无磁钻铤用Cr-Mn-Ni-N系高氮钢平衡凝固相变与析出行为

doi:10.13251/j.issn.0254-6051.2022.03.033

金属热处理 ›› 2022, Vol. 47 ›› Issue (3): 173-180.DOI: 10.13251/j.issn.0254-6051.2022.03.033

无磁钻铤用Cr-Mn-Ni-N系高氮钢平衡凝固相变与析出行为

王英虎^1,2, 郑淮北^1,2, 白青青^1,2, 宋令玺^1,2, 姚斌³, 王利伟³

1.成都先进金属材料产业技术研究院股份有限公司, 四川成都 610000;
2.海洋装备用金属材料及其应用国家重点实验室, 辽宁鞍山 114009;
3.攀钢集团江油长城特殊钢有限公司, 四川江油 621704

收稿日期:2021-10-28 修回日期:2022-01-19 出版日期:2022-03-25 发布日期:2022-04-22
作者简介:王英虎(1992—),男,硕士,主要研究方向为海洋装备用特种不锈钢材料及加工技术,E-mail:hihihowareyou@163.com

Phase transformation and precipitation behavior of Cr-Mn-Ni-N high nitrogen steel for non-magnetic drilling collar during equilibrium solidification

Wang Yinghu^1,2, Zheng Huaibei^1,2, Bai Qingqing^1,2, Song Lingxi^1,2, Yao Bin³, Wang Liwei³

1. Chengdu Advanced Metal Materials Industrial Technology Research Institute Co., Ltd., Chengdu Sichuan 610000, China;
2. State Key Laboratory of Metal Material for Marine Equipment and Application, Anshan Liaoning 114009, China;
3. Pangang Group Jiangyou Changcheng Special Steel Co., Ltd., Jiangyou Sichuan 621704, China

Received:2021-10-28 Revised:2022-01-19 Online:2022-03-25 Published:2022-04-22

摘要/Abstract

摘要： 借助Thermo-Calc软件对无磁钻铤用Fe-(15~25)Cr-(15~25)Mn-(0~5)Ni-(0~1)Mo-(0~1)N-(0~0.8)C多元系高氮钢在凝固和冷却过程中的相变及析出行为进行研究。使用Thermo-Calc软件中的TCFE9数据库对该钢相图的垂直截面图进行计算,分析了Cr、Mn、Ni、Mo、N及C元素对无磁钻铤用高氮钢凝固及冷却过程中相变的影响,并得到了平衡凝固相变路径图。结果表明,增加Cr、Mn含量可显著提高合金中氮的溶解度,Mo元素可以微弱提高氮的溶解度,Ni、C元素显著降低氮的溶解度。Ni、C和N含量提高可扩大单相奥氏体相区,具有稳定奥氏体的作用,Cr、Mo与Mn元素缩小单相奥氏体相区,具有稳定铁素体的作用。N元素可以促进M₂(C,N)相析出,使M₂₃C₆相析出受到抑制。Cr、Mn元素可以促进Sigma相析出,C、N元素抑制Sigma相析出。M₂₃C₆相的析出主要受C含量的影响,随着C含量的升高,M₂₃C₆相的析出温度显著升高。

关键词: 无磁钻铤, 高氮钢, 析出行为, 相变, 凝固, 相图计算

Abstract: Phase transformation and precipitation behavior of Fe-(15-25)Cr-(15-25)Mn-(0-5)Ni-(0-1)Mo-(0-1)N-(0-0.8)C multicomponent high nitrogen steel for non-magnetic drilling collar during equilibrium solidification were investigated by using Thermo-Calc software. The vertical sections of the phase diagram for this steel were calculated by using the TCFE9 database. Effects of Cr, Mn, Ni, Mo, N and C on phase transformation of the steel during solidification and cooling were analyzed, and the equilibrium solidification phase transformation path diagram was obtained. The results show that increasing Cr and Mn contents can significantly improve the solubility of nitrogen, Mo can slightly improve it, while Ni and C can significantly reduce it. With the increase of Ni, C and N contents, the single-phase austenite phase zone can be enlarged and the austenite can be stabilized. With the increase of Cr, Mo and Mn contents, the single-phase austenite phase zone can be reduced and the ferrite can be stabilized. The nitrogen can promote the precipitation of M₂(C,N) phase and inhibit the precipitation of M₂₃C₆ phase. The Cr and Mn can promote the precipitation of sigma phase, while C and N can inhibit the precipitation of sigma phase. The precipitation of M₂₃C₆ phase is mainly affected by the content of C, and with the increase of C content, the precipitation temperature of M₂₃C₆ phase increases significantly.

Key words: non-magnetic drilling collar, high nitrogen steel, precipitation behavior, phase transformation, solidification, phase diagram calculation

中图分类号:

TG142.71

王英虎, 郑淮北, 白青青, 宋令玺, 姚斌, 王利伟. 无磁钻铤用Cr-Mn-Ni-N系高氮钢平衡凝固相变与析出行为[J]. 金属热处理, 2022, 47(3): 173-180.

