变形条件和冷却速率对低碳含Nb钢的相变及纳米析出的影响

doi:10.13251/j.issn.0254-6051.2023.02.017

金属热处理 ›› 2023, Vol. 48 ›› Issue (2): 110-116.DOI: 10.13251/j.issn.0254-6051.2023.02.017

变形条件和冷却速率对低碳含Nb钢的相变及纳米析出的影响

刘彦强¹, 杨浩², 张志军¹, 贾书君³, 韩鹏彪⁴

1.河钢集团舞钢公司, 河南平顶山 462500;
2.河钢材料院, 河北石家庄 050018;
3.钢铁研究总院有限公司工程用钢研究所, 北京 100081;
4.河北科技大学材料科学与工程学院, 河北石家庄 050018

收稿日期:2022-09-02 修回日期:2022-12-12 出版日期:2023-02-25 发布日期:2023-03-22
通讯作者: 杨浩,高级工程师,博士,E-mail:yanghao1006@126.com
作者简介:刘彦强(1983—),男,工程师,主要研究方向为钢铁材料组织性能,E-mail: 187219435@qq.com。
基金资助:
河北省省级科技计划(19211007D)

Effect of deformation and cooling rate on transformation characteristic and nanoscale precipitation in a low carbon Nb micro-alloyed steel

Liu Yanqiang¹, Yang Hao², Zhang Zhijun¹, Jia Shujun³, Han Pengbiao⁴

1. HBIS Group Wusteel Company, Pingdingshan Henan 462500, China;
2. HBIS Materials Technology Research Institute, Shijiazhuang Heibei 050018, China;
3. Institute of Structural Steels, Central Iron and Steel Research Institute Co., Ltd., Beijing 100081, China;
4. School of Materials Science and Engineering, Hebei University of Scienceand Technology, Shijiazhuang Heibei 050018, China

Received:2022-09-02 Revised:2022-12-12 Online:2023-02-25 Published:2023-03-22

摘要/Abstract

摘要： 利用Gleeble 3800热模拟试验机,研究了奥氏体再结晶和未再结晶组织对低碳含Nb钢连续冷却转变行为的影响,并对不同变形温度及冷却速率下Nb(C, N)的纳米析出行为进行了研究。结果表明,未再结晶区奥氏体的变形能够为多边形铁素体提供更多的相变形核点,扩大铁素体相变区,并且能够细化铁素体晶粒;相比于再结晶区1050 ℃单道次变形,未再结晶区的第二道次变形能够促进Nb(C, N)的析出,其中910 ℃变形时Nb(C, N)的析出量最多,850 ℃次之;冷却速率的增大能够抑制Nb(C, N)在奥氏体中的析出,但能够促进其在铁素体中析出;对于本试验钢,10 ℃/s的冷却速率即可抑制Nb(C, N)的析出;Nb(C, N)的析出粒子平均粒径随着冷却速率的增加而减小。

关键词: 低碳含Nb钢, 形变, 冷却速率, 相变, 纳米析出

Abstract: Effects of austenite recrystallization and unrecrystallization structure on continuous cooling transformation behavior of low carbon Nb micro-alloyed steel were studied by Gleeble 3800 thermal simulator, and the nano precipitation behavior of Nb(C,N) at different deformation temperatures and cooling rates was analyzed. It is found that the plastic deformation in un-recrystallization region of austenite accelerates the ferrite transformation and the ferrite transformation zone is enlarged. The deformation also refines the ferrite grain size. Compared with the single-pass deformation at recrystallizing 1050 ℃, the second deformation in the unrecrystallized zone can promote the precipitation of Nb(C, N), and the precipitation of Nb(C, N) at 910 ℃ is the largest, followed by that at 850 ℃. The increase of cooling rate can inhibit the precipitation of Nb(C, N) in austenite, but can promote its precipitation in ferrite. And the size of precipitates is refined with the increase of cooling rate. When the cooling rate reaches 10 ℃/s, the nucleation of precipitation is totally inhibited during cooling process.

Key words: Nb micro-alloyed steel, deformation, cooling rate, phase transformation, nano precipitation

中图分类号:

TG142

刘彦强, 杨浩, 张志军, 贾书君, 韩鹏彪. 变形条件和冷却速率对低碳含Nb钢的相变及纳米析出的影响[J]. 金属热处理, 2023, 48(2): 110-116.

Liu Yanqiang, Yang Hao, Zhang Zhijun, Jia Shujun, Han Pengbiao. Effect of deformation and cooling rate on transformation characteristic and nanoscale precipitation in a low carbon Nb micro-alloyed steel[J]. Heat Treatment of Metals, 2023, 48(2): 110-116.

