金属热处理 ›› 2023, Vol. 48 ›› Issue (11): 282-287.DOI: 10.13251/j.issn.0254-6051.2023.11.046

• 表面工程 • 上一篇    下一篇

激光扫描速率对NiCr/Cr3C2涂层微结构与耐磨性的影响

董会, 甘少明, 杜永祺, 白佳鑫, 程煜辰, 李明, 朱朝璇   

  1. 西安石油大学 材料科学与工程学院 西安市高性能油气田材料重点实验室, 陕西 西安 710065
  • 收稿日期:2023-06-13 修回日期:2023-09-13 出版日期:2023-11-25 发布日期:2023-12-27
  • 作者简介:董 会(1981—),男,副教授,硕士生导师,博士,主要研究方向为热障耐磨耐蚀涂层性能,E-mail:donghuihyy@163.com
  • 基金资助:
    国家自然科学基金(51904331);西安石油大学《材料科学与工程》省级优势学科(YS37020203)

Effect of laser scanning rate on microstructure and wear resistance of NiCr/Cr3C2 coating

Dong Hui, Gan Shaoming, Du Yongqi, Bai Jiaxin, Cheng Yuchen, Li Ming, Zhu Chaoxuan   

  1. Xi'an Key Laboratory of High Performance Oil and Gas Field Materials, School of Materials Science and Engineering, Xi'an Shiyou University, Xi'an Shaanxi 710065, China
  • Received:2023-06-13 Revised:2023-09-13 Online:2023-11-25 Published:2023-12-27

摘要: 采用激光熔覆技术在3种扫描速率下制备了NiCr/Cr3C2复合涂层,分别采用扫描电镜(SEM)、X射线衍射仪(XRD)、显微维氏硬度计、摩擦磨损试验机表征了熔覆层的组织形貌、硬度与摩擦磨损性能。结果表明,激光扫描速率从2 mm/s升至4 mm/s时,熔覆层组织从以树枝晶为主转变为以等轴晶为主,缺陷由气孔转变为大尺寸间隙与裂纹。扫描速率低于3 mm/s时,Cr3C2熔化分解导致熔覆层主要含有Cr7C3,随着激光扫描速率增加,Cr3C2熔化程度降低,熔覆层以Cr7C3与Cr3C2为主。因此,随着激光扫描速率从2 mm/s升高至4 mm/s,熔覆层硬度从400 HV0.3提升至780 HV0.3。不同激光扫描速率下熔覆层磨损均以磨粒磨损为主,但是由于结构致密和硬度较高,3 mm/s涂层磨损量最小,耐磨性最好。

关键词: 激光熔覆, 激光扫描速率, NiCr/Cr3C2涂层, 组织, 耐磨性

Abstract: NiCr/Cr3C2 composite coating was prepared by laser cladding at three laser scanning rates. The microstructure, hardness and friction and wear properties of the coatings were characterized using scanning electron microscope (SEM), X-ray diffractometer (XRD), micro-hardness tester and friction and wear testing machine. The results show that the structure in clad layer transfer from dendrite to equiaxed as the laser scanning rate increases from 2 mm/s to 4 mm/s, and the defects transfer from pores to large gaps and microcracks. When the scanning rate is below 3 mm/s, the melting and decomposition of Cr3C2 results in the clad layer mainly containing Cr7C3. As the laser scanning rate increases, the melting degree of Cr3C2 decreases, and the clad layer is mainly composed of Cr7C3 and Cr3C2. Therefore, the hardness of the clad layer increases from 400 HV0.3 to 780 HV0.3 when the laser scanning rate rises from 2 mm/s to 4 mm/s. The wear mechanism of the clad layer at different laser scanning rates is mainly abrasive wear, but due to its dense structure and higher hardness, the wear loss of the clad layer at scanning rate of 3 mm/s is the smallest and the wear resistance is the best.

Key words: laser cladding, laser scanning rate, NiCr/Cr3C2 coating, microstructure, wear resistance

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