冷轧节镍型不锈钢水纹印形成机理

doi:10.13251/j.issn.0254-6051.2024.10.047

金属热处理 ›› 2024, Vol. 49 ›› Issue (10): 290-294.DOI: 10.13251/j.issn.0254-6051.2024.10.047

冷轧节镍型不锈钢水纹印形成机理

鲁斐¹, 刘瞿², 郭永亮³, 李小磊¹, 何流¹

1.季华实验室, 广东佛山 528200;
2.清华大学机械工程系, 北京 100084;
3.超滑科技(佛山)有限责任公司, 广东佛山 528200

收稿日期:2024-04-30 修回日期:2024-08-13 出版日期:2024-11-28 发布日期:2024-11-28
通讯作者: 何流,博士,E-mail:heliu@jihualab.ac.cn
作者简介:鲁斐(1992—),男,工程师,硕士,主要研究方向为润滑油功能型添加剂、金属成形加工油液,E-mail: lufei@jihualab.ac.cn。
基金资助:
季华实验室科研项目(X210281TN210);佛山市创新创业团队项目(2120001008031)

Forming mechanism of water marks on cold-rolled nickel-saving stainless steel

Lu Fei¹, Liu Qu², Guo Yongliang³, Li Xiaolei¹, He Liu¹

1. Jihua Laboratory, Foshan Guangdong 528200, China;
2. Department of Mechanical Engineering, Tsinghua University, Beijing 100084, China;
3. China Super Lubrication Technology (Foshan) Co., Ltd., Foshan Guangdong 528200, China

Received:2024-04-30 Revised:2024-08-13 Online:2024-11-28 Published:2024-11-28

摘要/Abstract

摘要： 冷轧节镍型不锈钢板带连续退火后表面产生水纹印现象,会演变为锈蚀造成严重损失。通过金相显微镜、扫描电镜和能谱分析等手段对比分析了不锈钢板带无水纹印和有水纹印试样的表面形貌、成分、微观组织及耐蚀性,结合轧制工艺研究了水纹印的形成机理。结果表明,冷轧节镍型不锈钢的冷轧过程中,出现水纹印的带中部分处于高速轧制状态,轧制塑性变形速率远大于无水纹印的头部和尾部,导致微观组织产生大量的变形带,恶化了冷轧不锈钢的耐蚀性能,进而形成了大量微小点蚀组成的水纹印形貌。

关键词: 节镍型不锈钢, 冷轧, 退火, 水纹印

Abstract: Water marks occurred on the surface of cold-rolled nickel-saving stainless steel strip after continuous annealing, which would evolve into corrosion and cause serious loss. The surface morphology, composition, microstructure and corrosion resistance of the stainless steel strip specimens with and without water marks were compared and analyzed by means of metallographic microscopy, scanning electron microscopy and EDS analysis, and the forming mechanism of water marks was studied in combination with rolling process. The results indicate that during the cold rolling process of stainless steel, the middle part of the cold-rolled nickel-saving stainless steel where the water marks forms is in a high speed rolling state and is at a higher plastic deformation rate than the head and end without water marks. The high speed rolling results in numerous deformation bands within the microstructure of the strip which compromise the corrosion resistance of cold-rolled stainless steel, ultimately leading to the formation of numerous micro-pitting water marks.

Key words: nickel-saving stainless steel, cold rolling, annealing, water marks

中图分类号:

TG156.26

鲁斐, 刘瞿, 郭永亮, 李小磊, 何流. 冷轧节镍型不锈钢水纹印形成机理[J]. 金属热处理, 2024, 49(10): 290-294.

Lu Fei, Liu Qu, Guo Yongliang, Li Xiaolei, He Liu. Forming mechanism of water marks on cold-rolled nickel-saving stainless steel[J]. Heat Treatment of Metals, 2024, 49(10): 290-294.

