深冷处理对K6509钴基合金表面性能的影响

doi:10.13251/j.issn.0254-6051.2020.07.006

金属热处理 ›› 2020, Vol. 45 ›› Issue (7): 28-31.DOI: 10.13251/j.issn.0254-6051.2020.07.006

深冷处理对K6509钴基合金表面性能的影响

王兴富^1,2, 李永刚^1,2,3, 雷达^1,2, 师佑杰^1,2, 李学楠^1,2

1. 太原理工大学机械与运载工程学院, 山西太原 030024;
2. 太原理工大学精密加工山西重点实验室, 山西太原 030024;
3. 太原理工大学山西省金属材料腐蚀与防护工程技术研究中心, 山西太原 030024

收稿日期:2019-01-13 出版日期:2020-07-25 发布日期:2020-09-07
通讯作者: 李永刚, 副教授, 博士, E-mail:liyonggang_tyut@126.com
作者简介:王兴富(1994—), 男, 硕士研究生, 主要研究方向为精密零件表面光整加工, E-mail:1129514273@qq.com。
基金资助:
国家自然科学基金(51705352);中国博士后科学基金(2018M641682);山西省高等学校科技创新项目(2019L0139)

Effect of cryogenic treatment on surface properties of K6509 Co-based alloy

Wang Xingfu^1,2, Li Yonggang^1,2,3, Lei Da^1,2, Shi Youjie^1,2, Li Xuenan^1,2

1. School of Mechanical Engineering, Taiyuan University of Technology, Taiyuan Shanxi 030024, China;
2. Shanxi Key Laboratory of Precision Machining, Taiyuan University of Technology, Taiyuan Shanxi 030024, China;
3. Engineering and Technology Research Center for Metal Material Corrosion and Protection of Shanxi Province, Taiyuan University of Technology, Taiyuan Shanxi 030024, China

Received:2019-01-13 Online:2020-07-25 Published:2020-09-07

摘要/Abstract

摘要： 研究了K6509钴基合金样品在-196 ℃液氮中分别深冷24 h和48 h后的表面性能变化,并与未深冷样品进行对比。通过显微组织分析、XRD成分分析、硬度分析等技术手段研究了深冷处理对钴基合金表面性能的影响,并分析了深冷处理和滚磨光整加工后表面粗糙度和形貌的变化。结果表明:钴基合金在深冷处理24 h时,有部分碳化物发生粗化,同时伴随着细小碳化物析出,深冷48 h时细小碳化物减少,碳化物粗化现象消失,显微组织变得均匀;通过XRD图谱发现,深冷过程中相组成没有发生变化,但含M₂₇C₆碳化物的共晶相和含M₇C₃碳化物的共晶相出现峰移现象,M₂₇C₆碳化物相衍射峰强度发生明显变化;延长深冷时间能够显著提高硬度,深冷48 h硬度提高了17.6%;选择合理的深冷时间与滚磨光整加工相结合能显著提高表面质量,经深冷48 h+滚磨光整处理后,表面粗糙度下降最多,R_a由1.215 μm降到0.662 μm,其表面缺陷明显减少,表面一致性好。

关键词: 钴基合金, 深冷处理, 表面形貌, 显微组织, 碳化物, XRD

Abstract: Surface properties of K6509 Co-based alloy specimens cryogenic treated by -196 ℃ liquid nitrogen for 24 h and 48 h were studied and compared with non-cryogenic specimens by means of microstructure analysis, XRD component analysis and hardness analysis, and the changes of surface roughness and morphologies after cryogenic treatment and rolling polishing were analyzed. The results show that some of the carbides in Co-base alloy are roughened and the fine carbides are precipitated after 24 h cryogenic treatment, but after 48 h cryogenic treatment, the fine carbide decreases, the carbide coarsening disappears, and the microstructure becomes uniform. The XRD patterns show that the phase composition does not change during the cryogenic process, but the peak value shift at the eutectic phase containing M₂₇C₆ carbide and the eutectic phase containing M₇C₃ carbides, and the diffraction peak intensity of the M₂₇C₆ carbides changes significantly. The hardness is significantly increased by prolonging the cryogenic time, and the hardness is increased by 17.6% after 48 h cryogenic treatment. The combination of reasonable cryogenic time and rolling polishing can significantly improve the surface quality. After 48 h cryogenic treatment and rolling polishing, the surface roughness decreases the most, and the R_a value decreases from 1.215 μm to 0.662 μm, and the surface defects are significantly reduced and the surface consistency is well.