Wang Yinghu, Zheng Huaibei, Bai Qingqing, Song Lingxi, Yao Bin, Wang Liwei. Phase transformation and precipitation behavior of Cr-Mn-Ni-N high nitrogen steel for non-magnetic drilling collar during equilibrium solidification[J]. Heat Treatment of Metals, 2022, 47(3): 173-180.

参考文献

[1]邹章雄, 朗宇平, 屈华鹏, 等. 无磁钻铤用Cr-Mn-N奥氏体不锈钢组织性能研究[J]. 热加工工艺, 2013, 42(18): 147-152.
Zou Zhangxiong, Lang Yuping, Qu Huapeng, et al. Research on microstructure and properties of Cr-Mn-N austenitic stainless steel for non-magnetic drilling collar application[J]. Hot Working Technology, 2013, 42(18): 147-152.
[2]张世霄, 崔岩, 屈华鹏, 等. 无磁钻铤用0Cr19Mn21Ni2N奥氏体不锈800 ℃等温时效析出机制[J]. 金属热处理, 2016, 41(9): 52-56.
Zhang Shixiao, Cui Yan, Qu Huapeng, et al. Precipitation mechanical of 0Cr19Mn21Ni2N austenitic stainless steel for non-magnetic drill collar during isothermal aging at 800 ℃[J]. Heat Treatment of Metals, 2016, 41(9): 52-56.
[3]Cordea J N, Sheth H V, Jasper J C. Development of an improved austenitic drilling collar alloy[J]. Material Performance, 1987, 26(9): 50-54.
[4]张世霄. 海洋油气钻采高氮奥氏体不锈钢加工工艺研究[D]. 唐山: 华北理工大学, 2016.
Zhang Shixiao. Research on processing technology of high nitrogen austenitic stainless steels for offshore oil gas drilling application[D]. Tangshan: North China University of Science and Technology, 2016.
[5]敖影, 周灿栋. P550奥氏体不锈钢的热变形行为研究[J]. 上海金属, 2016, 38(5): 22-26.
Ao Ying, Zhou Candong. Thermal deformation behavior of P550 austenitic stainless steel[J]. Shanghai Metals, 2016, 38(5): 22-26.
[6]屈华鹏, 郎宇平, 陈海涛. 无磁钻铤用高氮不锈钢的研究和发展[J]. 热加工工艺, 2014, 43(24): 14-18.
Qu Huapeng, Lang Yuping, Chen Haitao. Research and development on high nitrogen stainless steels used for non-magnetic drilling collar[J]. Hot Working Technology, 2014, 43(24): 14-18.
[7]吕栓录, 骆发前, 周杰, 等. 钻铤断裂原因分析[J]. 理化检验(物理分册), 2009, 45(5): 309-311, 322.
Lü Shuanlu, Luo Faqian, Zhou Jie, et al. Fracture reason analysis on drill collar[J]. Physical Testing and Chemical Analysis(Physical Testing), 2009, 45(5): 309-311, 322.
[8]吕栓录, 张宏, 许峰, 等. 石油钻铤断裂原因分析[J]. 机械工程材料, 2010, 36(6): 80-82.
Lü Shuanlu, Zhang Hong, Xu Feng, et al. Cause analysis of oil drill collar fracture[J]. Material for Mechanical Engineering, 2010, 36(6): 80-82.
[9]石锋, 崔文芳, 王立军, 等. 高氮奥氏体不锈钢研究进展[J]. 上海金属, 2006, 28(5): 45-50.
Shi Feng, Cui Wenfang, Wang Lijun, et al. Advance in the research of high-nitrogen austenitic stainless steels[J]. Shanghai Metals, 2006, 28(5): 45-50.
[10]孙征. 无磁钻铤用高氮不锈钢的研究和发展[J]. 信息记录材料, 2018, 19(4): 10-11.
[11]张增武. 无磁钻铤用高氮不锈钢TSMF166冶炼实践[J]. 炼钢, 2013, 29(4): 19-21.
Zhang Zengwu. Smelting practice of TSMF166 high-nitrogen non-magnetic steel for drill collar[J]. Steelmaking, 2013, 29(4): 19-21.
[12]Shankar P, Sundararaman D, Ranganathan S. Clustering and ordering of nitrogen in nuclear grade 316LN austenitic stainless steel[J]. Journal of Nuclear Materials, 1998, 254(1): 1-8.
[13]Briant C L, Hall E L. A comparision between grain boundary chromium depletion in austenitic stainless steel and corrosion in the modified strauss test[J]. Corrosion, 1986, 42(9): 522-531.
[14]房菲, 李静媛, 王一德. 含氮不锈钢凝固模式及显微组织研究[J]. 北京科技大学学报, 2014(11): 1490-1496.
Fang Fei, Li Jingyuan, Wang Yide. Solidification mode and microstructure of nitrogenous stainless steels[J]. Journal of University of Science and Technology Beijing, 2014(11): 1490-1496.
[15]房菲, 李静媛, 王一德. 18Mn18Cr 高氮钢析出相特征及形成机制[J]. 北京科技大学学报, 2014(6): 768-779.
Fang Fei, Li Jingyuan, Wang Yide. Characteristics and forming mechanism of precipitates in 18Mn18Cr high nitrogen steel[J]. Journal of University of Science and Technology Beijing, 2014(6): 768-779.
[16]Okazaki Y, Miyyahara K, Wade N, et al. Effect of manganese and chromium on microstructure and toughness of Fe-Cr-Mn alloys resulting from solid-solution treatment[J]. Journal of the Japan Institute of Metals, 1989, 53(5): 502-511.
[17]Franks R, Binder W O, Thampson J. Austenitic chromium-manganese-nickel steels containing nitrogen[J]. Transaction of the American Society for Metals, 1955, 47: 231-263.
[18]张玉碧, 刘海定, 王东哲, 等. 一种含氮Cr-Ni型奥氏体不锈钢的工艺设计与热处理研究[J]. 热加工工艺, 2016, 45(18): 177-181, 187.
Zhang Yubi, Liu Haiding, Wang Dongzhe, et al. Process design and heat treatment research of a nitrogen-containing Cr-Ni type austenitic stainless steel[J]. Hot Working Technology, 2016, 45(18): 177-181, 187.

