交流电场对工业纯钛TA2粉末法渗氧的影响

doi:10.13251/j.issn.0254-6051.2023.02.044

金属热处理 ›› 2023, Vol. 48 ›› Issue (2): 284-288.DOI: 10.13251/j.issn.0254-6051.2023.02.044

交流电场对工业纯钛TA2粉末法渗氧的影响

王鑫宇¹, 谢飞^1,2, 潘建伟³

1.常州大学材料科学与工程学院, 江苏常州 213164;
2.常州大学江苏省材料表面技术重点实验室, 江苏常州 213164;
3.常州大学怀德学院, 江苏靖江 214500

收稿日期:2022-09-27 修回日期:2023-01-01 出版日期:2023-02-25 发布日期:2023-03-22
通讯作者: 谢飞,教授,博士,E-mail:xiefei@cczu.edu.cn
作者简介:王鑫宇(1997—),男,硕士研究生,主要研究方向为材料表面工程,E-mail:894128757@qq.com。
基金资助:
国家自然科学基金(51171032)

Effect of alternating current field on powder oxidizing of commercially pure titanium TA2

Wang Xinyu¹, Xie Fei^1,2, Pan Jianwei³

1. School of Materials Science and Engineering, Changzhou University, Changzhou Jiangsu 213164, China;
2. Key Laboratory of Materials Surface Engineering of Jiangsu Province, Changzhou University, Changzhou Jiangsu 213164, China;
3. Huaide College, Changzhou University, Jingjiang Jiangsu 214500, China

Received:2022-09-27 Revised:2023-01-01 Online:2023-02-25 Published:2023-03-22

摘要/Abstract

摘要： 在650 ℃进行工业纯钛TA2的粉末法渗氧,通过渗罐内一组平行电极,对渗剂和TA2试样施加交流电场,进行交流电场增强粉末法渗氧。研究发现,以尿素作为供氧剂的粉末法渗氧生成的渗层表层主要由TiO₂组成,还有少量Ti₂N和固溶氧的α-Ti;交流电场能够大幅度提高纯钛的渗氧效率,随电场电流增加,渗层厚度、硬度增加,沿层深硬度分布改善;在电场电流为2 A和渗剂含2%尿素时,6 h渗扩所得渗层厚度约46 μm,渗层峰值硬度约1150 HV0.01。交流电场的物理作用能够强化渗氧剂中的反应,从而增加氧原子及含氧活性基团的产率和活性;交流电场通过提高试样内部的空位浓度,为氧原子的扩散提供更多通道;这两个因素加快氧向试样内部扩散。这种新技术可以在较低温度对钛进行高效渗氧处理,减少工件畸变。

关键词: 工业纯钛TA2, 粉末法渗氧, 交流电场, 表面改性

Abstract: Alternating current field (ACF) enhanced powder oxidizing was carried out on commercially pure titanium TA2 at 650 ℃ by applying ACF to pack agents and specimen with a pair of electrodes paralleling with each other set in a process container. The results show that the surface layer, produced by the oxidizing with carbamide as oxygen supplier in the pack agent, consists of mainly TiO₂ with few Ti₂N and α-Ti with dissolved oxygen. ACF can greatly enhance the oxidizing of TA2. The oxidized layer thickness and hardness increase with the increase of ACF current, which modifies the hardness distribution along the layer depth. After oxidizing for 6 h with pack agent containing 2% carbamide and the ACF with a current of 2 A, an oxidized layer is obtained with thickness of 46 μm and peak hardness of 1150 HV0.01. It is proposed that the ACF's physical effect of enhancing chemical reactions in the agent increases the productivity and activity of oxygen atoms or active oxygen-containing species. By increasing the vacancy concentration in the specimen, the ACF provides more channels for the diffusion of oxygen atoms. These two factors accelerate the diffusion of oxygen atoms into the specimen. This new oxidizing technology can carry out high-efficient oxygen infiltration treatment on titanium at a lower temperature and reduce workpiece distortion.

Key words: commercially pure titanium TA2, powder oxidizing, alternating current field, surface modification

中图分类号:

王鑫宇, 谢飞, 潘建伟. 交流电场对工业纯钛TA2粉末法渗氧的影响[J]. 金属热处理, 2023, 48(2): 284-288.

Wang Xinyu, Xie Fei, Pan Jianwei. Effect of alternating current field on powder oxidizing of commercially pure titanium TA2[J]. Heat Treatment of Metals, 2023, 48(2): 284-288.

