不同固溶冷速GH4096高温合金在高温蠕变测试中γ′相的演变行为

doi:10.13251/j.issn.0254-6051.2021.09.032

金属热处理 ›› 2021, Vol. 46 ›› Issue (9): 173-179.DOI: 10.13251/j.issn.0254-6051.2021.09.032

不同固溶冷速GH4096高温合金在高温蠕变测试中γ′相的演变行为

卢毓华^1,2, 王海舟^1,2, 付锐³, 李福林³, 李冬玲^1,2, 黄丹琪^1,2, 蔡文毅^1,2

1.钢铁研究总院北京材料基因工程高精尖创新中心, 北京 100081;
2.钢研纳克检测技术股份有限公司金属材料表征北京市重点实验室, 北京 100081;
3.钢铁研究总院高温材料研究所, 北京 100081

收稿日期:2021-05-09 出版日期:2021-09-25 发布日期:2021-12-09
通讯作者: 王海舟,院士,E-mail:wanghaizhou@ncschina.com
作者简介:卢毓华(1992—),男,博士研究生,主要研究方向为大尺寸高温合金γ′相的跨尺度定量分布表征,E-mail:luyuhua@ncschina.com。
基金资助:
国家重点研发计划(2016YFB0701401)

Behavior of γ′ precipitates under high temperature creep of GH4096 superalloy with different solution treatment cooling rates

Lu Yuhua^1,2, Wang Haizhou^1,2, Fu Rui³, Li Fulin³, Li Dongling^1,2, Huang Danqi^1,2, Cai Wenyi^1,2

1. Beijing Advanced Innovation Center for Materials Genome Engineering, Central Iron and Steel Research Institute, Beijing 100081, China;
2. Beijing Key Laboratory of Metal Materials Characterization, NCS Testing Technology Co., Ltd., Beijing 100081, China;
3. High Temperature Material Research Institute, Center Iron and Steel Research Institute, Beijing 100081, China

Received:2021-05-09 Online:2021-09-25 Published:2021-12-09

摘要/Abstract

摘要： 采用5种常见的冷却方式对析出强化型GH4096高温合金进行固溶冷却,分别制备了5种冷速下的标准尺寸涡轮盘挡板件。试样在700 ℃、690 MPa下进行高温蠕变测试,比较了5种冷却工艺下GH4096高温合金的性能。通过引入一种新颖的原位统计表征手段,以图像的形式跨尺度地实现了对合金材料中的强化相——一次、二次、三次γ′相的原位观察和统计定量分布观察,并比较和探讨了高温蠕变前后材料中γ′相形貌和尺寸分布的变化。结果表明:5种冷速方式得到的GH4096高温合金均展现较好的高温蠕变性能。5种工艺下的材料中γ′相分布密度为210~260个/μm²,经过高温蠕变测试以后,γ′相数量显著减少,γ′相分布密度降为150~200个/μm²。其中γ′相密度的降低,主要是由直径小于36 nm的γ′相减少所导致。

关键词: 高温合金, 冷却速率, γ′相, 高温蠕变, 定量统计表征

Abstract: Precipitation-strengthened solution treated GH4096 superalloy was cooled by five different cooling methods. Standard size turbine disc baffles under five cooling rates were prepared separately. The specimens were subjected to high temperature creep tests at 700 ℃ and 690 MPa, and the performance of the five GH4096 superalloy disc baffles was compared. By introducing a novel in-situ statistical characterization method, the in-situ observation and statistical quantitative distribution observation of the strengthening phase in the alloy material-primary, secondary, and tertiary γ′ phases were realized across scales in the form of images. The changes of γ′ phase morphology and size distribution in the materials before and after high temperature creep were compared and discussed. The results show that the GH4096 superalloys obtained by the five cooling rates all exhibit good high-temperature creep properties. The γ′ phase distribution density of the materials under the five processes is 210-260 μm^-2. After the high temperature creep test, the number of γ′ phases is significantly reduced, and the γ′ phase distribution density drops to 150-200 μm^-2. Among them, the decrease of γ′ phase density is mainly due to the decrease of γ′ phases with a diameter less than 36 nm.

Key words: superalloy, cooling rate, γ′ precipitates, high temperature creep, quantitative statistical characterization

中图分类号:

TG146.1⁺5

卢毓华, 王海舟, 付锐, 李福林, 李冬玲, 黄丹琪, 蔡文毅. 不同固溶冷速GH4096高温合金在高温蠕变测试中γ′相的演变行为[J]. 金属热处理, 2021, 46(9): 173-179.

Lu Yuhua, Wang Haizhou, Fu Rui, Li Fulin, Li Dongling, Huang Danqi, Cai Wenyi. Behavior of γ′ precipitates under high temperature creep of GH4096 superalloy with different solution treatment cooling rates[J]. Heat Treatment of Metals, 2021, 46(9): 173-179.

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不同固溶冷速GH4096高温合金在高温蠕变测试中γ′相的演变行为

Behavior of γ′ precipitates under high temperature creep of GH4096 superalloy with different solution treatment cooling rates

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