表面微弧氧化处理对不锈钢与环氧树脂粘接性能的影响

doi:10.13251/j.issn.0254-6051.2020.03.018

金属热处理 ›› 2020, Vol. 45 ›› Issue (3): 92-96.DOI: 10.13251/j.issn.0254-6051.2020.03.018

表面微弧氧化处理对不锈钢与环氧树脂粘接性能的影响

赵杰夫, 楚珑晟, 刘俊, 高朋

西南交通大学材料科学与工程学院, 四川成都 610031

收稿日期:2019-06-16 出版日期:2020-03-25 发布日期:2020-04-03
通讯作者: 楚珑晟,副教授,博士,主要从事复合材料、功能材料及轨道交通关键材料的研究,E-mail:lshchu@swjtu.edu.cn
作者简介:赵杰夫(1992—),男,硕士研究生,主要从事复合材料和表面改性领域的研究,E-mail:jeffzhao_92@yeah.net。
基金资助:
国家重点研发计划(2016YFB1200504-A-02)

Effect of micro-arc oxidation treatment on adhesion properties between stainless steel and epoxy resin

Zhao Jiefu, Chu Longsheng, Liu Jun, Gao Peng

School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu Sichuan 610031, China

Received:2019-06-16 Online:2020-03-25 Published:2020-04-03

摘要/Abstract

摘要：

采用热浸镀铝工艺在不锈钢表面镀铝,分析了浸镀时间与浸镀温度对合金层及纯铝层厚度的影响并获得最佳镀铝工艺参数,在此基础上再进行微弧氧化试验。用剪切法测试了氧化膜与环氧树脂之间的结合强度,采用SEM、XRD和激光共聚焦显微镜对微弧氧化膜的微观成分与结构进行了表征,进而探讨分析了不锈钢微弧氧化处理对其与环氧树脂粘接性能的影响。结果表明:适宜的浸镀温度为710 ℃,浸镀时间为11 min;微弧氧化膜主要由α-Al₂O₃和γ-Al₂O₃组成,不同微弧氧化时间下氧化膜产物基本相同;随着氧化时间增加,陶瓷膜表面粗糙度增大,微弧氧化膜-环氧树脂的结合强度增大,当时间增至30 min时,膜层表面粗糙度最大值为1.265 μm,结合强度增加到最高值33.20 MPa,比未处理过的试样结合强度提高了2.8倍。

关键词: 不锈钢, 热浸镀铝, 微弧氧化, 环氧树脂, 粘接性能

Abstract:

The surface of stainless steel was aluminized by hot-dip aluminizing process, the influences of dip time and dip temperature on the thicknesses of alloy layer and pure aluminum layer were analyzed to obtain the optimum process parameters, then micro-arc oxidation experiment was carried out. The bonding strength between the oxide film and epoxy resin was measured by the shear method, the microstructure of the micro-arc oxidation film was characterized by using SEM, XRD, and laser confocal microscopy to discuss and analyze the influence of micro-arc oxidation treatment of stainless steel on its adhesion to epoxy resin. The results show that the appropriate hot-dip temperature is 710 ℃, the appropriate hot-dip time is 11 min. The micro-arc oxidation film is mainly composed of α-Al₂O₃ and γ-Al₂O₃, and the oxidation film products are basically the same under different micro-arc oxidation time. Both the surface roughness of ceramic film and the micro-arc oxidation film-epoxy resin bonding strength increase with the increase of oxidation time. When the time increases to 30 minutes, the maximum surface roughness is 1.265 μm, the binding strength increases to the maximum value 33.20 MPa and being 2.8 times that of untreated samples.

Key words: stainless steel, hot-dip aluminizing, micro-arc oxidation, epoxy resin, bonding properties

中图分类号:

TG17

赵杰夫, 楚珑晟, 刘俊, 高朋. 表面微弧氧化处理对不锈钢与环氧树脂粘接性能的影响[J]. 金属热处理, 2020, 45(3): 92-96.

Zhao Jiefu, Chu Longsheng, Liu Jun, Gao Peng. Effect of micro-arc oxidation treatment on adhesion properties between stainless steel and epoxy resin[J]. HTM, 2020, 45(3): 92-96.

