NiTi基轴承合金研究进展

doi:10.13251/j.issn.0254-6051.2023.12.039

摘要/Abstract

摘要： 高Ni含量的NiTi基合金凭借其高硬度、低弹性模量、耐蚀性能以及无磁性等特点而成为一类重要的轴承合金。全面阐述了国内外在NiTi基轴承合金研究方面的进展,主要包括微观组织、力学性能、摩擦磨损特性与耐腐蚀特性等,重点介绍了热处理工艺、合金元素对合金性能的影响,探讨了NiTi基轴承合金今后的研究重点。

关键词: NiTi基合金, 微观组织, 硬度, 摩擦磨损

Abstract: NiTi-based alloys with higher Ni content have become an important bearing alloy because of their high hardness, low elastic modulus, good corrosion resistance and nonmagnetic, etc. In present work, recent progress of NiTi-based bearing alloys is comprehensively overviewed, mainly including microstructure, mechanical properties, frictional wear properties and corrosion resistance. The emphasis is laid on the effect of heat treatment and alloying element on mechanical properties of alloys. Some important issues on NiTi-based bearing alloys are discussed.

Key words: NiTi-based alloys, microstructure, hardness, friction and wear

中图分类号:

TB37

官磊, 刘嘉兴, 孙士博, 佟运祥. NiTi基轴承合金研究进展[J]. 金属热处理, 2023, 48(12): 236-243.

Guan Lei, Liu Jiaxing, Sun Shibo, Tong Yunxiang. Research progress of NiTi-based bearing alloys[J]. Heat Treatment of Metals, 2023, 48(12): 236-243.

