金属热处理 ›› 2020, Vol. 45 ›› Issue (7): 143-147.DOI: 10.13251/j.issn.0254-6051.2020.07.029

• 材料研究 • 上一篇    下一篇

含Co不锈钢析出相的模拟研究与强韧性能变化

陈婉婉, 邹德宁, 李姣, 张英波, 李雨浓   

  1. 西安建筑科技大学 冶金工程学院, 陕西 西安 710055
  • 收稿日期:2020-01-16 出版日期:2020-07-25 发布日期:2020-09-07
  • 通讯作者: 邹德宁, 教授, 博士, E-mail:zoudening@sina.com
  • 作者简介:陈婉婉(1994—), 女, 硕士研究生, 主要研究方向为马氏体不锈钢强韧化机理和超级奥氏体不锈钢凝固偏析行为, E-mail:879185849@qq.com。
  • 基金资助:
    国家自然科学基金钢铁联合基金(U1460104)

Simulation study of precipitate phases and variation of strength and toughness of Co-containing stainless steel

Chen Wanwan, Zou Dening, Li Jiao, Zhang Yingbo, Li Yunong   

  1. School of Metallurgical Engineering, Xi 'an University of Architecture and Technology, Xi 'an Shaanxi 710055, China
  • Received:2020-01-16 Online:2020-07-25 Published:2020-09-07

摘要: 采用数值模拟、组织表征和性能测试等方法,研究了添加Co对马氏体时效硬化不锈钢微观组织和力学性能的影响。根据ThermoCalc热力学及动力学计算结果:6wt%Co条件下,ε-Cu相的析出温度升高且孕育时间变长,相同时效条件下εCu相的平均半径会逐渐减小。借助光学显微镜(OM)及透射电镜(TEM)分析发现,固溶+时效处理后含Co试验钢超低碳板条马氏体细化,弥散分布的εCu相尺寸变小且析出量增加,薄膜状逆变奥氏体数量增多且尺寸增大。由于板条马氏体的位错强化、ε-Cu相的析出强化以及逆变奥氏体相的增韧作用,含Co试验钢的抗拉强度、硬度、伸长率及冲击吸收能量分别达到1346 MPa、433 HV0.5、16%和73 J。

关键词: 马氏体时效硬化不锈钢, 钴合金化, Thermo-Calc软件, ε-Cu相

Abstract: Influence of Co addition on the microstructure and mechanical properties of maraging stainless steel was studied by using numerical simulation, microstructure characterization and performance test. According to the thermodynamic and kinetic calculation with Thermo-Calc software, the results show that with addition of 6wt%Co,the precipitation temperature of ε-Cu phase rises and the incubation time becomes longer, and under the same aging condition the average radius of ε-Cu precipitates decreases. The optical microscopy (OM) and transmission electron microscopy (TEM) analysis results show that for the Co-containing tested steel after solution treatment and aging, the ultra-low carbon lath martensite is refined obviously, the dispersed ε-Cu phase size becomes smaller and the precipitation amount increases gradually, and the film-like inverted austenite increases in amount and in size. Owing to the dislocation strengthening of lath martensite, the precipitation strengthening of ε-Cu phase and the toughening effect of the inverted austenite phase, the strength, hardness, elongation and impact absorbed energy of the tested Co-containing steel reach 1350 MPa, 433 HV0.5, 16% and 75 J, respectively.

Key words: maraging stainless steel, cobalt alloying, Thermo-Calc software, ε-Cu phase

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