参考文献

[1]蒋鞠慧, 陈敬菊. 复合材料在轨道交通上的应用与发展[J]. 玻璃钢/复合材料, 2009(6): 81-85.
Jiang Juhui, Chen Jingju. Applications and development of composites in railway transportation[J]. Fiber Reinforced Plastics/Composites, 2009(6): 81-85.
[2]Guo H F, An M Z. Growth of ceramic coatings on AZ91D magnesium alloys by micro-arc oxidation in aluminate-fluoride solutions and evaluation of corrosion resistance[J]. Applied Surface Science, 2005, 246(1): 229-238.
[3]Guo P Y, Shao Y, Zeng C L, et al. Oxidation characterization of FeAl coated 316 stainless steel interconnects by high-energy micro-arc alloying technique for SOFC[J]. Materials Letters, 2011, 65(19): 3180-3183.
[4]Gao H, Zhang M, Yang X, et al. Effect of Na₂SiO₃ solution concentration of micro-arc oxidation process on lap-shear strength of adhesive-bonded magnesium alloys[J]. Applied Surface Science, 2014, 314: 447-452.
[5]Tang Y, Zhao X, Jiang K, et al. The influences of duty cycle on the bonding strength of AZ31B magnesium alloy by microarc oxidation treatment[J]. Surface and Coatings Technology, 2010, 205(6): 1789-1792.
[6]Sun S, Pan Y, Wu G, et al. Effect of electrolyte composition ratio of micro-arc oxidation on interlaminar strength of CFRP/Mg laminates[J]. International Journal of Adhesion and Adhesives, 2018, 87: 98-104.
[7]Husain H H, Razak Daud A, Daud M. Diffusion of aluminum into steel substrates by means of hot dip aluminizing[C]//AIP Conference Proceedings. American Institute of Physics, 2010, 1202(1): 146-148.
[8]杨钟时, 贾建峰, 田军, 等. 不锈钢表面Al₂O₃膜的微弧氧化制备[J]. 无机材料学报, 2004, 19(6): 1446-1450.
Yang Zhongshi, Jia Jianfeng, Tian Jun, et al. Preparation of micro-arc discharge oxidized coating on hot-dip aluminized stainless steel sheet[J]. Journal of Inorganic Materials, 2004, 19(6): 1446-1450.
[9]Su C W, Lee J W, Wang C S, et al. The effect of hot-dipped aluminum coatings on Fe-8Al-30Mn-0.8C alloy[J]. Surface and Coatings Technology, 2008, 202(9): 1847-1852.
[10]Wang D Q, Shi Z Y. Aluminizing and oxidation treatment of 1Cr18Ni9 stainless steel[J]. Applied Surface Science, 2004, 227(1): 255-260.
[11]韩石磊, 李华玲, 王树茂, 等. 不锈钢热浸镀铝中温度及合金元素对膜厚的影响[J]. 表面技术, 2009, 38(4): 20-22.
Han Shilei, Li Hualing, Wang Shumao, et al. Effects of temperature and alloy element on hot-dip aluminizing process for decreasing Fe-Al film thickness[J]. Surface Technology, 2009, 38(4): 20-22.
[12]Kobayashi S, Yakou T. Control of intermetallic compound layers at interface between steel and aluminum by diffusion-treatment[J]. Materials Science and Engineering A, 338(1/2): 44-53.
[13]Chang Y Y, Tsaur C C, Rock J C. Microstructure studies of an aluminide coating on 9Cr-1Mo steel during high temperature oxidation[J]. Surface and Coatings Technology, 2006, 200(22/23): 6588-6593.
[14]祝晓文, 韩建民, 崔世海, 等. 铝、镁合金微弧氧化技术研究进展[J]. 材料科学与工艺, 2006(4): 366-369.
Zhu Xiaowen, Han Jianmin, Cui Shihai, et al. The research progress of micro-arc oxidation on Al and Mg alloys[J]. Materials Science and Technology, 2006(4): 366-369.
[15]Liu W, Liu W, Bao A. Microstructure and properties of ceramic coatings on 7N01 aluminum alloy by micro-arc oxidation[J]. Procedia Engineering, 2012, 27: 828-832.
[16]Xin S G, Song L X, Zhao R G, et al. Properties of aluminum oxide coating on aluminum alloy produced by micro-arc oxidation[J]. Surface and Coatings Technology, 2005, 199(2/3): 184-188.
[17]Li Z S, Wu H L, Pan F S, et al. Microstructures and properties of ceramic layer on 7A55 aluminum alloy by micro-arc oxidation[J]. Journal of Aeronautical Materials, 2010, 30(5): 54-57.

表面微弧氧化处理对不锈钢与环氧树脂粘接性能的影响

Effect of micro-arc oxidation treatment on adhesion properties between stainless steel and epoxy resin

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