含氢类金刚石涂层在船用柴油机柱塞上的应用

doi:10.13251/j.issn.0254-6051.2020.11.044

金属热处理 ›› 2020, Vol. 45 ›› Issue (11): 226-231.DOI: 10.13251/j.issn.0254-6051.2020.11.044

含氢类金刚石涂层在船用柴油机柱塞上的应用

王永坤^1,2, 秦洪^1,2, 杨静^1,2, 缪学强^1,2, 刘惠娥^1,2, 陈超^1,2

1.重庆红江机械有限责任公司, 重庆 402160;
2.船舶与海洋工程动力系统国家工程实验室, 重庆 402160

收稿日期:2020-04-23 出版日期:2020-11-25 发布日期:2020-12-29
作者简介:王永坤(1987—),男,工程师,硕士,主要研究方向为金属材料表面改性与强化、金属热处理及新型超硬材料设计、合成与检测,E-mail: wyk2008xynu@163.com
基金资助:
工信部“高技术船舶科研计划—船用低速机工程(一期)”(船工科[2017]21号)

Applicant of hydrogenated diamond like coating on plunger for marine diesel engine

Wang Yongkun^1,2, Qin Hong^1,2, Yang Jing^1,2, Miao Xueqiang^1,2, Liu Hui'e^1,2, Chen Chao^1,2

1. Chongqing Hongjiang Machinery Co., Ltd., Chongqing 402160, China;
2. National Engineering Laboratory for Marine Power System, Chongqing 402160, China

Received:2020-04-23 Online:2020-11-25 Published:2020-12-29

摘要/Abstract

摘要： 利用磁控溅射和等离子增强化学气相沉积复合技术,以 Cr、WC、石墨为靶材,Ar和C₂H₂为工作气体,在船用低速柴油机柱塞上涂覆了过渡层依次为Cr、WC的含氢类金刚石涂层。结果表明:涂层晶体生长良好,结构连续致密,均未出现分层、开裂及剥离的现象;涂层相对光滑,大幅度提高了柱塞表面的纳米硬度与弹性模量,同时降低了在重柴油环境下的摩擦因数,长时间的台架试验后未涂覆涂层的柱塞表面出现非常明显的平行状沟槽磨痕,而且整体磨损比较严重,而涂覆涂层的柱塞表面磨痕非常窄且浅,数量较少,类金刚石涂层可以明显提高柱塞表面的耐磨损性能。

关键词: 柱塞, 磁控溅射, 等离子增强化学气相沉积, 含氢类金刚石涂层, 摩擦磨损

Abstract: With Cr, WC and graphite as targets and Ar and C₂H₂ as working gases, hydrogenated diamond like coating with Cr and WC as transition layers was prepared on the plunger of marine diesel engine by composite technology of magnetron sputtering and plasma enhanced chemical vapor deposition. The results show that the crystal of the coating grows well, and continuous with high density, no stratification, cracking or peeling phenomenon can be observed. The coating is relatively smooth, which improves sharply the hardness, elastic modulus and decreases the friction coefficient under heavy diesel oil environment. After the bench test, relatively obvious parallel grooving wear marks appear on the surface of the plunger without coating, and the overall wear is more serious, while the wear marks on the surface of the plunger with coating are very narrow and shallow, which is less in quantity. It is proved that the wear resistance of the plunger surface after preparing diamond like coating is significantly improved.

Key words: plunger, magnetron sputtering, plasma enhanced chemical vapor deposition, hydrogenated diamond like coating, friction and wear

中图分类号:

TG174.444

王永坤, 秦洪, 杨静, 缪学强, 刘惠娥, 陈超. 含氢类金刚石涂层在船用柴油机柱塞上的应用[J]. 金属热处理, 2020, 45(11): 226-231.

Wang Yongkun, Qin Hong, Yang Jing, Miao Xueqiang, Liu Hui'e, Chen Chao. Applicant of hydrogenated diamond like coating on plunger for marine diesel engine[J]. Heat Treatment of Metals, 2020, 45(11): 226-231.