Key words: Co-based alloy, cryogenic treatment, surface morphology, microstructure, carbide, XRD

中图分类号:

TG156.91

王兴富, 李永刚, 雷达, 师佑杰, 李学楠. 深冷处理对K6509钴基合金表面性能的影响[J]. 金属热处理, 2020, 45(7): 28-31.

Wang Xingfu, Li Yonggang, Lei Da, Shi Youjie, Li Xuenan. Effect of cryogenic treatment on surface properties of K6509 Co-based alloy[J]. Heat Treatment of Metals, 2020, 45(7): 28-31.

参考文献

[1]张忠杰. 深冷处理对Ti-6A1-4V钛合金摩擦磨损行为及机理的影响[D]. 太原: 太原理工大学, 2019.
Zhang Zhongjie. The influence of cryogenic treatment on the wear behavior and mechanism of Ti-6Al-4V titanium alloy[D]. Taiyuan: Taiyuan University of Technology, 2019.
[2]徐仰涛. 新型钴基Co-Al-W合金设计、制备及性能研究[D]. 兰州: 兰州理工大学, 2010.
Xu Yangtao. Study on cobalt based novel Co-Al-W superalloys design, preparation and properties[D]. Lanzhou: Lanzhou University of Technology, 2010.
[3]王少飞, 李树索, 沙江波. 钴基合金Co-Al-W-Ta-Nb的显微组织与高低温力学性能[J]. 稀有金属材料与工程, 2013, 42(5): 1003-1008.
Wang Shaofei, Li Shusuo, Sha Jiangbo. Microstructure and mechanical properties of Co-Al-W-Ta-Nb alloys at room- and high-temperatures[J]. Rare Metal Materials and Engineering, 2013, 42(5): 1003-1008.
[4]董炯, 张戈, 姜承民. 时效工艺对两种钴基高温合金组织和合金元素分布的影响[J]. 佳木斯大学学报(自然科学版), 2000(3): 224-228.
Dong Jiong, Zhang Ge, Jiang Chengmin. Effects of ageing on microstructure and alloy element distrbution of two kinds of cobalt-base alloys[J]. Journal of Jiamusi University(Natural Science Edition), 2000(3): 224-228.
[5]Cabrol E, Boher C, Vidal V, et al. A correlation between tribological behavior and crystal structure of cobalt-based hardfacings[J]. Wear, 2019, 426-427: 996-1007.
[6]Wei Zhenwei, Zhao Wenxia, Zhou Jingyi, et al. Microstructure evolution of K6509 cobalt-base superalloy for over-temperature[J]. Procedia Engineering, 2015, 99: 1302-1310.
[7]Dhokey N B, Dandawate J V. Study of wear stabilisation in cryoprocessed cobalt-based high speed steel[J]. Transactions of the Indian Institute of Metals, 2012, 65(4): 405-412.
[8]晏彬彬. 37CrMnMo热处理工艺参数研究与优化[D]. 上海: 上海工程技术大学, 2016.
Yan Binbin. Research and optimization on 37CrMnMo heat treatment process[D]. Shanghai: Shanghai University of Engineering Science, 2016.
[9]赵卫军. 深冷处理工艺对材料残余应力影响的研究[D]. 太原: 太原科技大学, 2018.
Zhao Weijun. Research on the effect of cryogenic treatment process on residual stress[D]. Taiyuan: Taiyuan University of Science and Technology, 2018.
[10]翟定荣. Ti和Hf在沉淀强化型钴基合金中的影响[D]. 镇江: 江苏科技大学, 2015.
Zhai Dingrong. The effects of Ti, Hf on the precipitate-strengthening Co-based alloy[D]. Zhenjiang: Jiangsu University of Science and Technology, 2015.
[11]王少飞, 李树索, 沙江波. 钴基合金Co-Al-W-Ta-Nb的显微组织与高低温力学性能[J]. 稀有金属材料与工程, 2013, 42(5): 1003-1008.
Wang Shaofei, Li Shusuo, Sha Jiangbo. Microstructure and mechanical properties of Co-Al-W-Ta-Nb alloys at room- and high-temperatures[J]. Rare Metal Materials and Engineering, 2013, 42(5): 1003-1008.

