马氏体钢中BL/M和AR/M复相组织调控方法及对性能影响的研究现状

doi:10.13251/j.issn.0254-6051.2021.07.014

摘要/Abstract

摘要： 综述了提高钢铁材料性能的马氏体钢中下贝氏体/马氏体(B_L/M)和残留奥氏体/马氏体(A_R/M)复相组织的调控方法及其强韧化机理等方面的研究进展。针对贝氏体等温淬火、淬火-配分(Q&P)、淬火-配分-回火(Q-P-T)等新型热处理工艺对微观组织特征和力学性能影响的研究现状进行了总结,并分析了钢铁材料复相组织调控工业化应用需重点突破的问题。

关键词: 复相组织控制, 贝氏体等温淬火, Q&P工艺, Q-P-T工艺

Abstract: The research progress of the lower bainite/martensite (B_L/M) and retained austenite/martensite (A_R/M) multiphase controlling methods to improve the properties of steels and the corresponding strengthening and toughening mechanisms were summarized in detail. The new heat treatment methods such as bainite isothermal quenching, quenching & partitioning (Q&P), quenching-partitioning-tempering (Q-P-T) were introduced. Also, the effects of multiphase controlling methods on microstructural characteristics and mechanical properties, as well as the key breakthrough problems in industrial application of the new heat treatments, were analyzed.

Key words: multiphase controlling, bainite isothermal quenching, quenching & partitioning process, quenching-partitioning-tempering process

中图分类号:

TG156.1

魏鑫鸿, 李志敏, 张旭, 何文超, 王永恒, 郭涵, 李绍宏. 马氏体钢中B_L/M和A_R/M复相组织调控方法及对性能影响的研究现状[J]. 金属热处理, 2021, 46(7): 72-78.

Wei Xinhong, Li Zhimin, Zhang Xu, He Wenchao, Wang Yongheng, Guo Han, Li Shaohong. Research progress of B_L/M and A_R/M multiphase controlling methods in martensitic steel and their influence on performance[J]. Heat Treatment of Metals, 2021, 46(7): 72-78.