参考文献

[1]Sumita M, Hanawab T, Teohc S H. Development of nitrogen containing nickel free austenitic stainless steels for metallic biomaterials-review[J]. Materials Science and Engineering C, 2004, 24(6/7/8): 753-760.
[2]Milititsky M, De Wispelaere N, Petrov R, et al. Characterization of the mechanical properties of low-nickel austenitic stainless steels[J]. Materials Science and Engineering A, 2008, 498(1/2): 289-295.
[3]李志, 高谦, 何冰, 等. 节镍型奥氏体不锈钢1Cr17Mn9Ni4N的组织和力学性能[J]. 钢铁研究学报, 2005, 17(2): 68-71.
Li Zhi, Gao Qian, He Bing, et al. Microstructure and mechanical properties of 1Cr17Mn9Ni4N steel[J]. Journal of Iron and Steel Research, 2005, 17(2): 68-71.
[4]张仲秋, 李新亚, 娄延春, 等. 含氮不锈钢研究的进展[J]. 铸造, 2002, 51(11): 661-665.
Zhang Zhongqiu, Li Yaxin, Lou Yanchun, et al. Advance in research of nitrogen contained stainless steels[J]. Foundry, 2002, 51(11): 661-665.
[5]曾垚, 杨剑洪, 王碧, 等. 节镍型奥氏体不锈钢的组织性能对比[J]. 金属热处理, 2020, 45(6): 163-166.
Zeng Yao, Yang Jianhong, Wang Bi, et al. Comparison of microstructure and properties of low-nickel austenitic stainless steels[J]. Heat Treatment of Metals, 2020, 45(6): 163-166.
[6]吴海林, 阮志勇, 王碧, 等. 节镍型奥氏体不锈钢组织性能及控制机理研究[J]. 轧钢, 2022, 39(3): 17-22.
Wu Hailin, Ruan Zhiyong, Wang Bi, et al. Study on microstructure, mechanical properties and control mechanism of low-nickel austenitic stainless steel[J]. Steel Rolling, 2022, 39(3): 17-22.
[7]罗兴壮, 罗庆革, 杨剑洪, 等. 低镍奥氏体不锈钢冷轧边裂原因分析[J]. 轧钢, 2021, 38(4): 89-93.
Luo Xingzhuang, Luo Qingge, Yang Jianhong, et al. Cause analysis of edge crack of low nickel austenitic stainless steel strip during cold rolling[J]. Steel Rolling, 2021, 38(4): 89-93.
[8]邢长军, 廖辉, 宁小智, 等. 新型节镍奥氏体不锈钢的成分设计及生产试制[J]. 钢铁, 2021, 56(4): 93-97.Xing Changjun, Liao Hui, Ning Xiaozhi, et al. Composition design and trial production of new nickel saving austenitic stainless steel[J]. Iron and Steel, 2021, 56(4): 93-97.
[9]黄俊霞. 客车车辆用含氮奥氏体不锈钢的研究[D]. 上海: 上海交通大学, 2013.
[10]Kim Y H, Kim K Y, Lee Y D. Nitrogen-alloyed, metastable austenitic stainless steel for automotive structural applications[J]. Materialsand Manufacturing Processes, 2004, 19(1): 51-59.
[11]Mahajan S, Pande C, Imam M, et al. Formation of annealing twins in fcc crystals[J]. Acta Materialia, 1997, 45: 2633-2638.
[12]Frankel G S. Pitting corrosion of metals: A review of the critical factors[J]. Cheminform, 1998, 29(32): 2186-2197.
[13]Dutta R S, Jagannath, Dey G K, et al. Characterization of microstructure and corrosion properties of cold worked alloy 800[J]. Corrosion Science, 2006, 48(9): 2711-2726.
[14]Zhang Y, Li M, Bi H. The mechanism of pitting initiation and propagation at deformation bands intersection of cold-rolled metastable stainless steel in acidic ferric chloride solution[J]. Journal of Materials Science, 2019, 54: 14914-14925.
[15]Mudali U K, Shankar P, Ningshen S, et al. On the pitting corrosion resistance of nitrogen alloyed cold worked austenitic stainless steels[J]. Corrosion Science, 2002, 44(10): 2183-2198.
[16]Luo H, Su H Z, Ying G B, et al. Effect of cold deformation on the electrochemicalbehaviour of 304L stainless steel in contaminated sulfuric acid environment[J]. Applied Surface Science, 2017, 425: 628-638.

冷轧节镍型不锈钢水纹印形成机理

Forming mechanism of water marks on cold-rolled nickel-saving stainless steel

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