电化学沉积镍铁合金镀层的研究进展

doi:10.13251/j.issn.0254-6051.2021.09.003

摘要/Abstract

摘要： 介绍了电化学沉积制备镍铁合金镀层中镍铁异常共沉积的发生机理,综述了电化学沉积的相关工艺参数,包括电流密度、主盐类型与浓度、添加剂分子和其它因素对镍铁合金镀层微观形貌、合金成分、晶体结构和应用性能的影响,重点介绍了镍铁合金镀层在耐磨损、防腐蚀、析氢电极材料和磁学性能方面的应用,揭示了目前镍铁合金镀层制备与应用方面的问题,展望了其未来的发展趋势。

关键词: 镍-铁合金镀层, 电沉积, 耐蚀性, 析氢电极, 磁学性能

Abstract: Mechanisms of abnormal co-deposition of nickel and iron in the preparation of Ni-Fe alloy coating by electrochemical deposition are introduced. The influences of parameters of electrochemical deposition, including current density, main salt type and concentration, additives and other factors, on surface morphology, alloy composition, phase composition and performance of the Ni-Fe alloy coating are reviewed, and the applications of Ni-Fe alloy coating in wear resistance and corrosion resistance, hydrogen evolution electrode and magnetic properties are emphatically introduced. Finally, the existing problems of current Ni-Fe alloy coating are summarized, and the future development trends in this field are prospected.

Key words: Ni-Fe alloy coating, electrochemical deposition, corrosion resistance, hydrogen evolution electrode, magnetic properties

中图分类号:

TQ153

颜庭林, 高晓丽, 王纪元. 电化学沉积镍铁合金镀层的研究进展[J]. 金属热处理, 2021, 46(9): 15-20.

Yan Tinglin, Gao Xiaoli, Wang Jiyuan. Research progress of electrodeposited Ni-Fe alloy coating[J]. Heat Treatment of Metals, 2021, 46(9): 15-20.