参考文献

[1]王峻森, 王海宽. 精密偶件磨损后对柴油机工作的影响[J]. 农村牧区机械化, 2011(6): 39-40.
[2]孟繁杰, 黄国靖, 王亚平. 柴油机燃油泵柱塞副失效分析[J]. 农业机械学报, 1982(4): 27-35.
Meng Fanjie, Huang Guojing, Wang Yaping. Failure analysis of plunger pairs of fuel pump of diesel engine[J]. Transactions of the Chinese Society of Agricultural Machinery, 1982(4): 27-35.
[3]张鼎明. 柱塞产生穴蚀的原因及预防[J]. 山西农机, 2004(3): 10.
[4]王忠俊, 陈军. 中高速船用柴油机燃用重油的应用[J]. 船海工程, 2010, 39(2): 74-77.
Wang Zhongjun, Chen Jun. Application of high-speed marine diesel engine burned heavy fuel oil[J]. Ship and Ocean Engineering, 2010, 39(2): 74-77.
[5]李伟新. 燃用重油对柴油机的消极影响与应对措施[J]. 柴油机, 2007(4): 61-62.
Li Weixin. Use the heavy oil makes negative influence of fuel to diesel engine and measure[J]. Internal Combustion Engines, 2007(4): 61-62.
[6]张仕明, 欧阳光耀, 王光辉. 船用柴油机燃用重油的问题及其解决措施[J]. 柴油机, 2015, 37(6): 45-47.
[7]薛群基, 王立平. 类金刚石碳基薄膜材料[M]. 北京: 科学出版社, 2012.
[8]Robertson J. Comparison of diamond-like carbon to diamond for applications[J]. Physical Status Solidi, 2008, 205(9): 2233-2244.
[9]Christophe Donnet, Ali Erdemir. Tribology of Diamond-like Carbon Films: Fundamentals and Applications[M]. US: Springer Science and Business Media, 2007.
[10]Gahlin R, Larsson M, Hedenqvist P. Me-C∶H coatings in motor vehicles[J]. Journal of Materials Processing Technology, 2001, 249(3/4): 302-309.
[11]Bauder R, Helbig J, Marckwardt H, et al. The new 3.0-L TDI Biturbo engine from Audi Part 1: Design and engine mechanics[J]. MTZ Worldwide, 2012, 73(1): 26-33.
[12]Boghe M, Carvalho N. Surface engineering for DLC coatings[J]. Auto Technology, 2006, 6(5): 50-53.
[13]武彬, 李骏, 张俊彦, 等. 类金刚石薄膜挺柱的制备与性能[J]. 吉林大学学报: 工学版, 2013(1): 51-55.
Wu Bin, Li Jun, Zhang Junyan, et al. Fabrication and properties of tappet with diamond-like carbon film[J]. Journal of Jilin University (Engineer and Technology Edition), 2013(1): 51-55.
[14]卢求元, 赵俊平. 发动机凸轮表面耐磨减摩薄膜的制备与表征[J]. 金属热处理, 2015, 40(6): 11-15.
Lu Qiuyuan, Zhao Junping. Preparation and characterization of films with high wear resistance and low friction coefficient on engine cam surface[J]. Heat Treatment of Metals, 2015, 40(6): 11-15.
[15]杨义勇, 彭志坚, 付志强, 等. 多组分缓冲层W梯度掺杂DLC复合薄膜研究[J]. 金属学报, 2010, 46(1): 34-40.
Yang Yiyong, Peng Zhijian, Fu Zhiqiang, et al. Study on W graded doping DLC composite film with multicomponent transition layer[J]. Acta Metallurgica Sinica, 2010, 46(1): 34-40.
[16]付志强, 王成彪, 岳文, 等. 钨含量和摩擦条件对掺钨DLC涂层摩擦性能研究[J]. 稀有金属材料与工程, 2011, 40(9): 1584-1588.
Fu Zhiqiang, Wang Chengbiao, Yue Wen, et al. Influences of W content and friction condition on the tribological properties of W-doped DLC coatings[J]. Rare Metal Materials and Engineering, 2011, 40(9): 1584-1588.
[17]Kalish R, Lifshitz Y, Nugent K, et al. Thermal stability and relaxation in diamond-like-carbon. A Raman study of films with different sp³ fractions (Ta-C to a-C)[J]. Applied Physics Letters, 1999, 74(20): 2936-2938.
[18]Irmer G, Dorner-Reisel A. Micro-Raman studies on DLC coatings[J]. Advanced Engineering Materials, 2005, 7(8): 694-705.
[19]Casiraghi C, Ferrari A C, Robertson J. Raman spectroscopy of hydrogenated amorphous carbons[J]. Physical Review B, 2005, 72(8): 1-14.
[20]王福, 谢明玲, 张广安, 等. 含硅无氢非晶碳基薄膜的摩擦磨损性能[J]. 中国表面工程, 2017, 30(1): 93-100.
Wang Fu, Xie Mingling, Zhang Guang'an, et al. Friction and wear properties of Si-containing H-free amorphous carbon-based films[J]. China Surface Engineering, 2017, 30(1): 93-100.
[21]Vidakis N, Antoniadis A, Bilalis N. The VDI-3198 indentation test evaluation of an reliable qualitative control for layered compounds[J]. Journal of Materials Processing Technology, 2003, 143: 481-485.
[22]莫继良, 陈龙, 朱旻昊. WC/C 固体润滑涂层的滑动摩擦磨损性能研究[J]. 材料工程, 2008(8): 13-16.
Mo Jiliang, Chen Long, Zhu Minhao. Friction and wear properties of WC/C solid lubricant coating[J]. Journal of Materials Engineering, 2008(8): 13-16.
[23]李光, 孙跃, 夏立芳, 等. 类金刚石碳膜的摩擦学性能及摩擦机制[J]. 金属热处理, 2001, 26(10): 1-4.
Li Guang, Sun Yue, Xia Lifang, et al. Tribological behavior and mechanism of diamond-like carbon films[J]. Heat Treatment of Metals, 2001, 26(10): 1-4.
[24]卓国海, 柯培玲, 李晓伟, 等. 不同过渡层对DLC薄膜力学性能和摩擦学性能的影响[J]. 中国表面工程, 2015, 28(6): 39-47.
Zhuo Guohai, Ke Peiling, Li Xiaowei, et al. Influence of different interlayers on mechanical and tribological properties of DLC film[J]. China Surface Engineering, 2015, 28(6): 39-47.

