Ni-WB2复合熔覆层的微观组织及摩擦磨损性能

doi:10.13251/j.issn.0254-6051.2023.01.037

金属热处理 ›› 2023, Vol. 48 ›› Issue (1): 207-216.DOI: 10.13251/j.issn.0254-6051.2023.01.037

Ni-WB₂复合熔覆层的微观组织及摩擦磨损性能

刘凌波¹, 杨贵荣¹, 宋文明², 李亚敏¹, 马颖¹

1.兰州理工大学省部共建有色金属先进加工与再利用国家重点实验室, 甘肃兰州 730050;
2.甘肃蓝科高新石化装备股份有限公司, 甘肃兰州 730070

收稿日期:2022-08-19 修回日期:2022-11-03 出版日期:2023-01-25 发布日期:2023-02-03
通讯作者: 杨贵荣,教授,博士生导师,E-mail: yanggrming@lut.cn
作者简介:刘凌波(1994—),助理工程师,硕士,主要研究方向为金属表面功能材料的制备与摩擦磨损性能研究,E-mail:1597300831@qq.com。
基金资助:
国家自然科学基金(51765035, 51205178);辽宁省航发材料摩擦学重点实验室开放课题(LKLAMTF202201)

Microstructure and wear performance of Ni-WB₂ composite clad layer

Liu Lingbo¹, Yang Guirong¹, Song Wenming², Li Yamin¹, Ma Ying¹

1. State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals, Lanzhou University of Technology, Lanzhou Gansu 730050, China;
2. Lanpec Technologies Co., Ltd., Lanzhou Gansu 730070, China

Received:2022-08-19 Revised:2022-11-03 Online:2023-01-25 Published:2023-02-03

摘要/Abstract

摘要： 利用真空熔覆技术在45钢表面制备了Ni-WB₂复合熔覆层,利用SEM、EDS、XRD等分析其组织特征,利用销盘式摩擦试验机对其摩擦磨损性能进行了测试与分析。结果表明,Ni-WB₂复合熔覆层组织致密并与基体呈牢固的冶金熔合,熔覆层具有特殊的分层结构,分为网状结构层、过渡结构层和扩散熔合层,网状复合区又分为网状Ⅰ区和网状Ⅱ区。扩散区主要由铁基固溶体和镍基固溶体构成,过渡区的主要组成相为γ-Ni及Cr的碳化物,网状复合区的主要组成相有镍基合金、铬碳化物、WB₂、镍硅共晶以及WB₂与镍基合金中的元素形成的复杂硼化物和碳化物。当WB₂含量低于20%时,随着WB₂在复合熔覆层中含量的增加,其磨损率及摩擦因数均逐渐降低,当WB₂含量为15%时,Ni-WB₂复合熔覆层的磨损率及摩擦因数与基体相比,分别降低了48.94%与14.62%。网状分布的硬质相在摩擦过程中起到支撑载荷的作用,摩擦磨损过程中形成了WO_x氧化物,均有利于降低复合熔覆层的摩擦磨损。

关键词: 真空熔覆, Ni-WB₂复合熔覆层, 网状复合层, 摩擦磨损行为

Abstract: Ni-WB₂ composite clad layer was prepared on the 45 steel substrate through vacuum cladding technology. The microstructure of the clad layer was characterized by means of SEM, EDS and XRD, and wear performance was studied by using pin-disc type wear apparatus. The results show that the Ni-WB₂ composite clad layer is dense, and a strong metallurgical bond formed at the interface between the clad layer and the substrate. The clad layer can be subdivided into reticular zone, transition zone and diffusion zone based on its microstructure, and the reticular composite zone is divided into area Ⅰ and area Ⅱ. The diffusion zone is mainly composed of Fe-based solid solution and Ni-based solid solution. The main phases of the transition zone are γ-Ni and chromium carbide, and the main compositions of the reticular composite zone are Ni-based alloy, chromium carbide, WB₂, nickel silicon eutectic and complex comppund formed owing to the chemical combination between the WB₂ and elements of nickel-based alloy. When the WB₂ content is lower than 20%, both the wear rate and friction factor of the Ni-WB₂ composite clad layer decrease gradually with the increase of WB₂ content. When the WB₂ content is 15%, the wear rate and friction factor of Ni-WB₂ composite clad layer decrease by 48.94% and 14.62% respectively compared with that of the 45 steel substrate. During the wear process, the load supporting effect of the hard phase with network distribution and the formation of WO_x oxide are conducive to reduce the friction and wear of the Ni-WB₂ composite clad layer.

Key words: vacuum cladding technology, Ni-WB₂ composite clad layer, network composite coating, friction and wear behavior

中图分类号:

TG178

刘凌波, 杨贵荣, 宋文明, 李亚敏, 马颖. Ni-WB₂复合熔覆层的微观组织及摩擦磨损性能[J]. 金属热处理, 2023, 48(1): 207-216.