参考文献

[1]Otsuka K, Ren X. Physical metallurgy of Ti-Ni-based shape memory alloys[J]. Progress in Materials Science, 2005, 50(5): 511-678.
[2]Mohd Jani J, Leary M, Subic A, et al. A review of shape memory alloy research, applications and opportunities[J]. Materials and Design, 2014, 56: 1078-1113.
[3]Tong Y, Shuitcev A, Zheng Y. Recent development of TiNi-based shape memory alloys with high cycle stability and high transformation temperature[J]. Advanced Engineering Materials, 2020, 22(4): 1900496.
[4]Buehler W J, Wang F E. A summary of recent research on the nitinol alloys and their potential application in ocean engineering[J]. Ocean Engineering, 1968, 1(1): 105-120.
[5]Dellacorte C, Pepper S V, Noebe R, et al. Nickel-titanium: A new candidate material for oil-lubricated bearing and mechanical component applications[C]//World Tribology Congress 2009, 2009: 353.
[6]Dellacorte C. Nickel-Titanium alloys: Corrosion “proof” alloys for space bearing, components and mechanism applications[R]. NASA/TM-2010-216334, NASA Glenn Research Center, Cleveland, 2010.
[7]张家华, 肖飞, 王建中, 等. 航天轴承新贵: 60NiTi 合金[J]. 金属热处理, 2021, 46(6): 1-7.
Zhang Jiahua, Xiao Fei, Wang Jianzhong, et al. New material for aerospace bearing: 60NiTi alloy[J]. Heat Treatment of Metals, 2021, 46(6): 1-7.
[8]Khanlari K, Ramezani M, Kelly P. 60NiTi: A review of recent research findings, potential for structural and mechanical applications, and areas of continued investigations[J]. Transactions of the Indian Institute of Metals, 2018, 71(4): 781-799.
[9]燕超, 曾群锋, 杨华斌. 新型超弹性轴承材料TiNi60 合金的研究进展[J]. 中国有色金属学报, 2020, 30(5): 1038-1048.
Yan Chao, Zeng Qunfeng, Yang Huabin. Research progress of new superelastic bearing material TiNi60 alloy[J]. The Chinese Journal of Nonferrous Metals, 2020, 30(5): 1038-1048.
[10]Hornbuckle B C, Noebe R D, Thompson G B. Influence of Hf solute additions on the precipitation and hardenability in Ni-rich NiTi alloys[J]. Journal of Alloys and Compounds, 2015, 640: 449-454.
[11]Chen H, Zheng L J, Zhang F X, et al. Thermal stability and hardening behavior in superelastic Ni-rich Nitinol alloys with Al addition[J]. Materials Science and Engineering: A, 2017, 708: 514-522.
[12]Zhang F, Zheng L, Wang F, et al. Effects of Nb additions on the precipitate morphology and hardening behavior of Ni-rich Ni₅₅Ti₄₅ alloys[J]. Journal of Alloys and Compounds, 2018, 735: 2453-2461.
[13]Yuan K J, Wang Y, Zheng L J, et al. Microstructural evolution, mechanical properties, and oxidation performance of highly Ni-rich NiTi alloys with added V using vacuum arc melting[J]. Journal of Alloys and Compounds, 2021, 877: 160263.
[14]Tong Y X, Liu J X, Sun S B, et al. Unusual precipitation and its hardness enhancement in Fe-alloyed 60NiTi alloy[J]. Materials Letters, 2022, 329: 133170.
[15]Fan G L, Chen W, Yang S, et al. Origin of abnormal multi-stage martensitic transformation behavior in aged Ni-rich Ti-Ni shape memory alloys[J]. Acta Materialia, 2004, 52(14): 4351-4362.
[16]Wang X, Kustov S, Li K, et al. Effect of nanoprecipitates on the transformation behavior and functional properties of a Ti-50.8at.%Ni alloy with micron-sized grains[J]. Acta Materialia, 2015, 82: 224-233.
[17]Nishida M, Wayman C M, Kainuma R, et al. Further electron microscopy studies of the Ti₁₁Ni₁₄ phase in an aged Ti-52at.%Ni shape memory alloy[J]. Scripta Metallurgica, 1986, 20(6): 899-904.
[18]Saburi T, Nenno S, Fukuda T. Crystal Structure and morphology of the metastable X phase in shape memory Ti-Ni alloys[J]. Journal of the Less-Common Metals, 1986, 125: 157-166.
[19]Hara T, Ohba T, Otsuka K, et al. Phase transformation and crystal structures of Ti₂Ni₃ precipitates in TiNi alloys[J]. Materials Transactions, JIM, 1997, 38(4): 277-284.
[20]Taylor A, Floyo R W. Precision measurements of lattice parameters of Non-cubic crystals[J]. Acta Crystallographica, 1950, 3: 285-289.
[21]Adharapurapu R R. Phase transformations in nickel-rich nickel-titanium alloys: Influence of strain-rate, temperature, thermomechanical treatment and nickel composition on the shape memory and superelastic characteristics[D]. San Diego: University of California, 2007.
[22]Hornbuckle B C, Yu X X, Noebe R D, et al. Hardening behavior and phase decomposition in very Ni-rich Nitinol alloys[J]. Materials Science and Engineering A, 2015, 639: 336-344.
[23]Nishida M, Wayman C M, Honma T. Precipitation processes in near-equiatomic TiNi shape memory alloys[J]. Metallurgical Transactions A, 1986, 17(9): 1505-1515.
[24]Zhou J, Wang C, Fu Y C, et al. Study on the microstructure and mechanical properties of 60NiTi alloy quenched by hot oil[J]. Metals, 2022, 12(9): 1513.
[25]Xu G X, Zheng L J, Zhang F X, et al. Influence of solution heat treatment on the microstructural evolution and mechanical behavior of 60NiTi[J]. Journal of Alloys and Compounds, 2019, 775: 698-706.
[26]杜志伟, 彭永刚, 韩小磊, 等. NiTi40 合金微观组织结构的电子显微学分析[J]. 中国有色金属学报, 2020, 30(3): 587-594.
Du Zhiwei, Peng Yonggang, Han Xiaolei, et al. Electron microscopic analysis of microstructure of NiTi40 alloy[J]. The Chinese Journal of Nonferrous Metals, 2020, 30(3): 587-594.
[27]Adharapurapu R R, Jiang F, Vecchio K S. Aging effects on hardness and dynamic compressive behavior of Ti-55Ni (at.%) alloy[J]. Materials Science and Engineering A, 2010, 527(7-8): 1665-1676.
[28]Waqar S, Wadood A, Mateen A, et al. Effects of Ni and Cr addition on the wear performance of NiTi alloy[J]. The International Journal of Advanced Manufacturing Technology, 2020, 108(3): 625-634.
[29]Han X D, Wang R, Zhang Z, et al. A new precipitate phase in a TiNiHf high temperature shape memory alloy[J]. Acta Materialia, 1998, 46(1): 273-281.