[1]	张子延, 陈君, 陈晓亚, 李全安, 刘建鑫. 固溶时效处理对Mg-4Sm-3Gd-0.5Zr合金显微组织和耐蚀性能的影响[J]. 金属热处理, 2022, 47(4): 10-16.
[2]	梁恩溥, 徐乐, 杨勇, 王毛球. 添加Al、Cu对40CrNi3MoV钢组织和力学性能的影响[J]. 金属热处理, 2022, 47(4): 17-23.
[3]	王英虎, 郑淮北, 刘庭耀, 宋令玺, 白青青. 固溶处理对53Cr21Mn9Ni4N耐热钢组织及碳化物的影响[J]. 金属热处理, 2022, 47(4): 39-45.
[4]	陈连生, 张露友, 田亚强, 杨子旋, 李红斌, 潘红波, 魏英立. 低碳高强舰船用钢的CCT曲线及其组织性能[J]. 金属热处理, 2022, 47(4): 63-68.
[5]	王琪, 吴光亮. 回火温度对1100 MPa级高强钢组织与性能的影响[J]. 金属热处理, 2022, 47(4): 146-150.
[6]	孙凯, 陈研, 杨绍斌. 时效温度对激光选区熔化TC21钛合金微观组织及硬度的影响[J]. 金属热处理, 2022, 47(4): 155-158.
[7]	刘文彬, 乔龙阳, 潘新宇, 程格, 李爱娜, 裴新军. 淬火温度对刀剪用M390粉末冶金不锈钢组织和性能的影响[J]. 金属热处理, 2022, 47(4): 189-195.
[8]	王瑞琴, 葛鹏, 廖强, 侯鹏, 刘宇. 固溶冷却方式对短时用高温钛合金板材组织和性能的影响[J]. 金属热处理, 2022, 47(4): 196-198.
[9]	王绍灼, 孟晗, 王芬, 樊海卫, 李燕, 唐超. 改善低氧TC4-LC及重熔TC4钛合金性能的热处理工艺[J]. 金属热处理, 2022, 47(4): 204-207.
[10]	戴建科, 韩顺, 厉勇, 刘宪民, 王春旭, 庞学东, 李建新. 航空齿轮钢C69高温渗碳后的组织性能[J]. 金属热处理, 2022, 47(4): 219-225.
[11]	苏勇, 王帅, 王吉星, 于兴福, 刘洪秀, 刘金玲. 复合化学热处理对G13Cr4Mo4Ni4V钢组织和硬度的影响[J]. 金属热处理, 2022, 47(4): 226-230.
[12]	张宁, 高星, 王芝林, 蒋波, 刘雅政. 18CrNiMo7-6钢齿轮组织性能异常分析[J]. 金属热处理, 2022, 47(4): 268-273.
[13]	王敬元, 吴松全, 张博华, 辛社伟, 杨义, 王皞, 黄爱军. 固溶时效处理对BT25y钛合金显微组织及硬度的影响[J]. 金属热处理, 2022, 47(3): 14-19.
[14]	孙建, 黄贞益, 李景辉, 王萍. 固溶和时效处理对Fe-Mn-Al-C轻质钢组织和硬度的影响[J]. 金属热处理, 2022, 47(3): 34-38.
[15]	王方军, 刘应龙, 时瑶, 万红, 刘斌斌. 等温退火处理对Inconel 625合金箔材组织和性能的影响[J]. 金属热处理, 2022, 47(3): 77-81.

深冷处理对K6509钴基合金表面性能的影响

Effect of cryogenic treatment on surface properties of K6509 Co-based alloy

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价