参考文献

[1]Wang Zhaodong, Wang Bingxing, Wang Bin, et al. Development and application of thermo-mechanical control process involving ultra-fast cooling technology in China[J]. ISIJ International, 2019, 59(12): 2131-2141.
[2]Wang Xin, Li Zhaodong, Zhou Shitong, et al. Precipitation behavior of Ti-Nb-V-Mo quaternary microalloyed high strength fire-resistant steel and its influence on mechanical properties[J]. Materials Science and Engineering A, 2021, 807(11): 140865-140867.
[3]陈剑, 李余飞, 赵永桥, 等. Nb微合金钢中析出相演变过程研究[J]. 上海金属, 2016, 38(5): 12-16.
Chen Jian, Li Yufei, Zhao Yongqiao, et al. Research on the evolution process of precipitated phase in Nb-microalloyed steel[J]. Shanghai Metals, 2016, 38(5): 12-16.
[4]周晓光, 曾才有, 徐少华, 等. 控制冷却对含Nb钢组织性能的影响研究[J]. 机械工程学报, 2014, 50(22): 57-62.
Zhou Xiaoguang, Zeng Caiyou, Xu Shaohua, et al. Effect of controlling cooling on microstructure and mechanical properties for Nb bearing steel[J]. Journal of Mechanical Engineering, 2014, 50(22): 57-62.
[5]Yu Ping, Song Renbo, Xiong Wenming, et al. Phase transformation law of Nb microalloyed steel at different cooling rates[J]. Materials Science Forum, 2021, 6114: 396-403.
[6]Zhou Xiaoguang, Wang Meng, Liu Zhenyu, et al. Precipitation behavior of Nb in steel under ultra fast cooling conditions[J]. Journal of Wuhan University of Technology (Materials Science), 2015, 30(2): 375-379.
[7]韩毅, 商艳, 韩庆生, 等. 汽车车轮用低碳Nb微合金钢中的析出行为研究[J]. 金属热处理, 2009, 34(8): 52-56.
Han Yi, Shang Yan, Han Qingsheng, et al. Precipitation in low carbon steel microalloyed with Nb for automotive wheel[J]. Heat Treatment of Metals, 2009, 34(8): 52-56.
[8]李小琳, 王昭东, 邓想涛, 等. Nb元素对含Ti低碳微合金钢连续冷却转变及析出行为的影响[J]. 轧钢, 2016, 33(1): 5-9.
Li Xiaolin, Wang Zhaodong, Deng Xiangtao, et al. Effect of Nb on continuous cooling transformation process and precipitation behaviors of the Ti-bearing low-carbon steel[J]. Steel Rolling, 2016, 33(1): 5-9.
[9]庞启航, 唐荻, 赵征志, 等. 析出相对Nb-V-Ti微合金钢显微组织和性能的影响[J]. 华南理工大学学报(自然科学版), 2016, 44(2): 133-139.
Pang Qihang, Tang Di, Zhao Zhengzhi, et al. Effect of precipitation phase on microstructure and properties of Nb-V-Ti micro-alloyed steel[J]. Journal of South China University of Technology(Natural Science Edition), 2016, 44(2): 133-139.
[10]李殿杰, 贾书君, 胡日荣, 等. Nb对抗大变形管线钢铁素体相变的影响[J]. 金属热处理, 2017, 42(6): 161-165.
Li Dianjie, Jia Shujun, Hu Rirong, et al. Effect of niobium on ferrite transformation of high-strain pipeline steel[J]. Heat Treatment of Metals, 2017, 42(6): 161-165.
[11]魏同锋, 甘立建, 王启迪. Nb对低碳微合金钢组织与性能的影响[J]. 热加工工艺, 2015, 44(14): 126-128.
Wei Tongfeng, Gan Lijian, Wang Qidi. Effect of Nb on microstructure and properties of low-carbon microalloyed steel[J]. Hot Working Technology, 2015, 44(14): 126-128.
[12]Olasolo M, Uranga P, Rodriguez-Ibabe J M, et al. Effect of austenite microstructure and cooling rate on transformation characteristics in a low carbon Nb-V microalloyed steel[J]. Materials Science and Engineering A, 2011, 528(6): 2559-2569.
[13]Zrniík J, Kvackaj T, Pongpaybul A, et al. Effect of thermomechanical processing on the microstructure and mechanical properties of Nb-Ti microalloyed steel[J]. Materials Science and Engineering A, 2001, 319: 321-325.
[14]王晓南, 邸洪双, 杜林秀. 形变及冷却速率对热轧超高强汽车钢板中纳米析出的影响[J]. 金属学报, 2012, 48(5): 621-628.
Wang Xiaonan, Di Hongshuang, Du Linxiu. Effects of deformation and cooling rate on nano-scale precipitation in hot-rolled ultra-high strength steel[J]. Acta Metallurgica Sinica, 2012, 48(5): 621-628.
[15]苑少强, 刘炳新, 张凤梅. Nb钢及Nb-Ti钢的应变诱导析出行为[J]. 唐山学院学报, 2005(4): 104-106.
Yuan Shaoqiang, Liu Bingxin, Zhang Fengmei. Strain-induced precipitation in Nb and Nb-Ti microalloyed steel[J]. Journal of Tangshan College, 2005(4): 104-106.
[16]Dutta B, Palmiere E J, Sellars C M. Modelling the kinetics of strain induced precipitation in Nb microalloyed steels[J]. Acta Materialia, 2001, 49(5): 785-794.
[17]Pandit A, Murugaiyan A, Podder A S, et al. Strain induced precipitation of complex carbonitrides in Nb-V and Ti-V microalloyed steels[J]. Scripta Materialia, 2005, 53(11): 1309-1314.
[18]Zhou Xiaoguang, Liu Zhenyu, Wu Di. Modeling of strain-induced precipitation kinetics in Nb microalloyed steels[J]. Acta Metallurgica Sinica(English Letters), 2006(5): 385-390.
[19]Akben M G, Bacroix B, Jonas J J. Effect of vanadium and molybdenum addition on high temperature recovery, recrystallization and precipitation behavior of niobium-based microalloyed steels[J]. Acta Metallurgica, 1983, 31(1): 161-174.
[20]吴新朗, 赵征志, 田允, 等. Nb-Ti微合金钢热变形后组织演变及第二相粒子析出行为[J]. 钢铁钒钛, 2008(1): 66-70.
Wu Xinlang, Zhao Zhengzhi, Tian Yun, et al. Phase transformation and second-phase precipitation behavior of Nb-Ti microalloyed steel during cooling after deformation[J]. Iron Steel Vanadium Titanium, 2008(1): 66-70.
[21]陈俊, 唐帅, 刘振宇, 等. 冷却方式对Nb-Ti微合金钢组织和性能及沉淀行为的影响[J]. 金属学报, 2012, 48(5): 441-449.
Chen Jun, Tang Shuai, Liu Zhenyu, et al. Effects of cooling process on microstructure, mechanical properties and precipitation behaviors of niobium-titanium micro-alloyed steel[J]. Acta Metallurgica Sinica, 2012, 48(5): 441-449.