参考文献

[1]李雪松, 马立军, 高金芝, 等. 电流密度对光亮镍-铁合金镀层表面形貌及耐蚀性的影响[J]. 电镀与环保, 2009, 29(3): 7-9.
Li Xuesong, Ma Lijun, Gao Jinzhi, et al. The effects of current density to surface morphology and corrosion resistance of bright Ni-Fe alloy coating[J]. Electroplating and Pollution Control, 2009, 29(3): 7-9.
[2]豆红波. 电流密度对汽车用碳素钢上镍-铁合金箔性能的影响[J]. 电镀与环保, 2019, 39(2): 4-7.
Dou Hongbo. Influence of current density on properties of Ni-Fe alloy foils prepared on carbon steel for automotive applications[J]. Electroplating and Pollution Control, 2019, 39(2): 4-7.
[3]罗北平, 龚竹青, 陈梦君, 等. 富铁Fe-Ni合金电沉积工艺及其形貌结构与耐蚀性[J]. 腐蚀科学与防护技术, 2006, 18(1): 32-36.
Luo Beiping, Gong Zhuqing, Chen Mengjun, et al. Microstructure and corrosion resistance of iron-rich Fe-Ni alloy foil prepared by electrodeposition[J]. Corrosion Science and Protection Technology, 2006, 18(1): 32-36.
[4]于洋, 陈吉, 储刚, 等. Fe^2⁺质量浓度对纳米晶Ni-Fe合金电沉积层耐蚀性的影响[J]. 石油化工高等学校学报, 2011, 24(4): 51-54.
Yu Yang, Chen Ji, Chu Gang, et al. Effect of Fe^2⁺ concentration on corrosion resistance of electroplated nanocrystalline Ni-Fe coatings[J]. Journal of Petrochemical Universities, 2011, 24(4): 51-54.
[5]王志义, 刘向秀. 紫铜表面镍-铁合金镀层的织构及性能[J]. 电镀与环保, 2019, 39(6): 20-23.
Wang Zhiyi, Liu Xiangxiu. Texture and properties of Ni-Fe alloy coatings on red copper[J]. Electroplating and Pollution Control, 2019, 39(6): 20-23.
[6]Kim S H, Sohn H J, Joo Y C, et al. Effect of saccharin addition on the microstructure of electrodeposited Fe-36 wt.%Ni alloy[J]. Surface and Coatings Technology, 2005, 199(1): 43-48.
[7]孙冬来, 陈吉, 储刚, 等. 糖精对脉冲电镀纳米晶镍-铁合金镀层耐蚀性的影响[J]. 电镀与环保, 2013, 33(3): 21-24.
Sun Donglai, Chen Ji, Chu Gang, et al. Influence of saccharin on corrosion resistance of nanoscrystalline Ni-Fe alloy coating prepared by pulse plating[J]. Electroplating & Pollution Control, 2013, 33(3): 21-24.
[8]邢乐红, 王宜鑫, 王慧, 等. 氨基乙酸对硫酸盐体系电镀镍-铁合金的影响[J]. 电镀与涂饰, 2019, 38(19): 1039-1041.
Xing Lehong, Wang Yixin, Wang Hui, et al. Effect of glycine on electroplating of nickel-iron alloy in sulfate bath[J]. Electroplating and Finishing, 2019, 38(19): 1039-1041.
[9]邢乐红, 黎德育, 李宁, 等. 抗坏血酸对硫酸盐体系镍-铁合金镀液稳定性的影响[J]. 电镀与涂饰, 2018, 37(12): 526-528.
Xing Lehong, Li Deyu, Li Ning, et al. Effect of ascorbic acid on stability of sulfate nickel-iron alloy electroplating bath[J]. Electroplating and Finishing, 2018, 37(12): 526-528.
[10]朱福良, 张霞, 黄秀扬, 等. 稀土氧化钐对直流电沉积纳米镍铁合金箔的影响[J]. 兰州理工大学学报, 2010, 36(6): 13-16.
Zhu Fuliang, Zhang Xia, Huang Xiuyang, et al. Influence of rare-earth Sm₂O₃ on alloy foil with DC-electrodeposited nanocrystal line Ni-Fe[J]. Journal of Lanzhou University of Technology, 2010, 36(6): 13-16.
[11]温艳玲, 钟云波, 任忠鸣, 等. 强磁场对电沉积镍铁合金膜显微组织的影响[J]. 中国有色金属学报, 2006, 16(4): 715-721.
Wen Yanling, Zhong Yunbo, Ren Zhongming, et al. Effect of high static magnetic field on microstructure of electrodeposited NiFe film[J]. The Chinese Journal of Nonferrous Metals, 2006, 16(4): 715-721.
[12]李军, 李雪松, 马立军, 等. 搅拌方式对Ni-Fe合金镀层中铁的质量分数的影响[J]. 电镀与环保, 2008, 28(4): 18-20.
Li Jun, Li Xuesong, Ma Lijun, et al. Effects of stirring methods on mass fraction of iron in electrodeposited Ni-Fe alloy[J]. Electroplating and Pollution Control, 2008, 28(4): 18-20.