参考文献

[1] 安佰锋. 经济型高强韧贝/马复相钢的研究与应用[D]. 北京: 北京交通大学, 2016.
An Baifeng. Research and application on low-cost high strength and toughness of bainite/martensite multiphase steel[D]. Beijing: Beijing Jiaotong University, 2016.
[2] 陈梦圆, 刘卓, 吴润, 等. 配分时间对Q&P钢组织及性能的影响[J]. 金属热处理, 2020, 45(9): 62-65.
Chen Mengyuan, Liu Zhuo, Wu Run, et al. Effect of partitioning time on microstructure and properties of Q&P steel[J]. Heat Treatment of Metals, 2020, 45(9): 62-65.
[3] 朱飞. 高强塑积热轧双相钢组织调控研究[D]. 马鞍山: 安徽工业大学, 2017.
Zhu Fei. The study of microstructure control on hot-rolled dual-phase steel with high product of strength and elongation[D]. Ma'anshan: Anhui University of Technology, 2017.
[4] Dong Han. High performance steels: Initiative and practice[J]. Science China(Technological Sciences), 2012, 55(7): 1774-1790.
[5] 马后逾. 1200 MPa级低合金复相钢的组织多尺度细化与性能[D]. 马鞍山: 安徽工业大学, 2013.
Ma Houyu. Multi-scale microstructure refinement and mechanical properties of 1200 MPa low alloy multi-phase steels[D]. Ma'anshan: Anhui University of Technology, 2013.
[6] 张超, 郭辉, 王家星, 等. 等温淬火温度对超细贝氏体钢组织及耐磨性的影响[J]. 工程科学学报, 2018, 40(12): 1502-1509.
Zhang Chao, Guo Hui, Wang Jiaxing, et al. Effect of austempering temperature on the microstructure and wear resistance of ultrafine bainitic steel[J]. Chinese Journal of Engineering, 2018, 40(12): 1502-1509.
[7] Liu K, He T Q, Wan X L, et al. The effect of isothermal holding on the microstructures and mechanical properties of a low carbon alloy steel[J]. Materials Characterization, 2011, 62(3): 340-345.
[8] 陈建志. 贝氏体/马氏体复相EA4T钢微观组织与疲劳性能研究[D]. 沈阳: 东北大学, 2016.
Chen Jianzhi. Microstructures and fatigue properties of bainite/martensite EA4T steels[D]. Shenyang: Northeastern University, 2016.
[9] Wang K, Tan Z, Gao G, et al. Microstructure-property relationship in bainitic steel: The effect of austempering[J]. Materials Science and Engineering A, 2016, 675: 120-127.
[10] Matas S, Hehemann R F. Retained austenite and the tempering of martensite[J]. Nature, 1960, 187(4738): 685-686.
[11] 钟宁. 高强度Q&P钢和Q-P-T钢的研究[D]. 上海: 上海交通大学, 2009.
Zhong Ning. Research on high strength Q&P and Q-P-T steels[D]. Shanghai: Shanghai Jiao Tong University, 2009.
[12] Speer J G, Matlock D K, De Cooman B C, et al. Carbon partitioning into austenite after martensite transformation[J]. Acta Materialia, 2003, 51(9): 2611-2622.
[13] Matlock D K, Brautigam V E, Speer J G, et al. Application of the quenching and partitioning (Q&P) process to amedium-carbon, high-Si microalloyedbar steel[J]. Materials Science Forum, 2003, 426-432: 1089-1094.
[14] Clarke A J, Speer J G, Miller M K, et al. Carbon partitioning to austenite from martensite or bainite during the quench and partition (Q&P) process: A critical assessment[J]. Acta Materialia, 2008, 56(1): 16-22.
[15] 王存宇, 解西强, 刘苏, 等. Q&P工艺研究现状[J]. 钢铁研究学报, 2009, 21(9): 6-11.
Wang Cunyu, Jie Xiqiang, Liu Su, et al. Present status of quenching and partitioning process[J]. Journal of Iron and Steel Research, 2009, 21(9): 6-11.
[16] Speer J G, Edmonds D V, Rizoo F C, et al. Partitioning of carbon from supersaturated plates of ferrite, with application to steel processing and fundamentals of the bainite transformation[J]. Current Opinion in Solid State and Materials Science, 2004, 8(3/4): 219-237.
[17] Hillert M, Höglund L,Ågren J. Escape of carbon from ferrite plates in austenite[J]. Acta Metallurgica et Materialia, 1993, 41(7): 1951-1957.
[18] Hillert M,Ågren J. On the definitions of paraequilibrium and orthoequilibrium[J]. Scripta Materialia, 2004, 50(5): 697-699.
[19] 吴化. 低合金高强度高塑性复相钢材的成分设计[D]. 上海: 东华大学, 2007.
Wu Hua. Composition design of low alloy high strength and plasticity complex phase steels[D]. Shanghai: Donghua University, 2007.
[20] Zhong N, Wang X, Rong Y, et al. Interface migration between martensite and austenite during quenching and partitioning (Q&P) process[J]. Journal of Materials Science and Technology, 2006, 22(6): 751-754.
