石墨烯添加剂对ZL109铝合金活塞微弧氧化复合膜层摩擦性能的影响

doi:10.13251/j.issn.0254-6051.2020.02.045

金属热处理 ›› 2020, Vol. 45 ›› Issue (2): 231-234.DOI: 10.13251/j.issn.0254-6051.2020.02.045

石墨烯添加剂对ZL109铝合金活塞微弧氧化复合膜层摩擦性能的影响

胡海峰, 李晓, 王连海, 马强, 刘新建

山东交通学院船舶与轮机工程学院, 山东威海 264200

收稿日期:2019-08-29 出版日期:2020-02-25 发布日期:2020-04-03
作者简介:胡海峰(1979—),男,讲师,硕士,主要从事金属表面处理技术、船用设备零部件再制造技术研究,E-mail:hfjamy@163.com。

Effect of graphene on friction properties of miro-arc oxidation films produced on ZL109 aluminum alloy piston

Hu Haifeng, Li Xiao, Wang Lianhai, Ma Qiang, Liu Xinjian

Naval Architecture & Marine Engineering College, Shandong Jiaotong University, Weihai Shandong 264200, China

Received:2019-08-29 Online:2020-02-25 Published:2020-04-03

摘要/Abstract

摘要：

在电解液中加入不同浓度石墨烯添加剂,通过微弧氧化在ZL109铝合金表面制备了石墨烯复合陶瓷膜,通过测厚仪和硬度计对膜层进行检测;然后对最佳浓度处理试件进行摩擦磨损试验,分析其摩擦因数、表面形貌以评价石墨烯添加剂对微弧氧化复合陶瓷膜摩擦性能的影响和作用机理。结果表明:石墨烯添加剂的加入使微弧氧化膜层具有更加优异表面性能和抗磨减摩性能,在浓度为6 g/L时膜层厚度达29.68 μm,硬度达到990.12 HV0.3,摩擦因数稳定在0.19,较普通陶瓷膜摩擦因数显著降低,达34.48%。在磨擦过程中,石墨烯对摩擦副表面的凹槽和划痕进行了填充,表面珩磨纹更加细密;同时,复合添加剂在磨擦过程中形成了C元素薄膜,起到了自修复作用。

关键词: 复合陶瓷膜, 石墨烯, 减摩抗磨, 摩擦因数

Abstract:

Graphene composite ceramic film was prepared on the surface of ZL109 aluminum alloy by micro arc oxidation with different concentration of graphene additive in the electrolyte. The film was tested by thickness gauge and hardness tester. Then, the friction and wear tests were carried out on the optimized concentration treated samples, and the friction coefficient and surface morphology were analyzed to evaluate the friction performance of the composite ceramic film prepared by micro arc oxidation with graphene additive and its action mechanism. The results show that the graphene additive makes the micro-arc oxidation film layer have better surface properties, anti-wear and friction reducing properties. When the concentration is 6 g/L, the film thickness reaches 29.68 μm, the hardness reaches 990.12 HV0.3, and the friction coefficient is stable at 0.19. The friction coefficient is significantly lower than that of ordinary ceramic coatings, up to 34.48%. During the friction process, graphene fills the grooves and scratches on the surface of the friction pair, and the surface honing is finer. At the same time, the composite additive forms a carbon film during the friction process, which plays a self-repairing role.

Key words: composite ceramic film, grapnene, anti-wear and friction reducing, friction coefficient

中图分类号:

TH117.1

胡海峰, 李晓, 王连海, 马强, 刘新建. 石墨烯添加剂对ZL109铝合金活塞微弧氧化复合膜层摩擦性能的影响[J]. 金属热处理, 2020, 45(2): 231-234.

Hu Haifeng, Li Xiao, Wang Lianhai, Ma Qiang, Liu Xinjian. Effect of graphene on friction properties of miro-arc oxidation films produced on ZL109 aluminum alloy piston[J]. HTM, 2020, 45(2): 231-234.

