酸气后冷器封头开裂原因分析

doi:10.13251/j.issn.0254-6051.2023.08.043

金属热处理 ›› 2023, Vol. 48 ›› Issue (8): 265-271.DOI: 10.13251/j.issn.0254-6051.2023.08.043

酸气后冷器封头开裂原因分析

刘民¹, 鲁美朋¹, 刘嘉晨², 顾宝兰², 郭静², 孙跃军¹, 宋明²

1.辽宁工程技术大学材料科学与工程学院, 辽宁阜新 123000;
2.中国特种设备检测研究院, 北京 100020

收稿日期:2023-04-25 修回日期:2023-07-03 出版日期:2023-08-25 发布日期:2023-10-10
通讯作者: 宋明,教授级高工,博士,E-mail: songm214@foxmail.com
作者简介:刘民(1965—),男,副教授,主要研究方向为化工静设备状态评估,E-mail: 18340430635@163.com。

Analysis of cracking cause of acid gas post-cooler head

Liu Min¹, Lu Meipeng¹, Liu Jiachen², Gu Baolan², Guo Jing², Sun Yuejun¹, Song Ming²

1. College of Materials Science and Engineering, Liaoning Technical University, Fuxin Liaoning 123000, China;
2. China Special Equipment Inspection and Research Institute, Beijing 100020, China

Received:2023-04-25 Revised:2023-07-03 Online:2023-08-25 Published:2023-10-10

摘要/Abstract

摘要： 某天然气净化厂酸气后冷器浮头式封头内壁出现鼓包和裂纹,采用宏观检验、化学成分分析、硬度测试、金相检验、能谱分析、断口分析及EBSD测试等方法,对鼓包和裂纹产生的原因进行了分析。结果表明,封头内壁鼓包和开裂为氢鼓包(HB)和氢致开裂(HIC)。由于该封头材料(20g钢)显微组织沿轧制方向呈(铁素体+珠光体)带状分布,且在1/2板厚位置存在因元素偏析所致的贝氏体组织和较多MnS夹杂物,而该封头的服役环境中含有湿H₂S介质,与钢材发生电化学反应后产生了氢,氢在板厚1/2缺陷处聚集,导致了封头内壁的鼓包和开裂。

关键词: 20g钢, 湿H₂S环境, 显微组织, MnS夹杂物, 氢致开裂, 鼓包

Abstract: Bulges and cracks appeared in the inner wall of floating head of acid gas post-cooler in a natural gas purification plant. The causes of bulges and cracks were analyzed by means of macroscopic examination, chemical composition analysis, hardness test, metallographic examination, energy spectrum analysis, fracture analysis and EBSD test. The results show that the bulge and cracking of the inner wall of the head are hydrogen bulge (HB) and hydrogen-induced cracking (HIC). Since the microstructure of the head material (20g steel) is banded ferrite+pearlite along the rolling direction, with bainite and more MnS inclusions appearing at the position of 1/2 plate thickness caused by element segregation, and the service environment of the head contains wet H₂S medium which generates hydrogen after electrochemical reaction with the steel, then the hydrogen accumulates at the defects of 1/2 plate thickness, leading to bulge and cracking of the inner wall of the head.

Key words: 20g steel, wet H₂S environment, microstructure, MnS inclusion, hydrogen-induced cracking, bulge

中图分类号:

TG115

刘民, 鲁美朋, 刘嘉晨, 顾宝兰, 郭静, 孙跃军, 宋明. 酸气后冷器封头开裂原因分析[J]. 金属热处理, 2023, 48(8): 265-271.

Liu Min, Lu Meipeng, Liu Jiachen, Gu Baolan, Guo Jing, Sun Yuejun, Song Ming. Analysis of cracking cause of acid gas post-cooler head[J]. Heat Treatment of Metals, 2023, 48(8): 265-271.

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酸气后冷器封头开裂原因分析

Analysis of cracking cause of acid gas post-cooler head

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