[21] 徐祖耀. 淬火-碳分配-回火(Q-P-T)工艺浅介[J]. 金属热处理, 2009, 34(6): 1-8.
Xu Zuyao. A brief introduction to quenching-partitioning-tempering(Q-P-T) process[J]. Heat Treatment of Metals, 2009, 34(6): 1-8.
[22] 刘成龙. 300M钢的Q-P和Q-P-T热处理工艺研究[D]. 沈阳: 东北大学, 2014.
Liu Chenglong. Studies on the Q-P and Q-P-T heat treatment processes of 300M steels[D]. Shenyang: Northeastern University, 2014.
[23] 郭元钧, 黄继富. 65Mn钢马氏体/下贝氏体复相组织和性能[J]. 南昌大学学报, 1987, 9(2): 67-74.
Guo Yuanjun, Huang Jifu. The martensite/lower bainite duplex structure of steel 65Mn and its mechanical properties[J]. Journal of Nanchang University, 1987, 9(2): 67-74.
[24] 王琦, 卢军, 邹忠华. Cr12MoV 钢马氏体/贝氏体复相热处理工艺研究[J]. 金属热处理, 2011, 36(10): 63-65.
Wang Qi, Lu Jun, Zou Zhonghua. Heat treatment of martensite/bainite dual phase of Cr12MoV steel[J]. Heat Treatment of Metals, 2011, 36(10): 63-65.
[25] 杨福宝, 白秉哲, 刘东雨, 等. 无碳化物贝氏体/马氏体复相高强度钢的组织与性能[J]. 金属学报, 2004, 40(3): 296-300.
Yang Fubao, Bai Bingzhe, Liu Dongyu, et al. Microstructure and properties of a carbide-free bainite/martensiteultra-high strength steel[J]. Acta Metallurgiga Sinica, 2004, 40(3): 293-300.
[26] 许伯藩. 55SiMnVB钢复相热处理的组织与性能的研究[J]. 武汉钢铁学院学报, 1987(3): 34-41.
Xu Bofan. A study on the texture and performance of the 55SiMnVB steel during heterogeneous heat treatment[J]. Journal of Wuhan University of Science and Technology, 1987(3): 34-41.
[27] 周莲, 沈国兴, 徐杰. 中碳低合金钢的马氏体与下贝氏体复相组织研究[J]. 上海金属, 1988, 10(4): 36-41.
[28] 郭元钧, 黄继富. 65Mn钢马氏体/下贝氏体复相组织的韧性和耐磨性[J]. 材料热处理学报, 1991, 12(1): 8-15.
Guo Yuanjun, Huang Jifu. The toughness and wear resistance for the martensite-lower bainite dual phase structure of 65Mn steel[J]. Transactions of Materials and Heat Treatment, 1991, 12(1): 8-15.
[29] 林化春. Cr12钢马氏体/贝氏体复相处理强韧化及应用[J]. 金属热处理, 1997, 26(5): 11-12, 18.
Lin Huachun. Strengthening and toughening technique and application on (M/B) dual-phase heat treating of Cr12 steel[J]. Heat Treatment of Metals, 1997, 26(5): 11-12, 18.
[30] Tomita Yoshiyuki, Okabayashi Kunio. Heat treatment for improvement in lower temperature mechanical properties of 0.40 pct C-Cr-Mo ultrahigh strength steel[J]. Metallurgical Transactions A, 1983, 14(11): 2387-2393.
[31] Tomita Yoshiyuki, Okabayashi Kunio. Improvement in lower temperature mechanical properties of 0.40 pct C-Ni-Cr-Mo ultrahigh strength steel with the second phase lower bainite[J]. Metallurgical Transactions A, 1983, 14(2): 485-492.
[32] Tomita Yoshiyuki, Okabayashi Kunio. Mechanical properties of 0.40 pct C-Ni-Cr-Mo high strength steel having a mixed structure of martensite and bainite[J]. Metallurgical Transactions A, 1985, 16(1): 73-82.
[33] 秦晓峰, 朱洪武, 周乐育, 等. FF710钎具钢下贝氏体/马氏体复相组织的控制[J]. 材料热处理学报, 2013, 34(S2): 111-116.
Qin Xiaofeng, Zhu Hongwu, Zhou Leyu, et al. Control of lower bainite/martensite duplex structure of the FF710 drill steel[J]. Transactions of Materials and Heat Treatment, 2013, 34(S2): 111-116.
[34] Wang K, Tan Z, Gu K, et al. Effect of deep cryogenic treatment on structure-property relationship in an ultrahigh strength Mn-Si-Cr bainite/martensite multiphase rail steel[J]. Materials Science and Engineering A, 2017, 684: 559-566.
[35] 李玲慧, 周青春, 计天予, 等. 高硅马氏体型热作模具钢贝氏体等温工艺的研究[J]. 上海金属, 2012, 34(5): 20-24.
Li Linghui, Zhou Qingchun, Ji Tianyu, et al. Bainite isothermal process for martensitic hot working die steel containing high Si content[J]. Shanghai Metals, 2012, 34(5): 20-24.
[36] Dan W, Zhang W, Liu F. Constitutive model for multi-phase high strength steels[J]. Procedia Engineering, 2014, 81: 1204-1209.
[37] 孙培祯, 文翠娥, 赵建生, 等. 马氏体/下贝氏体复相热处理对GD钢强韧性的影响[J]. 材料热处理学报, 1991, 12(3): 1-5.
Sun Peizhen, Wen Cui'e, Zhao Jiansheng, et al. Effect of dual phase heat treatment of martensite lower bainite on strength and toughness of GD steel[J]. Transactions of Materials and Heat Treatment, 1991, 12(3): 1-5.
