金属热处理 ›› 2024, Vol. 49 ›› Issue (7): 281-286.DOI: 10.13251/j.issn.0254-6051.2024.07.043

• 工艺研究 • 上一篇    下一篇

阳极氧化对酸性盐雾环境中铝锂合金性能的影响

于娟, 冯朝辉, 陈高红, 伍镭   

  1. 北京航空材料研究院 北京市先进铝合金材料及应用工程技术研究中心, 北京 100095
  • 收稿日期:2024-02-06 修回日期:2024-05-07 出版日期:2024-07-25 发布日期:2024-08-29
  • 作者简介:于 娟(1988—),女,高级工程师,博士,主要研究方向为铝锂合金的开发,E-mail: 342014715@qq.com

Effect of anodizing process on properties of Al-Li alloy in acid salt spray environment

Yu Juan, Feng Zhaohui, Chen Gaohong, Wu Lei   

  1. Beijing Engineering Research Center of Advanced Aluminum Alloys and Applications, Beijing Institute of Aeronautical Materials, Beijing 100095, China
  • Received:2024-02-06 Revised:2024-05-07 Online:2024-07-25 Published:2024-08-29

摘要: 通过表面形貌观察、腐蚀速率分析、室温拉伸等方法,研究阳极氧化工艺对暴露在酸性盐雾腐蚀环境中的铝锂合金腐蚀行为和抗拉强度的影响。结果表明,未经阳极氧化处理的合金暴露在酸性盐雾环境中24 h后,即发生明显腐蚀,腐蚀面积为58.417%,144 h后的腐蚀形貌更加均匀,腐蚀面积达到88.350%,腐蚀增量速率随盐雾腐蚀时间的延长明显降低,腐蚀不同时间后的铝锂合金的抗拉强度均为400 MPa左右;经过硫酸阳极氧化和硼硫酸阳极氧化后的铝锂合金发生腐蚀需要的时间增加,腐蚀速率缓慢,暴露在酸性盐雾环境中240 h后未发现明显腐蚀,360 h后的腐蚀面积仅约7%,腐蚀不同时间后的铝锂合金的抗拉强度为500 MPa左右;阳极氧化处理后,铝锂合金表面形成了氧化膜,阻挡了腐蚀溶液中Cl-的侵蚀,显著提高了铝锂合金在酸性盐雾环境中的耐腐蚀性能和抗拉强度。

关键词: 铝锂合金, 酸性盐雾, 阳极氧化, 耐蚀性能, 抗拉强度

Abstract: Effect of anodizing process on the corrosion behavior and tensile strength of Al-Li alloy which exposed to acid salt spray environment was studied by means of surface morphology observation, corrosion rate analysis and room temperature tensile test. The results show that in acid salt spray environment, the unanodized Al-Li alloy occurs significant corrosion after 24 h with a corrosion area of 58.417%. After 144 h, the corrosion morphology is more uniform with a corrosion area of 88.350%. The corrosion mass gain rate decreases significantly with the extension of salt spray corrosion time. The tensile strength of the unanodized Al-Li alloy under different corrosion time is about 400 MPa. The corrosion of the sulfuric acid anodized and boron sulfuric acid anodized Al-Li alloy needs more time and the corrosion rate is slower. In acid salt spray environment, no obvious corrosion is found after 240 h, and the corrosion area is only about 7% after 360 h. The tensile strength of the Al-Li alloy under different corrosion time is about 500 MPa. After anodizing, an oxide film forms on the surface of the Al-Li alloy, which blocks the etching of Cl- in corrosion solution, and significantly improves the corrosion resistance and the tensile strength of the Al-Li alloy in the acid salt spray environment.

Key words: Al-Li alloy, acid salt spray, anodizing, corrosion resistance, tensile strength

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