参考文献

[1]Kobayashi M, Funami K, Suzuki S, et al. Manufacturing process and mechanical properties of fine TiB dispersed Ti-6Al-4V alloy composites obtained by reaction sintering[J]. Materials Science and Engineering A, 1998, 243(1): 279-284.
[2]Quast J P, Boehlert C J, Gardner R, et al. A microstructure and sonic fatigue investigation of Ti-TiB functionally graded materials[J]. Materials Science and Engineering A, 2008, 497(1): 1-9.
[3]Brandstötter J, Lengauer W. Multiphase reaction diffusion in transition metal-boron systems[J]. Journal of Alloys and Compounds, 1997, 262-263: 390-396.
[4]Bailey R, Sun Y. Corrosion and tribocorrosion performance of thermally oxidized commercially pure titanium in a 0.9%NaCl solution[J]. Journal of Materials Engineering and Performance, 2015, 24(4): 1669-1678.
[5]Jamesh M, Kumar S, Sankara Narayanan T S N. Effect of thermal oxidation on corrosion resistance of commercially pure titanium in acid medium[J]. Journal of Materials Engineering and Performance, 2012, 21(6): 900-906.
[6]马红岩, 王茂才, 冯瑞亮, 等. 钛合金TC11的高温渗氧[J]. 科学技术与工程, 2003(2): 162-163.
Ma Hongyan, Wang Maocai, Feng Ruiliang, et al. Oxygen permeation of titanium alloys TC11 on high temperature[J]. Science Technology and Engineering, 2003(2): 162-163.
[7]马红岩, 王茂才, 冯瑞亮, 等. 三种钛合金的高温渗氧行为[J]. 金属热处理, 2003, 28(7): 1-5.
Ma Hongyan, Wang Maocai, Feng Ruiliang, et al. Oxygen permeation of three titanium alloys at high temperature[J]. Heat Treatment of Metals, 2003, 28(7): 1-5.
[8]张聪惠, 刘颖, 肖桂枝, 等. 脉冲渗氧对工业纯钛表面摩擦磨损性能的影响[J]. 中国有色金属学报, 2021, 31(4): 945-955.
Zhang Conghui, Liu Ying, Xiao Guizhi, et al. Effect of pulse oxidation on surface fricition and wear properties of pure titanium properties of industrial puer titanium[J]. The Chinese Journal of Nonferrous Metals, 2021, 31(4): 945-955.
[9]严伟, 王小祥. 热氧化处理钛表面渗氧层的组织与性能研究[J]. 稀有金属材料与工程, 2005(3): 471-474.
Yan Wei, Wang Xiaoxiang. Characterization of the surface oxygen-diffusion zone of the thermally oxidized titanium[J]. Rare Metal Materials and Engineering, 2005(3): 471-474.
[10]Tikekar N M, Ravi Chandran K S, Sanders A. Nature of growth of dual titanium boride layers with nanostructured titanium boride whiskers on the surface of titanium[J]. Scripta Materialia, 2007, 57(3): 273-276.
[11]Xie Fei, Cheng Jian, Wang Shuo. Effects and mechanisms of an alternating current field on pack boriding[J]. Vacuum, 2018, 148: 41-47.
[12]谢飞, 王晓娟, 潘建伟. 交流电场增强45钢中温粉末法硼铝共渗特性[J]. 中国表面工程, 2020, 33(4): 121-127.
Xie Fei, Wang Xiaojuan, Pan Jianwei. Characterization of alternating current field enhanced pack boron-aluminizing at a medium temperature for 45 steel[J]. China Surface Engineering, 2020, 33(4): 121-127.
[13]王晓娟, 谢飞, 程健, 等. 45钢直流电场增强粉末法渗硼层相结构与性能[J]. 材料热处理学报, 2015, 36(2): 197-202.
Wang Xiaojuan, Xie Fei, Cheng Jian, et al. Phase structure and property of boriding case of 45 steel by direct current field enhanced pack boronizing[J]. Transactions of Materials and Heat Treatment, 2015, 36(2): 197-202.
[14]程健, 谢飞, 孙力, 等. 交流电场增强45钢中低温粉末法渗硼特性[J]. 金属学报, 2014, 50(11): 1311-1318.
Cheng Jian, Xie Fei, Sun Li, et al. Characterization of alternating current field enhanced pack boriding for 45 carbon steel at low and medium temperatures[J]. Acta Metallurgica Sinica, 2014, 50(11): 1311-1318.
[15]陈长军, 马红岩, 张敏, 等. 钛合金的表面渗氧强化研究进展[J]. 热加工工艺, 2007, 36(14): 63-65, 70.
Chen Changjun, Ma Hongyan, Zhang Min, et al. Research progress of surface oxygen diffusion hardening of titanium alloy[J]. Hot Working Technology, 2007, 36(14): 63-65, 70.
[16]Xie Fei, Sun Li, Cheng Jian. Alternating current field assisted pack boriding to Fe₂B coating[J]. Surface Engineering, 2013, 29(3): 240-243.
[17]Xie Fei, Xu Shaoqiang, Pan Jianwei. Novel pack cementations: alternating current field assisted pack cementations[J]. Materials Performance and Characterization, 2018, 7(5): 1164-1177.
[18]Xie Fei, Wang Xiaojuan, Pan Jianwei. Accelerate pack boriding with reused boriding media by simultaneously employing Al and alternating current field[J]. Vacuum, 2017, 141: 166-169.
[19]闫梦龙, 谢飞, 潘建伟. 交流电场对45钢粉末法渗铝的影响 [J]. 材料热处理学报, 2015, 36(2): 203-208.
Yan Menglong, Xie Fei, Pan Jianwei. Effects of alternating current field on pack aluminizing of 45 steel [J]. Transactions of Materials and Heat Treatment, 2015, 36(2): 203-208.

交流电场对工业纯钛TA2粉末法渗氧的影响

Effect of alternating current field on powder oxidizing of commercially pure titanium TA2

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