变形条件和冷却速率对低碳含Nb钢的相变及纳米析出的影响

Effect of deformation and cooling rate on transformation characteristic and nanoscale precipitation in a low carbon Nb micro-alloyed steel

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	王新志, 张可, 黄重, 徐党委, 杜海明, 章小峰, 张熹. Cr-Ni-Cu桥梁耐候钢的连续冷却相变及其组织和硬度[J]. 金属热处理, 2023, 48(2): 17-22.
[2]	王伟, 张文, 赵建森, 朱百智, 米艳军, 江红兵, 胡成飞. 42CrMo钢输出法兰感应淬火的数值模拟及验证[J]. 金属热处理, 2023, 48(2): 242-246.
[3]	黄朋, 镇凡, 杜平, 曲锦波. 薄规格耐磨钢淬火条纹分析与工艺改进[J]. 金属热处理, 2023, 48(1): 266-269.
[4]	苏长珠, 吴润, 李钊, 吴腾, 秦金柱. 配分时间对低碳热轧F-Q&P钢组织和性能的影响[J]. 金属热处理, 2022, 47(9): 27-30.
[5]	骆艳萍, 汪家晗, 李沐泽, 张云祥, 周建勋, 赵志恒. HRB400E抗震螺纹钢静态CCT曲线测定及组织分析[J]. 金属热处理, 2022, 47(9): 188-193.
[6]	周文浩. 高强度桥梁钢Q690q的连续冷却转变行为[J]. 金属热处理, 2022, 47(9): 202-207.
[7]	张铮, 陈进磊, 张敏, 乔珺威. 热变形对塑料模具钢SDFT600贝氏体相变的影响[J]. 金属热处理, 2022, 47(8): 1-6.
[8]	许峰, 陈前, 林芷民, 成浩, 管怡杰, 陆凯健. Nb和Mo对矿用磨球用钢微结构和相变的影响[J]. 金属热处理, 2022, 47(8): 52-57.
[9]	张文文, 董福涛, 刘云双, 田亚强, 陈连生. 终轧温度对Cu合金化Fe-18Mn-0.6C TWIP钢微观组织和力学性能的影响[J]. 金属热处理, 2022, 47(7): 102-106.
[10]	国春艳, 刘玉宝, 杨鹏飞, 李园, 吕卫东, 高日增, 张洋, 侯复生. FeCoCrNiMn高熵合金大形变冷轧板再结晶退火过程中的组织演变[J]. 金属热处理, 2022, 47(7): 163-167.
[11]	王英虎. 基于FactSage的Fe-15Mn-8Al-0.25C低密度钢的组织及力学性能[J]. 金属热处理, 2022, 47(7): 203-210.
[12]	严翔, 李德发, 官计生, 杨治争. 形变对低碳微合金化热处理钢组织和性能的影响[J]. 金属热处理, 2022, 47(6): 85-88.
[13]	吴轲源, 刘云鹏, 李孔斋, 徐良乐. 17-4PH不锈钢连续冷却转变及相变动力学[J]. 金属热处理, 2022, 47(6): 161-167.
[14]	焦清洋, 赵栋, 王新宇, 李世键. 回火态AerMet100钢的热物理性能[J]. 金属热处理, 2022, 47(6): 168-172.
[15]	李阳, 张建伟, 朱鹏凯, 杨扬. 碳含量及冷却速率对钢件淬火残余应力的影响[J]. 金属热处理, 2022, 47(6): 192-195.