含氢类金刚石涂层在船用柴油机柱塞上的应用

Applicant of hydrogenated diamond like coating on plunger for marine diesel engine

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	刘乃瑜, 曹磊, 郑少梅. 不同沉积温度下CrCN涂层的力学性能[J]. 金属热处理, 2022, 47(4): 240-244.
[2]	石铭霄, 王雄栋, 李敬勇, 杨志东, 茅卫东, 倪慧锋. AISI 410钢膏剂渗硼工艺渗层的组织与性能[J]. 金属热处理, 2022, 47(4): 245-250.
[3]	杨文灏, 鲍明东, 唐宾, 王钰鹏, 赵国华, 王帅康, 王铎. 表面粗糙度对磁控溅射纯Cu靶材刻蚀区表面形貌及溅射性能的影响[J]. 金属热处理, 2021, 46(8): 230-235.
[4]	云璐, 郝新. 退火温度对磁控溅射TiN/TiCN薄膜残余应力、结构及耐蚀性能的影响[J]. 金属热处理, 2021, 46(5): 166-170.
[5]	刘冉, 高苑, 吴韬. Al/Si比例对TC4合金表面激光熔覆Ti-Al-Si涂层组织与摩擦性能的影响[J]. 金属热处理, 2021, 46(3): 135-139.
[6]	王钰鹏, 吴泓均, 鲍明东, 田武, 周兵. 非平衡磁控溅射离子镀Cu-Nb纳米晶薄膜的微观结构及性能[J]. 金属热处理, 2021, 46(12): 156-161.
[7]	王钰鹏, 吴泓均, 鲍明东, 杨文灏, 赵国华, 周兵. 磁控溅射Cu-Cr合金薄膜与Sn-Ag-Cu焊料在时效处理时的界面反应[J]. 金属热处理, 2021, 46(11): 103-109.
[8]	余国庆, 景然, 王国迪, 张曼雪, 冯甜, 解念锁. MAO电压对TC4合金氧化膜层摩擦磨损性能的影响[J]. 金属热处理, 2021, 46(11): 126-130.
[9]	陈滋鑫, 周后明, 朱宇旭, 张哲豪, 何方佳, 徐采星, 刘刚. Cr12MoV钢激光熔覆Ni-Al复合涂层的组织及性能[J]. 金属热处理, 2021, 46(11): 226-231.
[10]	沈智, 晏建武, 金康, 周英丽, 殷剑. 制备工艺对超磁致伸缩Fe-Ga合金薄膜表面形貌的影响[J]. 金属热处理, 2021, 46(11): 236-240.
[11]	王钦娟, 林少阳, 陈忠士, 刘东. QPQ技术中渗氮时间对合金铸铁组织及摩擦性能的影响[J]. 金属热处理, 2021, 46(10): 226-231.
[12]	刘瑞霞, 郭锋, 韩海鹏. 铬过渡层对氮化铬/镁合金膜基界面结合强度的影响[J]. 金属热处理, 2021, 46(1): 143-148.
[13]	夏思海, 武美萍, 马毅青, 崔宸. TiC含量对TC4合金激光熔覆层组织和性能的影响[J]. 金属热处理, 2020, 45(6): 212-215.
[14]	王明, 纪红, 卢硕. 金属间化合物Ni₃Al薄膜制备工艺[J]. 金属热处理, 2020, 45(5): 183-186.
[15]	刘冉, 王传婷, 高苑, 韦征杭, 傅超. 时效温度对Ti-29Nb-13Ta-4.6Zr合金组织及摩擦磨损性能的影响[J]. 金属热处理, 2020, 45(4): 124-127.