不同氮含量镀锡板连续退火后的组织与性能

doi:10.13251/j.issn.0254-6051.2025.01.021

金属热处理 ›› 2025, Vol. 50 ›› Issue (1): 140-145.DOI: 10.13251/j.issn.0254-6051.2025.01.021

不同氮含量镀锡板连续退火后的组织与性能

兰昊天, 宋乙峰, 岳重祥, 杨佳伟

江苏省沙钢钢铁研究院有限公司, 江苏张家港 215625

收稿日期:2024-08-02 修回日期:2024-11-18 出版日期:2025-01-25 发布日期:2025-03-12
通讯作者: 岳重祥,高级工程师,博士,E-mail:chongxiang39@163.com
作者简介:兰昊天(1993—),男,工程师,硕士,主要研究方向为镀锡板产品与工艺开发,E-mail:lanht-iris@shasteel.cn。

Microstructure and properties of tinplate with different nitrogen contents after continuous annealing

Lan Haotian, Song Yifeng, Yue Chongxiang, Yang Jiawei

Institute of Research of Iron and Steel, Shagang, Jiangsu Province, Zhangjiagang Jiangsu 215625, China

Received:2024-08-02 Revised:2024-11-18 Online:2025-01-25 Published:2025-03-12

摘要/Abstract

摘要： 采用连续退火试验机对不同氮含量镀锡板进行不同温度(595~710 ℃)连续退火试验,对退火处理镀锡板的组织形貌、晶粒尺寸、硬度和拉伸性能进行分析。结果表明,氮含量的增加提升了镀锡板的再结晶温度,同时起到细化晶粒和抑制晶粒长大的作用。高氮含量镀锡板的硬度、强度均高于低含量镀锡板。析出氮化物主要为弥散的矩形TiN和AlN,析出物随着氮含量的提升而增多。当退火温度提升至690 ℃以上时,不同氮含量镀锡板中片层状珠光体沿晶界分布,取代沿轧制方向分布的粒状珠光体。根据试验结果,将工业生产高硬度镀锡板的连续退火温度控制在645~660 ℃范围,可减小硬度波动,提升制罐效率。

关键词: 镀锡板, 氮含量, 连续退火, 析出物, 组织, 性能

Abstract: Continuous annealing tests were conducted on tinplate with different nitrogen contents at different temperatures (595-710 ℃) using a continuous annealing testing machine. The microstructure, grain size, hardness, and tensile properties of the annealed tinplate were analyzed. The results show that the increase in nitrogen content raises the recrystallization temperature of the tinplate, while also refines grain size and inhabits grain growth. The hardness and strength of tinplate with higher nitrogen content are both higher than those with lower nitrogen content. The main nitrogen precipitates are dispersed rectangular TiN and AlN, which increase with the increase of nitrogen content. When the annealing temperature is raised to above 690 ℃, the lamellar pearlite in tinplate with different nitrogen contents is distributed along grain boundaries, replacing the granular pearlite distributed along the rolling direction. Based on the experimental results, controlling the continuous annealing temperature for the production of high-hardness tinplate in the industrial production within the range of 645-660 ℃ can reduce the hardness fluctuation and improve the canning efficiency.

Key words: tinplate, nitrogen content, continuous annealing, precipitate, microstructure, properties

中图分类号:

TG142.1

兰昊天, 宋乙峰, 岳重祥, 杨佳伟. 不同氮含量镀锡板连续退火后的组织与性能[J]. 金属热处理, 2025, 50(1): 140-145.

Lan Haotian, Song Yifeng, Yue Chongxiang, Yang Jiawei. Microstructure and properties of tinplate with different nitrogen contents after continuous annealing[J]. Heat Treatment of Metals, 2025, 50(1): 140-145.