参考文献

[1]林玉金, 胡权, 杜勋贵, 等. Cu含量对7003铝合金挤压材组织与性能的影响[J]. 世界有色金属, 2018(4): 7-9.
Lin Yujin, Hu Quan, Du Xungui, et al. Effect of Cu content on microstructure and mechanical properties of as-extruded 7003 alloy[J]. World Nonferrous Metal, 2018(4): 7-9.
[2]张继魁, 张国亮, 纪同圣, 等. 重型汽车柴油机活塞销用钢及表面处理技术[J]. 汽车工艺与材料, 2015(6): 46-50, 57.
[3]黄智, 李佐军, 周科朝. 植入用镁及其合金可生物降解涂层的研究进展[J]. 材料导报, 2014, 28(3): 66-70.
Huang Zhi, Li Zuojun, Zhou Kechao. Research progress on biodegradable coatings of magnesium and magnesium alloys for implant[J]. Materials Reports, 2014, 28(3): 66-70.
[4]康永, 李雯. 不同基材微弧氧化无机陶瓷膜性能研究进展[J]. 陶瓷, 2016(8): 14-19.
Kang Yong, Li Wen. Research progress on properties of ceramic coatings prepared with micro plasma oxidation technology on different substrates[J]. Ceramics, 2016(8): 14-19.
[5]Wang B, Zhang L, Su Y, et al. Investigation on the corrosion behavior of aluminum alloys 3A21 and 7A09 in chloride aqueous solution[J]. Materials & Design, 2013, 8(3): 435-442.
[6]王剑桥, 雷卫宁, 薛子明, 等. 石墨烯增强金属基复合材料的制备及应用研究进展[J]. 材料工程, 2018, 46(12): 18-27.
Wang Jianqiao, Lei Weining, Xue Ziming, et al. Research progress on synthesis and application of graphene reinforced metal matrix composites[J]. Journal of Materials Engineering, 2018, 46(12): 18-27.
[7]袁文辉, 李保庆, 李莉. 改进液相氧化还原法制备高性能氢气吸附用石墨烯[J]. 物理化学学报, 2011, 27(9): 2244-2250.
Yuan Wenhui, Li Baoqing, Li Li. Superior graphene for hydrogen adsorption prepared by the improved liquid oxidation-reduction method[J]. Acta Physico-Chimica Sinica, 2011, 27(9): 2244-2250.
[8]张玉林, 于佩航, 韦银河, 等. 石墨烯添加剂对铝合金表面微弧氧化膜耐磨耐蚀性的影响[J]. 材料热处理学报, 2017, 38(8): 103-109.
Zhang Yulin, Yu Peihang, Wei Yinhe, et al. Influence of graphene additive on wear resistance and corrosion resistance of micro arc oxidation coating formed on LY12 aluminium alloy surface[J]. Transactions of Materials and Heat Treatment, 2017, 38(8): 103-109.
[9]徐曦. 柴油机铝合金活塞表面自修复耐磨陶瓷层制备及性能研究[D]. 大连: 大连海事大学, 2016.
[10]鲁闯, 谢发勤, 朱利萍. Al-Si合金微弧氧化工艺优化研究[J]. 兵器材料与科学工程, 2016, 39(4): 74-77.

Lu Chuang, Xie Faqin, Zhu Liping. Technology improvement of micro-arc oxidation on Al-Si alloy[J]. Ordnance Material Science and Engineering, 2016, 39(4): 74-77.
[11]龙北玉, 吴汉华, 龙北红, 等. 电解液对铝合金微弧氧化陶瓷膜相组成和元素成分的影响[J]. 吉林大学学报: 理学版, 2005, 43(1): 68-72.
Long Beiyu, Wu Hanhua, Long Beihong, et al. Effects of electrolyte solution on phase component and elementary composition of MAO coatings on aluminium alloy[J]. Journal of Jilin University (Science Edition), 2005, 43(1): 68-72.
[12]胡海峰, 刘新建, 王连海, 等. 蛇纹石纳米粒子对ZL109铝合金活塞微弧氧化膜层摩擦性能的影响[J]. 润滑与密封, 2017, 42(10): 75-79, 86.
Hu Haifeng, Liu Xinjian, Wang Lianhai, et al. Effects of serpentine nano-particles on the friction properties of miro-arc oxidation films produced on ZL109 aluminum alloy piston surface[J]. Lubrication Engineering, 2017, 42(10): 75-79, 86.
[13]孙安元, 吴亚平, 陈坤, 等. 瞬时滑动状态下轮轨摩擦系数试验研究[J]. 铁道标准设计, 2018, 62(2): 48-52.
Sun Anyuan, Wu Yaping, Chen Kun, et al. Experimental research on wheel/rail friction coefficient under transient sliding condition[J]. Railway Standard Design, 2018, 62(2): 48-52.
[14]乔玉林, 崔庆生, 臧艳, 等. 石墨烯油润滑添加剂的减摩抗磨性能[J]. 装甲兵工程学院学报, 2014, 28(6): 97-100.
Qiao Yulin, Cui Qingsheng, Zang Yan, et al. Friction-reducing and anti-wear behavior of graphene oil lubricating additives[J]. Journal of Academy of Armored Force Engineering, 2014, 28(6): 97-100.

石墨烯添加剂对ZL109铝合金活塞微弧氧化复合膜层摩擦性能的影响

Effect of graphene on friction properties of miro-arc oxidation films produced on ZL109 aluminum alloy piston

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