主要研究方向为新材料制备、冶金物理化学领域,E-mail: zhangshixian0303@163.com。
基金资助:
国家自然科学基金(51974129);河北省“三三三人才工程”项目(A202101030);河北工业职业技术大学博士基金(bz202301)

Diffusion mechanism and rules of nickel on surface of low carbon steel

Zhang Shixian¹, Xu Mingyue², Zhao Xiaoping¹, Li Yungang³

1. Hebei Vocational University of Industry and Technology, Shijiazhuang Hebei 050091, China;
2. Tangshan Iron Steel Group Co., Ltd., Tangshan Hebei 063000, China;
3. School of Metallurgy and Energy, North China University of Science and Technology, Tangshan Hebei 063009, China

Received:2022-11-30 Revised:2023-03-20 Online:2023-05-25 Published:2023-06-21

摘要/Abstract

摘要： 采用水溶液电沉积+高温固态扩散法成功制备了镍/低碳钢表面复合材料,研究了镍在低碳钢表面的扩散机理,利用 Den Broeder 法得到了不同温度下镍在低碳钢中的扩散规律。结果表明,高温固态扩散退火处理实现了镍沉积层与低碳钢的冶金结合,镍原子主要沿低碳钢晶界进行扩散,其扩散抑制了晶粒的长大。碳、硅、锰、硫、磷原子对镍原子的扩散影响较小。镍原子在低碳钢表面的固态扩散规律为D_Ni=-3.53×10^-21T⁴+1.75×10^-17T³ -3.22×10^-14T²+2.60×10^-11T -7.81×10^-9。在973~1373 K温度区间固态扩散时,随着温度的升高,镍原子的平均互扩散系数呈现先上升后下降再上升的趋势;晶体结构对于镍原子的扩散影响较大,镍原子在体心立方晶体结构中的扩散速度明显大于在面心立方晶体结构中的扩散速度。

关键词: 镍/低碳钢表面复合材料, 互扩散系数, 扩散机理, 扩散规律

Abstract: Nickel/low carbon steel surface composites were successfully prepared by means of aqueous solution electrodeposition+high temperature solid diffusion method. The diffusion mechanism of nickel on the surface of low carbon steel was studied. The diffusion rules of nickel on the surface of low carbon steel at different temperatures were obtained by using Den Broeder method. The results show that high temperature solid diffusion annealing realizes the metallurgical combination of nickel deposit layer and low carbon steel. Nickel atoms mainly diffuse along the grain boundary of low carbon steel, and its diffusion inhibits the growth of grains. Carbon, silicon, manganese, sulfur and phosphorus atoms have little influence on the diffusion of nickel atoms. The solid state diffusion rule of nickel atom on surface of the low carbon steel is D_Ni=-3.53×10^-21T⁴+1.75×10^-17T³ -3.22×10^-14T²+2.60×10^-11T -7.81×10^-9. During solid state diffusion at 973-1373 K, the average interdiffusion coefficient of nickel atoms increases first, then decreases and then increases with the increase of temperature. The crystal structure has a great influence on the diffusion of nickel atoms, and the diffusion speed of nickel atoms in the body centered cubic crystal structure is obviously higher than that in the face centered cubic crystal structure.

Key words: nickel/low carbon steel surface composite, interdiffusion coefficient, diffusion mechanism, diffusion rules

中图分类号:

TB331

张士宪, 徐鸣悦, 赵晓萍, 李运刚. 镍在低碳钢表面的扩散机理与规律[J]. 金属热处理, 2023, 48(5): 121-128.

Zhang Shixian, Xu Mingyue, Zhao Xiaoping, Li Yungang. Diffusion mechanism and rules of nickel on surface of low carbon steel[J]. Heat Treatment of Metals, 2023, 48(5): 121-128.