参考文献

[1]蒋新国, 汪为健, 宋超群. 马口铁生产工艺和工艺设备[M]. 北京: 科学出版社, 2017.
[2]兰昊天, 秦松, 徐晓涵. 易开盖用镀锡板开裂原因及改进措施[J]. 机械工程材料, 2022, 46(10): 113-118.
Lan Haotian, Qing Song, Xu Xiaohan. Cracking cause of tin plate for easy-opening lid and improvements[J]. Materials for Mechanical Engineering, 2022, 46(10): 113-118.
[3]吴圣杰, 刘新院, 李化龙, 等. 退火工艺对冷轧镀锡基板组织与性能的影响[J]. 材料热处理学报, 2016, 37(11): 123-128.
Wu Shengjie, Liu Xinyuan, Li Hualong, et al. Effects of anneling process on microstructure and mechanical properties of tin mill black plate[J]. Transactions of Materials and Heat Treatment, 2016, 37(11): 123-128.
[4]毛卫民, 赵新兵. 金属的再结晶与晶粒长大[M]. 北京: 冶金工业出版社, 1994.
[5]张宇飞, 刘海涛, 郑淮北. 冷轧压下率对高氮奥氏体不锈钢组织性能的影响[J]. 轧钢, 2022, 39(6): 159-164.
Zhang Yufei, Liu Haitao, Zheng Huaibei. Effect of cold rolling reduction rate on microstructure and property of high nitrogen austenitic stainless steel[J]. Steel Rolling, 2022, 39(6): 159-164.
[6]丁进明, 王运起, 张岩岩. 氮含量对镀锡板组织性能的影响及工艺优化研究[J]. 轧钢, 2023, 40(3): 53-58.
Ding Jinming, Wang Yunqi, Zhang Yanyan. Study on effect of nitrogen content on microsturcture and mechanical properties of tinplate and process optimization[J]. Steel Rolling, 2023, 40(3): 190-193.
[7]方圆, 吴志国, 宋浩, 等. 氮对镀锡板再结晶温度的影响[J]. 金属热处理, 2018, 43(2): 190-193.
Fang Yuan, Wu Zhiguo, Song Hao, et al. Effect of nitrogen on recrystallization temperature of tinplate[J]. Heat Treament of Metals, 2018, 43(2): 190-193.
[8]薛忍让, 宋志刚, 郑文杰, 等. 氮对316L晶粒尺寸和力学性能的影响[J]. 钢铁研究学报, 2013, 25(10): 36-41.
Xue Renrang, Song Zhigang, Zheng Wenjie, et al. Effect of adding nitrogen on grain size and mechanical properties of 316L[J]. Journal of Iron and Steel Research, 2013, 25(10): 36-41.
[9]邓素怀, 梁江涛, 刘锟, 等. 珠光体形态对SK85钢球化退火组织和硬度的影响[J]. 金属热处理, 2023, 48(11): 211-215.
Deng Suhuai, Liang Jiangtao, Liu Kun, et al. Effect of pearlite morphology on microstructure and hardness after spheroidizing annealing of SK85 steel[J]. Heat Treament of Metals, 2023, 48(11): 211-215.
[10]孙超凡, 方圆, 王雅晴, 等. 氮对镀锡钢板的强化作用[J]. 金属热处理, 2020, 45(3): 64-67.
Sun Chaofan, Fang Yuan, Wang Yaqing, et al. Strengthening effect of nitrogen on tin-plated steel sheet[J]. Heat Treament of Metals, 2020, 45(3): 64-67.
[11]Cui B, Luo T, Feng M. Effect of nitrogen content on the microstructure and properties of the laser-arc hybird welding Joint of high nitrogen steel[J]. Optik-International Journal for Light and Electron Optics, 2021, 243(6): 1-13.
[12]傅杰, 朱剑, 迪林, 等. 微合金钢中TiN的析出规律研究[J]. 金属学报, 2000, 36(8): 801-804.
Fu Jie, Zhu Jian, Di Lin, et al. Study on the precipitation behavior of TiN in the microalloyed steels[J]. Acta Metallurgica Sinica, 2000, 36(8): 801-804.
[13]Li Lihao, Zhang Wei, Gu Jinbo, et al. Effect of nitrogen-substituted carbon on thermal stability of Cr-Mo-V hot-working die steel[J]. Steel Research International, 2020, 91(10): 1-14.

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不同氮含量镀锡板连续退火后的组织与性能

Microstructure and properties of tinplate with different nitrogen contents after continuous annealing

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