[30]Karaca H E, Saghaian S M, Ded G, et al. Effects of nanoprecipitation on the shape memory and material properties of an Ni-rich NiTiHf high temperature shape memory alloy[J]. Acta Materialia, 2013, 61(19): 7422-7431.
[31]Zhang F, Zheng L, Wang Y, et al. Effect of Ni content and Hf addition on the unlubricated wear performance of Ni-rich NiTi alloys[J]. Intermetallics, 2019, 112: 106548.
[32]Mills S H, Noebe R D, Dellacorte C, et al. Development of nickel-rich nickel-titanium-hafnium alloys for tribological applications[J]. Shape Memory and Superelasticity, 2020, 6(3): 311-322.
[33]Khanlari K, Shi Q, Li K, et al. Development of hardening treatments for 58Ni39Ti-3Hf alloy system as compared to baseline 60NiTi[J]. Intermetallics, 2021, 137: 107282.
[34]Yang F, Coughlin D R, Phillips P J, et al. Structure analysis of a precipitate phase in an Ni-rich high-temperature NiTiHf shape memory alloy[J]. Acta Materialia, 2013, 61(9): 3335-3346.
[35]Zhang F, Zheng L, Wang F, et al. Effects of Hf additions on the microstructures and mechanical properties of Ni-rich Ni₅₅Ti₄₅ alloys[J]. Materials Science and Engineering A, 2021, 815: 141263.
[36]Mills S H, Dellacorte C, Noebe R D, et al. Heat treatment-microstructure-hardness relationships of new nickel-rich nickel-titanium-hafnium alloys developed for tribological applications[J]. Materialia, 2021, 16: 101064.
[37]Benefan O, Grag A, Noebe R D, et al. Deformation characteristics of the intermetallic alloy 60NiTi[J]. Intermetallics, 2017, 82: 40-52.
[38]Kaya I. Shape memory and transformation behavior of high strength 60NiTi in compression[J]. Smart Materials and Structures, 2016, 25(12): 125031.
[39]Casalena L, Bucsek A N, Pagan D C, et al. Structure-property relationships of a high strength superelastic NiTi-1Hf alloy[J]. Advanced Engineering Materials, 2018, 20(9): 1800046.
[40]Li B, Xu G X, Zheng L J, et al. Dependence of microstructure and mechanical properties of 60NiTi alloy on aging conditions[J]. Materials Science and Engineering A, 2022, 840: 142903.
[41]Liu R, Li D Y. Modification of Archard’s equation by taking account of elastic/pseudoelastic properties of materials[J]. Wear, 2001, 251(1): 956-964.
[42]Li D Y. A new type of wear-resistant material: Pseudo-elastic TiNi alloy[J]. Wear, 1998, 221(2): 116-123.
[43]Lin H C, Wu S K, Yeh C H. A comparison of slurry erosion characteristics of TiNi shape memory alloys and SUS304 stainless steel[J]. Wear, 2001, 249(7): 557-565.
[44]Zeng Q F, Zhao X M, Dong G N, et al. Lubrication properties of Nitinol 60 alloy used as high-speed rolling bearing and numerical simulation of flow pattern of oil-air lubrication[J]. Transactions of Nonferrous Metals Society of China (English Edition), 2012, 22(10): 2431-2438.
[45]Liu J X, Sun S B, Chen F, et al. High temperature wear behavior of Ni-rich NiTi-based alloys[J]. Journal of Materials Research and Technology, 2022, 20: 440-447.
[46]Nasehi J, Ghasemi H M, Abedini M. Effects of aging treatments on the high-temperature wear behavior of 60Nitinol alloy[J]. Tribology Transactions, 2016, 59(2): 286-291.
[47]Khanlari K, Ramezani M, Kelly P, et al. Comparison of the reciprocating sliding wear of 58Ni39Ti-3Hf alloy and baseline 60NiTi[J]. Wear, 2018, 408-409: 120-130.
[48]Khanlari K, Ramezani M, Kelly P, et al. Reciprocating sliding wear behavior of 60NiTi as compared to 440C steel under lubricated and unlubricated conditions[J]. Tribology Transactions, 2018, 61(6): 991-1002.
[49]Khanlari K, Ramezani M, Kelly P, et al. An investigation on reasons causing inferiority in unlubricated sliding wear performance of 60NiTi as compared to 440C steel[J]. Tribology Transactions, 2019, 62(1): 96-109.
[50]Zeng Q, Dong G. Influence of load and sliding speed on super-low friction of nitinol 60 alloy under castor oil lubrication[J]. Tribology Letters, 2013, 52(1): 47-55.
[51]Zeng Q F, Dong G N. Superlubricity behaviors of Nitinol 60 alloy under oil lubrication[J]. Transactions of Nonferrous Metals Society of China (English Edition), 2014, 24(2): 354-359.
[52]Walters N, Martini A. Friction dependence on surface roughness for castor oil lubricated NiTi alloy sliding on steel[J]. Tribology Transactions, 2018, 61(6): 1162-1166.
[53]Yan C, Zeng Q, Hao Y, et al. Friction-induced hardening behaviors and tribological properties of 60NiTi alloy lubricated by lithium grease containing nano-BN and MoS₂[J]. Tribology Transactions, 2019, 62(5): 812-820.
[54]Robin A, Meirelis J P. Influence of fluoride concentration and pH on corrosion behavior of titanium in artificial saliva[J]. Journal of Applied Electrochemistry, 2007, 37(4): 511-517.
[55]Qin Q, Wen Y, Wang G, et al. Effects of solution and aging treatments on corrosion resistance of as-cast 60NiTi alloy[J]. Journal of Materials Engineering and Performance, 2016, 25(12): 5167-5172.
[56]Zhang L, Peng H, Qin Q, et al. Effects of annealing on hardness and corrosion resistance of 60NiTi film deposited by magnetron sputtering[J]. Journal of Alloys and Compounds, 2018, 746: 45-53.
[57]Guo F, Shen H, Xiong Z, et al. Selective laser melting of 60NiTi alloy with superior wear resistance[J]. Metals, 2022, 12(4): 620.
[58]Mills S H, Dellacorte C, Noebe R D, et al. Rolling contact fatigue deformation mechanisms of nickel-rich nickel-titanium-hafnium alloys[J]. Acta Materialia, 2021, 209: 116784.
[59]Zhou Y, Chen Z, Hu Z, et al. Tribological performance of hydrogenated diamond-like carbon coating deposited on superelastic 60NiTi alloy for aviation self-lubricating spherical plain bearings[J]. Chinese Journal of Aeronautics, 2022, 35(12): 309-320.