CrAlN基涂层力学及抗氧化性能研究进展

doi:10.13251/j.issn.0254-6051.2024.09.050

摘要/Abstract

摘要： CrAlN涂层具有较高的硬度和耐磨性,被广泛应用于切削刀具和模具的表面防护。本文首先介绍了CrAlN涂层的结构及其对涂层力学性能和热分解机制的影响,指出Al元素含量及其存在方式是影响CrAlN晶体结构和性能的重要因素;其次,综述了CrAlN基多元涂层和多层涂层在力学性能、高温抗氧化性能的研究现状,围绕元素掺杂改性和多层涂层结构设计,对比分析各种改性方法的优势与不足;随后,总结了Si、Y、V等元素掺杂对涂层性能的影响,指出构建纳米尺度的多层结构能显著改善涂层性能;最后,讨论了CrAlN基涂层的高温氧化行为和高温失效机制,为CrAlN基硬质涂层的性能优化提供参考。

关键词: CrAlN基涂层, 多层结构, 元素掺杂, 力学性能, 抗氧化性能

Abstract: CrAlN coatings are extensively applied in the protection of the cutting tools and molds due to their higher hardness and abrasive resistance. Firstly, the structure of CrAlN coatings and its effect on the mechanical properties and thermal decomposition mechanism of the coatings is introduced in the present review, and then pointing out that the Al content and its existence mode are important factors affecting the structure and properties of CrAlN crystals. Secondly, research status of CrAlN-based multicomponent coating and multilayer coating about the mechanical properties and high temperature oxidation resistance properties is reviewed. Focused on the doping modification of elements and the designing of multilayer coating structure, the advantages and disadvantages of various modification methods are compared and analyzed, then the doping of Si, Y, V and their influence to the performance of coating are summarized, and pointing out that constructing nanoscale multilayer coating can significantly improve the performance. Finally, the high-temperature oxidation behavior and high-temperature failure mechanism of CrAlN-based coatings are discussed, providing a reference for the performance optimization of CrAlN-based hard coatings.

Key words: CrAlN-based coating, multilayer structure, element doping, mechanical properties, oxidation resistance

中图分类号:

TG174.4

贺涛, 曹红帅, 李贝贝, 齐福刚, 赵镍, 廖斌, 欧阳晓平. CrAlN基涂层力学及抗氧化性能研究进展[J]. 金属热处理, 2024, 49(9): 297-307.

He Tao, Cao Hongshuai, Li Beibei, Qi Fugang, Zhao Nie, Liao Bin, Ouyang Xiaoping. Research progress on mechanical properties and oxidation resistance of CrAlN-based coatings[J]. Heat Treatment of Metals, 2024, 49(9): 297-307.

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