金属热处理 ›› 2021, Vol. 46 ›› Issue (10): 133-136.DOI: 10.13251/j.issn.0254-6051.2021.10.023

• 工艺研究 • 上一篇    下一篇

提高Cr-Ni-Co-Mo马氏体时效不锈钢超低温韧性的热处理工艺

吉昱睿1,2, 杨卓越2, 谭红琳1, 丁雅莉2   

  1. 1.昆明理工大学 材料科学与工程学院, 云南 昆明 650093;
    2.钢铁研究总院 特殊钢研究所, 北京 100081
  • 收稿日期:2021-05-07 出版日期:2021-10-25 发布日期:2021-12-08
  • 通讯作者: 杨卓越,教授级高工,博士,E-mail:Yangzhuoyue@ nercast.com
  • 作者简介:吉昱睿(1995—),男,硕士研究生,主要研究方向为超低温用高强不锈钢的韧化工艺,E-mail:1119258030@qq.com

Heat treatment process for improving cryogenic toughness of Cr-Ni-Co-Mo maraging stainless steel

Ji Yurui1,2, Yang Zhuoyue2, Tan Honglin1, Ding Yali2   

  1. 1. Faculty of Materials Science and Engineering, Kunming University of Science and Technology, Kunming Yunnan 650093, China;
    2. Special Steels Research Institute, Central Iron and Steel Research Institute, Beijing 100081, China
  • Received:2021-05-07 Online:2021-10-25 Published:2021-12-08

摘要: 研究了改善Cr-Ni-Co-Mo马氏体时效不锈钢超低温韧性的热处理工艺,即1000 ℃固溶处理后分别进行600 ℃预保温+750 ℃低温固溶处理和一次或两次直接750 ℃低温固溶处理,分析了马氏体、残留奥氏体和逆转变奥氏体含量的变化以及室温和-196 ℃抗拉强度、-196 ℃缺口抗拉强度和冲击性能。结果表明:与常规热处理工艺相比,增加750 ℃低温固溶处理后试验钢中含有较多的残留奥氏体,再经500 ℃时效后可形成更多的逆转变奥氏体,更多的残留奥氏体/逆转变奥氏体含量起到韧化作用,可显著改善试验钢的超低温韧性。进一步对比分析表明,直接进行750 ℃固溶处理工艺过程相对简单,室温和-196 ℃抗拉强度最高,-196 ℃缺口抗拉强度也最高,且缺口敏感性较低,因此更具有优势。

关键词: 马氏体时效不锈钢, 超低温韧性, 低温固溶处理, 残留奥氏体, 逆转变奥氏体

Abstract: Heat treatment processes to improve the cryogenic toughness of Cr-Ni-Co-Mo maraging stainless steel were investigated, including preheating at 600 ℃+low temperature solution treatment at 750 ℃, and direct solution treating once or twice at 750 ℃ without preheating respectively, all after solution treatment at 1000 ℃. The volume fractions of martensite, retained austenite and reversed austenite phases were determined respectively, and the tensile strength at room temperature and -196 ℃, the notched tensile strength and impact toughness at -196 ℃ were analyzed. The results show that compared with the conventional heat treatment, more retained austenite exists in the steel after adding low temperature solution treatment at 750 ℃. Moreover, more reversed austenite is formed after subsequently aging at 500 ℃, which can significantly improve the cryogenic toughness. Further comparative analysis shows that the process of direct solution treatment at 750 ℃ is relatively simple, which can lead to the highest tensile strength at both room temperature and -196 ℃, the highest notch tensile strength at -196 ℃, and lower notch sensitivity at -196 ℃. Therefore, the direct solution treatment at 750 ℃ has advantage over other treatments.

Key words: maraging stainless steel, cryogenic toughness, low temperature solution treatment, retained austenite, reversed austenite

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