[13]王霞, 李后国, 陈玉祥, 等. 热处理对纳米 Ni-W合金镀层结构及性能的影响[J]. 金属热处理, 2016, 41(10): 141-146.
Wang Xia, Li Houguo, Chen Yuxiang, et al. Influence of heat treatment on structure and properties of nanostructured Ni-W coating[J]. Heat Treatment of Metals, 2016, 41(10): 141-146.
[14]Tomlinson W J, Campbell S A. Passivity, pitting and corrosion of anodically polarized Fe-Ni alloys in 0.5 M H₂SO₄ containing Cl^-[J]. Journal of Materials Science, 1986, 21(7): 2590-2596.
[15]Solmaz R, Kardaş G. Electrochemical deposition and characterization of NiFe coatings as electrocatalytic materials for alkaline water electrolysis[J]. Electrochimica Acta, 2009, 54(14): 3726-3734.
[16]姜吉琼, 林福胜. Ni-Fe-SiC复合镀层的制备及性能研究[J]. 电镀与涂饰, 2008, 27(8): 8-10.
Jiang Jiqiong, Lin Fusheng. Study on preparation and properties of Ni-Fe-SiC composite coating[J]. Electroplating and Finishing, 2008, 27(8): 8-10.
[17]闫巍, 余智勇, 周亚欢, 等. 钛基镍-铁合金电极的制备及其析氢性能[J]. 电镀与涂饰, 2016, 35(21): 1097-1102.
Yan Wei, Yu Zhiyong, Zhou Yahuan, et al. Preparation of nickel-iron alloy electrode on titanium substrate and its hydrogen evolution performance[J]. Electroplating and Finishing, 2016, 35(21): 1097-1102.
[18]闫巍, 余智勇, 李新杰, 等. 钛/石墨烯/镍-铁合金析氢电极的制备及其析氢性能[J]. 电镀与涂饰, 2017, 36(7): 337-341.
Yan Wei, Yu Zhiyong, Li Xinjie, et al. Preparation and hydrogen evolution performance of titanium/reduced graphene oxide/nickel-iron alloy electrode[J]. Electroplating and Plating, 2017, 36(7): 337-341.
[19]宋利君, 孟惠民. 电沉积纳米镍合金在模拟海水溶液中的析氢性能[J]. 物理化学学报, 2010, 26(9): 2375-2380.
Song Lijun, Meng Huimin. Electrodeposition of nanocrystalline nickel alloys and their hydrogen evolution in simulated seawater solution[J]. Acta Physico-Chimica Sinica, 2010, 26(9): 2375-2380.
[20]齐海东. 电沉积制备镍基电极及其催化析氢性能[D]. 唐山: 华北理工大学, 2019.
Qi Haidong. Ni-based electrode by electrodeposition and catalytic hydrogen evolution property[D]. Tangshan: North China University of Science and Technology, 2019.
[21]Shorowordi K M, Moniruzzaman M, Taufique M, et al. Effect of Ni/Fe ratio of electrolyte salts on the magnetic property of electrodeposited Fe-Ni alloy[J]. Surface Engineering and Applied Electrochemistry, 2017, 53(1): 52-58.
[22]张卫国, 刘宁, 王宏智, 等. Ni79-Fe21合金纳米线的电化学制备与表征[J]. 电镀与精饰, 2014, 36(8): 1-3, 13.
Zhang Weiguo, Liu Ning, Wang Hongzhi, et al. Electrochemical preparation and characterization of Ni79-Fe2l alloy nanowires[J]. Plating and Finishing, 2014, 36(8): 1-3, 13.
[23]崔智军. 电镀镍铁合金中糖精对磁通门噪声的影响[J]. 传感器与微系统, 2018, 37(1): 35-37.
Cui Zhijun. Effect of saccharin in electroplated NiFe alloy on noise of fluxgate[J]. Transducer and Microsystem Technologies, 2018, 37(1): 35-37.
[24]吴军民, 汤学华. 射频微机电系统开关软磁悬臂梁微电镀工艺[J]. 上海电机学院学报, 2010, 13(4): 193-196.
Wu Junmin, Tang Xuehua. Microelectroplation for soft magnetic cantilever of radio frequency microelectromechanical system switch[J]. Journal of Shanghai Dianji University, 2010, 13(4): 193-196.
[25]蒙延双, 朱福良. 电沉积纳米晶镍铁合金箔微结构与软磁性能[J]. 有色金属工程, 2013, 3(3): 15-17.
Meng Yanshuang, Zhu Fuliang. Microstructure and soft magnetic properties of electrodeposited nanocrystalline nickel-iron alloy foil[J]. Nonferrous Metals Engineering, 2013, 3(3): 15-17.