Liu Lingbo, Yang Guirong, Song Wenming, Li Yamin, Ma Ying. Microstructure and wear performance of Ni-WB₂ composite clad layer[J]. Heat Treatment of Metals, 2023, 48(1): 207-216.

参考文献

[1]Sahai B. Engineering applications of remote sensing[J]. Journal of the Indian Society of Remote Sensing, 1989, 17(4): 1-8.
[2]Funatani K. Emerging technology in surface modification of light metals[J]. Surface and Coatings Technology, 2000, 133-134: 264-272.
[3]Wu Xiaolei. Rapidly solidified nonequilibrium microstructure and phase transformation of laser-synthesized iron-based alloy coating[J]. Surface and Coatings Technology, 1999, 115(2/3): 153-162.
[4]De Mol Van Otterloo J L, De Hosson J Th M. Microstructure and abrasive wear of cobalt-based laser coatings[J]. Scripta Materialia, 1997, 36(2): 239-245.
[5]Pelletier J M, Sallamand P, Criqui B. Microstructure and mechanical properties of some metal matrix composites coatings by laser cladding[J]. Journal De Physique IV, 1994, 4: 93-96.
[6]梁秀兵, 程江波, 徐滨士, 等. 铁基非晶涂层的研究进展[J]. 材料工程, 2017, 45(9): 1-12.
Liang Xiubing, Cheng Jiangbo, Xu Binshi, et al. Research progress on Fe-based amorphous coatings[J]. Journal of Materials Engineering, 2017, 45(9): 1-12.
[7]张帅, 刘福朋, 戴万祥, 等. 镍基涂层耐磨损性耐腐蚀性的研究现状[J]. 热加工工艺, 2020, 49(10): 16-19.
Zhang Shuai, Liu Fupeng, Dai Wanxiang, et al. Research status of wear resistance and corrosion resistance of nickel-based coatings[J]. Hot Working Technology, 2020, 49(10): 16-19.
[8]Feng S Q, Guo F, Li J Y, et al. Theoretical investigations of physical stability, electronic properties and hardness of transition-metal tungsten borides WB_x(x=2.5, 3)[J]. Chemical Physics Letters, 2015, 635: 205-209.
[9]Sun Shibo, Wang Haibin, Liu Xuemei, et al. Outstanding anti-oxidation performance of boride coating under high-temperature friction[J]. Corrosion Science, 2020, 179: 109-133
[10]Torkamani A D, Velashjerdi M, Abbas A, et al. Electrodeposition of nickel matrix composite coatings via various boride particles: A review[J]. Journal of Composites and Compounds, 2021, 3(7): 106-113.
[11]Sokeng I T, Ngom B D, Msimanga M, et al. Coatings synthesized by the pulsed laser ablation of a B₄C/W₂B₅ ceramic composite[J]. Thin Solid Films, 2015, 593(10): 5-9.
[12]Liu Y, Tian L, Chang J, et al. Effect of modulation ratio on structure and mechanical properties of WB₂/CrN films deposited by direct-current magnetron sputtering[J]. Journal of Alloys and Compounds, 2020, 851: 156852.
[13]Jiang C, Pei Z, Liu Y, et al. Preparation and characterization of superhard AlB₂-type WB₂nano-composite coatings[J]. Physica Status Solidi, 2013, 210(6): 1221-1227.
[14]Qin M, Gild J, Wang H, et al. Dissolving and stabilizing soft WB₂ and MoB₂ phases into high-entropy borides via boron-metals reactive sintering to attain higher hardness[J]. Journal of the European Ceramic Society, 2020, 40(12): 4348-4353.
[15]Fuger C, Schwartz B, Wojcik T, et al. Influence of Ta on the oxidation resistance of WB_2-zcoatings[J]. Journal of Alloys and Compounds, 2021, 864: 158121
[16]Habig K H. 材料的磨损与硬度[M]. 严立, 译. 北京: 机械工业出版社, 1987: 146-150.
[17]Wang Q, Lu Y, Yu Q, et al. The exceptional strong face-centered cubic phase and semi-coherent phase boundary in a eutectic dual-phase high entropy alloy AlCoCrFeNi[J]. Scientific Reports, 2018, 8(1): 1-7.
[18]Lugscheider E, Rwulf S, Barimani C. Properties of tungsten and vanadium oxides deposited by MSIP-PVD process for self-lubricating applications[J]. Surface and Coatings Technology, 1999, 121(1): 458-464.
[19]Zheng Haidong, Ou Jianzhen, Michael S, et al. Nanostructured tungsten oxide -Properties, synthesis, and applications[J]. Advanced Functional Materials, 2011, 21(12): 2175-2196.
[20]熊党生, 李建亮. 高温摩擦磨损与润滑[M]. 西安: 西北工业大学出版社, 2013. 230-231.

Ni-WB₂复合熔覆层的微观组织及摩擦磨损性能

Microstructure and wear performance of Ni-WB₂ composite clad layer

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