[38] 解西强, 高文涛, 时捷, 等. Q-P淬火和分配工艺对25Si2Ni3钢组织和力学性能的影响[J]. 特殊钢, 2008, 163(5): 56-58.
Jie Xiqiang, Gao Wentao, Shi Jie, et al. Effect of quenching and partition (Q&P) process on structure and mechanical properties of steel 25Si2Ni3[J]. Special Steel, 2008, 163(5): 56-58.
[39] 刘敬广. 具有TRIP效应的热轧Q&P钢组织与力学性能研究[D]. 济南: 山东建筑大学, 2013.
Liu Jingguang. Research on microstructures and mechanical properties of hot rolled quenching and partitioning steel with TRIP effect[J]. Jinan: Shandong Jianzhu University, 2013.
[40] Paravicini E Bagliani, Santofimia M J, Zhao L, et al. Microstructure, tensile and toughness properties after quenching and partitioning treatments of a medium-carbon steel[J]. Materials Science and Engineering A, 2013, 559: 486-495.
[41] Pierce D T, Coughlin D R, Williamson D L, et al. Quantitative investigation into the influence of temperature on carbide and austenite evolution during partitioning of a quenched and partitioned steel[J]. Scripta Materialia, 2016, 121: 5-9.
[42] Wang Zijian, Wang Kai, Liu Yong, et al. Multi-scale simulation for hot stamping quenching & partitioning process of high-strength steel[J]. Journal of Materials Processing Technology, 2019, 269: 150-162.
[43] Wang X D, Guo Z H, Rong Y H. Mechanism exploration of an ultrahigh strength steel by quenching-partitioning-tempering process[J]. Materials Science and Engineering A, 2011, 529: 35-40.
[44] Wang X D, Zhong N, Rong Y H, et al. Novel ultrahigh-strength nanolath martensitic steel by quenching-partitioning-tempering process[J]. Journal of Materials Research, 2009, 24(1): 260-267.
[45] Zhong N, Wang X D, Wang L, et al. Enhancement of the mechanical properties of a Nb-microalloyed advanced high-strength steel treated by quenching-partitioning-tempering process[J]. Materials Science and Engineering A, 2008, 506(1): 111-116.
[46] 黎雨, 李伟, 金学军. 淬火-配分-回火QPT钢的研究进展[J]. 中国材料进展, 2019, 38(7): 631-640, 650.
Li Yu, Li Wei, Jin Xuejun. Review of quenching-partitioning-tempering (QPT) steels[J]. Materials China, 2019, 38(7): 631-640, 650.
[47] 张柯. 高强塑积Q-P-T钢及其强塑性机制的研究[D]. 上海: 上海交通大学, 2011.
Zhang Ke. High product of strength and elongation of steels treated by quenching-partitioning-tempering process and the mechanism of strength and ductility[D]. Shanghai: Shanghai Jiao Tong University, 2011.
[48] Zhang Ke, Zhang Meihan, Guo Zhenghong, et al. A New effect of retained austenite on ductility enhancement in high-strength quenching-partitioning-tempering martensitic steel[J]. Materials Science and Engineering A, 2011, 528(29): 8486-8491.
[49] Bhadeshia H K D H. Computational design of advanced steels[J]. Scripta Materialia, 2014, 70: 12-17.
[50] Zheng Hui, Li Wei, Gong Yu. Microstructure-based finite element modeling of effect of metastable austenite on mechanical properties of quenching and partitioning (Q&P) 980 steel[J]. Journal of Iron and Steel Research, International, 2018, 25(11): 1140-1148.
[51] Li Y, Li W, Liu W, et al. The austenite reversion and Co-precipitation behavior of an ultra-low carbon medium manganese quenching-partitioning-tempering steel[J]. Acta Materialia, 2018, 146: 126-141.
[52] Li Y, Li W, Min N, et al. Effects of hot/cold deformation on the microstructures and mechanical properties of ultra-low carbon medium manganese quenching-partitioning-tempering steels[J]. Acta Materialia, 2017, 139: 96-108.
[53] 戎咏华, 陈乃录. 淬火-分配-回火工艺和多循环淬火-分配-回火工艺[J]. 热处理, 2011, 26(5): 1-10.
Rong Yonghua, Chen Nailu. Quenching-partitioning-tempering and multicycle quenching-partioning-tempering processes[J]. Heat Treatment, 2011, 26(5): 1-10.
[54] 吕宇鹏, 李阳. 钢的淬火-分配(Q-P)处理工艺科技发展报告[R] //山东省科学技术协会. 山东省材料发展报告2010~2011. 北京: 中国建材工业出版社, 2012: 360-365.
[55] 李阳, 吕宇鹏, 李士同. 钢的淬火-分配(Q-P)处理研究现状与进展[J]. 金属热处理, 2010, 35(4): 65-68.
Li Yang, Lü Yupeng, Li Shitong. Study status and process of quenching and portioning (Q-P) heat treatment for steel[J]. Heat Treatment of Metals, 2010, 35(4): 65-68.