超音速火焰喷涂NiTi合金涂层的形状记忆效应

doi:10.13251/j.issn.0254-6051.2021.04.032

金属热处理 ›› 2021, Vol. 46 ›› Issue (4): 176-181.DOI: 10.13251/j.issn.0254-6051.2021.04.032

超音速火焰喷涂NiTi合金涂层的形状记忆效应

段学燕¹, 李文利², 覃恩伟¹, 王博¹, 陆海峰¹, 吴树辉¹

1.苏州热工研究院有限公司表面工程研究所, 江苏苏州 215004;
2.苏州大学机电工程学院, 江苏苏州 215004

收稿日期:2020-10-11 出版日期:2021-04-25 发布日期:2021-05-08
通讯作者: 李文利,副教授,博士,E-mail:wlli@suda.edu.cn
作者简介:段学燕(1993—),女,硕士研究生,主要研究方向为功能材料表面改性,激光沉积成型,E-mail:16324469@qq.com。
基金资助:
国家重点研发计划(2016YFB1100200);苏州市重点产业技术创新(SGC201720)

Shape memory effect of NiTi alloy coating deposited by high-velocityoxygen-fuel spraying

Duan Xueyan¹, Li Wenli², Qin Enwei¹, Wang Bo¹, Lu Haifeng¹, Wu Shuhui¹

1. Division for Surface Technology and Engineering, Suzhou Nuclear Power Research Institute Co., Ltd., Suzhou Jiangsu 215004, China;
2. School of Mechanical and Electric Engineering, Suzhou University, Suzhou Jiangsu 215004, China

Received:2020-10-11 Online:2021-04-25 Published:2021-05-08

摘要/Abstract

摘要： 采用超音速火焰喷涂制备超致密NiTi合金涂层,通过后续热处理获得优化相变结构,并通过压痕法分析涂层的形状记忆效应。光学显微镜及扫描电镜对NiTi合金涂层微观结构表征显示,喷涂制备态涂层由内部岛状-链状界面叠片组成,涂层致密孔隙率约为0.82%。X射线衍射分析显示,NiTi涂层制备态为全奥氏体,经时效处理析出Ni₄Ti₃相。压痕法分析表明,在制备态及时效态涂层中均获得了一定的单程及双程形状记忆效应。X射线物相分析及差示扫描量热仪对比分析揭示,时效析出的第二相粒子显著增加形状记忆效应。

关键词: NiTi合金, 形状记忆效应, 超音速火焰喷涂, 压痕法

Abstract: A highly dense NiTi alloy coating was prepared by high-velocity oxygen-fuel (HVOF) spraying, and the microstructure was optimized by subsequent aging treatment. The shape memory effects of the as-HVOF sprayed and as-aged specimens were evaluated through an indentation method. The OM and SEM microstructural characterization show that the as-sprayed NiTi coating consists of laminated internal island-chain interfaces, with a porosity of about 0.82%. The X-ray diffraction analysis shows that the as-sprayed NiTi coating owns 100% austenite, from which the Ni₄Ti₃ phase precipitates out in aging treatment. The indentation analysis shows that both the one-way and the two-way shape memory effects can be induced in the as-sprayed and the aged coatings, while the X-ray phase analysis and the differential scanning calorimetry analysis show that the shape memory effect is significantly increased by the precipitated second phase particles in aging treatment.

Key words: NiTi alloy, shape memory effect, high-velocity oxygen-fuel spraying, indentation method

中图分类号:

TG132

段学燕, 李文利, 覃恩伟, 王博, 陆海峰, 吴树辉. 超音速火焰喷涂NiTi合金涂层的形状记忆效应[J]. 金属热处理, 2021, 46(4): 176-181.

Duan Xueyan, Li Wenli, Qin Enwei, Wang Bo, Lu Haifeng, Wu Shuhui. Shape memory effect of NiTi alloy coating deposited by high-velocityoxygen-fuel spraying[J]. Heat Treatment of Metals, 2021, 46(4): 176-181.

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超音速火焰喷涂NiTi合金涂层的形状记忆效应

Shape memory effect of NiTi alloy coating deposited by high-velocityoxygen-fuel spraying

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