参考文献

[1]Yang H Q, Zhang Q, Li Y M, et al. Effects of mechanical stress and cathodic protection on the performance of a marine organic coating on mild steel[J]. Materials Chemistry and Physics, 2021, 261: 124233.
[2]Vinodhini S P, Xavier J R. Evaluation of corrosion protection performance and mechanical properties of epoxy-triazole/graphene oxide nanocomposite coatings on mild steel[J]. Journal of Materials Science, 2021, 56: 7094-7110.
[3]冉斗, 孟惠民, 刘星, 等. pH对14Cr12Ni3WMoV不锈钢在含氯溶液中腐蚀行为的影响[J]. 中国腐蚀与防护学报, 2021, 41(1): 51-59.
Ran Dou, Meng Huimin, Liu Xing, et al. Effect of pH on corrosion behavior of 14Cr12Ni3WMoV stainless steel in chlorine-containing solutions[J]. Journal of Chinese Society for Corrosion and Protection, 2021, 41(1): 51-59.
[4]陈学群, 张万灵, 陈珊, 等. 经济型耐腐蚀钢中氧作用的研究[J]. 工程科学学报, 2021, 43(7): 960-965.
Chen Xuequn, Zhang Wanling, Chen Shan, et al. Effect of oxygen on economical corrosion resistant steel[J]. Chinese Journal of Engineering, 2021, 43(7): 960-965.
[5]杨江. 采用磁控溅射法在钢材表面镀钛膜研究[D]. 成都: 西华大学, 2012.
Yang Jiang. The research of titanium film deposited on steel surface by magnetron sputtering[D]. Chengdu: Xihua University, 2012.
[6]辛蔚, 王玉江, 魏世丞, 等. 热喷涂制备非晶合金涂层性能的研究进展[J]. 工程科学学报, 2021, 43(3): 311-320.
Xin Wei, Wang Yujiang, Wei Shicheng, et al. Research progress on the properties of amorphous alloy coatings prepared by thermal spraying[J]. Chinese Journal of Engineering, 2021, 43(3): 311-320.
[7]赵帅, 孙建春, 周文, 等. 基于电沉积镍的低碳钢表面合金化扩散研究[J]. 热加工工艺, 2018, 47(10): 137-139, 143.
Zhao Shuai, Sun Jianchun, Zhou Wen, et al. Study on surface alloying diffusion of low carbon steel based on electrodeposited nickel[J]. Hot Working Technology, 2018, 47(10): 137-139, 143.
[8]刘双. 镍基金属涂层的制备及其腐蚀行为和机理研究[D]. 成都: 西南石油大学, 2019.
Liu Shuang. Preparation, corrosion behavior and mechanism ofnickel based metal coatings[D]. Chengdu: Southwest Petroleum University, 2019.
[9]耿瑛, 李菲晖, 巩运兰, 等. 温度对钢基体上暗镍镀层性能的影响[J]. 电镀与精饰, 2015, 37(4): 1-5.
Geng Ying, Li Feihui, Gong Yunlan, et al. Effects of temperature on the properties of nickel coatings electrodeposited on steel substrate[J]. Plating and Finishing, 2015, 37 (4): 1-5.
[10]赵国辰. 一步电镀镍复合纳米层改善低碳钢表面性能及相关技术的拓展研究[D]. 上海: 上海大学, 2016.
Zhao Guochen. One step electroplating of nickel based nanocomposite coatings for improving the surface properties of mild steel and the application of corresponding technique[D]. Shanghai: Shanghai University, 2016.
[11]Bolzmann L. Zur integration der diffusionsgleichung bei variabeln diffusions coefficienten[J]. Wiedemann's Annalen, 1894, 53: 959-964.
[12]Kavakbasi B T, Golovin I S, Paul A, et al. On the analysis of composition profiles in binary single-phase diffusion couples: Systems with a strong compositional dependence of the interdiffusion coefficient[J]. Defect and Diffusion Forum, 2018, 383: 23-30.
[13]Li J Q, Yuan C H. Electrochemical study of the effect of oxidation and amorphization of Cr nanoparticles on the co-deposition of Ni-Cr nanocomposite film[J]. Journal of Electroanalytical Chemistry, 2017, 795: 110-115.
[14]李孟星, 张宏博, 孟祥海, 等. 退火过程中Ni的扩散行为[J]. 金属热处理, 2019, 44(9): 46-51.
Li Mengxing, Zhang Hongbo, Meng Xianghai, et al. Diffusion behavior of Ni during annealing[J]. Heat Treatment of Metals, 2019, 44(9): 46-51.
[15]Zhang Q, Wu J, Jiang S, et al. The effect of grain size on the diffusion bonding properties of SP700 alloy[J]. Metals, 2022, 12(2): 237.
[16]杨朝曦, 柳文波, 张璁雨, 等. Fe-Cr合金晶界偏析及辐照加速晶界偏析的相场模拟[J]. 物理学报, 2021, 70(11): 236-245.
Yang Chaoxi, Liu Wenbo, Zhang Congyu, et al. Phase field simulation of grain boundary segregation and radiation-enhanced segregation in Fe-Cr alloys[J]. Acta Physica Sinica, 2021, 70(11): 236-245.
[17]Lin I C, Lin C J, Tuan W H. Diffusion coefficient of carbon in Fe-Ni alloy during synthesis of diamond under high temperature and high pressure[J]. Ceramics International, 2013, 39(8): 8861-8864.
[18]Hong L K, Cheng R, Ai L Q, et al. Mechanism of carbon diffusion in the iron sheet during gas-solid decarburization[J]. Transactions of the Indian Institute of Metals, 2019, 72(2): 335-342.
[19]Wang H Y, Gao X Y, Ren H P, et al. Diffusion coefficients of rare earth elements in fcc Fe: A first-principles study[J]. Journal of Physics and Chemistry of Solids, 2018, 112: 153-157.
[20]Sebastian A K, Sungwoo S, David U, et al. Phase selection motifs in high entropy alloys revealed through combinatorial methods: Large atomic size difference favors BCC over FCC[J]. Acta Materialia, 2019, 166: 677-686.
[21]董凤, 陈少平, 胡利方, 等. 电场作用下AZ31B/Cu扩散界面的结构及性能[J]. 材料工程, 2015, 43(2): 35-40.
Dong Feng, Chen Shaoping, Hu Lifang, et al. Structure and properties of AZ31B/Cu diffusion interface under electric field[J]. Journal of Materials Engineering, 2015, 43(2): 35-40.
[22]Pan R, Wang Q, Sun D L, et al. Effects of electric field on interfacial microstructure and shear strength of diffusion bonded α-Al₂O₃/Ti joints[J]. Journal of the European Ceramic Society, 2015, 35(1): 219-226.

镍在低碳钢表面的扩散机理与规律

Diffusion mechanism and rules of nickel on surface of low carbon steel

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