无磁钻铤用Cr-Mn-Ni-N系高氮钢平衡凝固相变与析出行为

Phase transformation and precipitation behavior of Cr-Mn-Ni-N high nitrogen steel for non-magnetic drilling collar during equilibrium solidification

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	王英虎, 郑淮北, 刘庭耀, 宋令玺, 白青青. 固溶处理对53Cr21Mn9Ni4N耐热钢组织及碳化物的影响[J]. 金属热处理, 2022, 47(4): 39-45.
[2]	王云龙, 余伟, 张昳, 史佳新, 李明辉. 奥氏体化温度对贝氏体钢等温转变及力学性能的影响[J]. 金属热处理, 2022, 47(4): 80-85.
[3]	吕金峄, 张义伟, 罗小兵, 袁晓敏. 含铜钢奥氏体连续冷却组织转变特性的原位观察[J]. 金属热处理, 2022, 47(1): 19-24.
[4]	王英虎, 郑淮北, 宋令玺, 白青青, 姚斌, 王利伟. 无磁钻铤用0Cr19Mn21Ni2N高氮钢的高温塑性变形行为[J]. 金属热处理, 2022, 47(1): 113-119.
[5]	杜鹏举, 吴迪. 中锰钢中原奥氏体晶粒尺寸对马氏体相变的影响[J]. 金属热处理, 2021, 46(9): 21-27.
[6]	王晓东, 陈蕴博, 左玲立, 游龙, 陈冲, 毛丰, 张峻嘉. V-N微合金化CrSiMn系低合金铸钢中的析出行为[J]. 金属热处理, 2021, 46(8): 15-19.
[7]	杨晓伟, 陈焕德, 周云, 张宇. 轧制工艺对V-Nb微合金化HRB600E钢筋组织及性能的影响[J]. 金属热处理, 2021, 46(8): 150-155.
[8]	张楠, 李岩, 定巍. 0.2C-5Mn-0.5Si-2.5Al中锰钢临界退火后的微观组织及力学性能[J]. 金属热处理, 2021, 46(7): 37-42.
[9]	张梅, 孙国胜, 秦岽烊, 杜林秀. 冷轧304不锈钢的马氏体逆相变及奥氏体再结晶行为[J]. 金属热处理, 2021, 46(7): 51-55.
[10]	高天宇, 乔珺威, 吴玉程. FeMnCoCr系亚稳高熵合金的研究进展[J]. 金属热处理, 2021, 46(4): 1-8.
[11]	刘洁, 徐乐, 何肖飞, 李晓源, 王毛球. Ti微合金化非调质钢中碳化物析出行为及其对再结晶的影响[J]. 金属热处理, 2021, 46(4): 9-15.
[12]	吕冠辰, 梁文雷, 索玉松, 李磊. Sn-Co合金热处理过程中的CoSn₂→CoSn₄相变[J]. 金属热处理, 2021, 46(4): 16-19.
[13]	梁静宇, 石增敏, 谢镐, 邓李辰贵, 李光宇, 戴雷. 汽车用超高强度钢的合金化方式及组织控制[J]. 金属热处理, 2021, 46(4): 20-25.
[14]	赵锴, 杨忠民, 李佳蕊, 陈颖, 曹燕光, 李昭东. 热处理工艺对Fe-15Mn-4.5Si-10Cr-5Ni系形状记忆合金析出相及形状记忆性能的影响[J]. 金属热处理, 2021, 46(12): 7-12.
[15]	李鹏涛, 刘金旺, 罗贤, 陈建新. 生物医用316L奥氏体不锈钢的形变组织[J]. 金属热处理, 2021, 46(12): 162-167.