脉冲频率对铝基PEO涂层隔热性能的影响规律及作用机理

doi:10.13251/j.issn.0254-6051.2021.07.038

金属热处理 ›› 2021, Vol. 46 ›› Issue (7): 195-200.DOI: 10.13251/j.issn.0254-6051.2021.07.038

脉冲频率对铝基PEO涂层隔热性能的影响规律及作用机理

朱剑威^1,2, 齐少豹³, 李国栋^1,2, 王志坚³, 马飞³, 祁同晖³, 李志杰³, 李光^1,2, 夏原^1,2

1.中国科学院力学研究所, 北京 100190;
2.中国科学院大学材料科学与光电工程中心, 北京 100049;
3.潍柴动力股份有限公司, 山东潍坊 261061

收稿日期:2021-03-16 出版日期:2021-07-25 发布日期:2021-12-10
通讯作者: 夏原,研究员,博士,E-mail:xia@imech.ac.cn
作者简介:朱剑威(1995—),男,硕士研究生,主要研究方向为材料表面改性、等离子体电解氧化等,E-mail:zhujianwei@imech.ac.cn。
基金资助:
国家自然科学基金(51871230,51701229)

Effect and mechanism of pulse frequency on thermal property of aluminum based plasma electrolytic oxidation coating

Zhu Jianwei^1,2, Qi Shaobao³, Li Guodong^1,2, Wang Zhijian³, Ma Fei³, Qi Tonghui³, Li Zhijie³, Li Guang^1,2, Xia Yuan^1,2

1. Institute of Mechanics, Chinese Academy of Sciences, Beijing 100190, China;
2. Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Science, Beijing 100049, China;
3. Weichai Power Co., Ltd., Weifang Shandong 261061, China

Received:2021-03-16 Online:2021-07-25 Published:2021-12-10

摘要/Abstract

摘要： 在硅酸盐体系下使用等离子体电解氧化(PEO)技术在ZL109铝合金试样表面进行了陶瓷化处理,并采用SEM、XRD、DSC、激光导热仪等方法系统地研究了脉冲频率变化对PEO涂层热性能的影响规律及作用机理。研究表明,脉冲频率主要通过影响涂层的相结构组成及显微结构从而引起隔热性能的变化。当频率为200 Hz时,PEO涂层的热导率最低,为0.113 W/(m·K)。

关键词: ZL109铝合金, 等离子体电解氧化(PEO), 脉冲频率, 体积热容, 热导率

Abstract: A ceramic coating was prepared on the surface of ZL109 aluminum alloy by using plasma electrolytic oxidation (PEO) in silicate system. The effect and mechanism of different pulse frequencies on heat capacity and heat conductivity were studied by means of SEM, XRD, DSC and laser-flash apparatus (LFA). The results indicate that the changes in thermal properties of the coating are mainly influenced by microstructure and phase structure constituent which is mainly related to the pulse frequency. When the frequency is 200 Hz, PEO coating has a low heat conductivity of 0.113 W/(m·K).

Key words: ZL109 aluminum alloy, plasma electrolytic oxidation (PEO), pulse frequency, heat capacity, heat conductivity

中图分类号:

TG142.1

朱剑威, 齐少豹, 李国栋, 王志坚, 马飞, 祁同晖, 李志杰, 李光, 夏原. 脉冲频率对铝基PEO涂层隔热性能的影响规律及作用机理[J]. 金属热处理, 2021, 46(7): 195-200.

Zhu Jianwei, Qi Shaobao, Li Guodong, Wang Zhijian, Ma Fei, Qi Tonghui, Li Zhijie, Li Guang, Xia Yuan. Effect and mechanism of pulse frequency on thermal property of aluminum based plasma electrolytic oxidation coating[J]. Heat Treatment of Metals, 2021, 46(7): 195-200.

参考文献

[1] 刘泽泽, 朱新河, 程东, 等. 高脉冲能量下ZL109铝合金微弧氧化陶瓷膜特性[J]. 金属热处理, 2017, 42(6): 28-32.
Liu Zeze, Zhu Xinhe, Cheng Dong, et al. Properties of micro-arc oxidation ceramic coating on ZL109 aluminum alloy surface under high pulsed energy[J]. Heat Treatment of Metals, 2017, 42(6): 28-32.
[2] 张波, 陈伟, 吴广新. 新型铝合金的组织与耐磨性能研究[J]. 上海金属, 2020, 42(1): 50-54.
Zhang Bo, Chen Wei, Wu Guangxin. Microstructure and wear resistance of a new type of aluminum alloy[J]. Shanghai Metals, 2020, 42(1): 50-54.
[3] 龚建飞, 胡正前, 马晋. 耐热铸造铝合金微弧氧化工艺特性研究[J]. 轻合金加工技术, 2005, 33(9): 43-45.
Gong Jianfei, Hu Zhengqian, Ma Jin. Research on technology conditions of microarc oxidation of heat-resistant cast aluminium alloys[J]. Light Alloy Fabrication Technology, 2005, 33(9): 43-45.
[4] 肖佑涛. 天然气发动机用铝活塞材料微弧氧化工艺及CeO₂掺杂性能研究[D]. 成都: 西南石油大学, 2018.
[5] Saikiran A, Hariprasad S, Arun S, et al. Effect of electrolyte composition on morphology and corrosion resistance of plasma electrolytic oxidation coatings on aluminized steel[J]. Surface and Coatings Technology, 2019, 372: 239-251.
[6] Yerokhin A L, Nie X, Leyland A, et al. Plasma electrolysis for surface engineering[J]. Surface and Coatings Technology, 1999, 122(2): 73-93.
[7] Zhong Y, Shi L, Li M, et al. Characterization and thermal shock behavior of composite ceramic coating doped with ZrO₂ particles on TC4 by micro-arc oxidation[J]. Applied Surface Science, 2014, 311: 158-163.
[8] 马春生, 程东, 刘泽泽, 等. ZL109铝合金微弧氧化耐磨陶瓷层的工艺优化[J]. 材料热处理学报, 2017, 38(7): 160-166.
Ma Chunsheng, Cheng Dong, Liu Zeze, et al. Process optimization of micro arc oxidation wear resistant ceramic films on ZL109 aluminum alloy[J]. Transactions of Materials and Heat Treatment, 2017, 38(7): 160-166.
[9] 吴煦, 牟仁德, 王开军. 三元共掺杂对YSZ热障涂层热物理性能的影响[J]. 航空材料学报, 2019, 39(2): 49-54.
Wu Xu, Mu Rende, Wang Kaijun. Influence of ternary co-doping on thermo-physical properties of YSZ thermal barrier coatings[J]. Journal of Aeronautical Materials, 2019, 39(2): 49-54.
[10] 史建公, 刘志坚, 李卫红, 等. γ-Al₂O₃转化为α-Al₂O₃热力学分析[J]. 化学世界, 2014, 55(7): 385-388.
Shi Jiangong, Liu Zhijian, Li Weihong, et al. Thermodynamic analysis of phase transition of γ-Al₂O₃ to α-Al₂O₃[J]. Chemical World, 2014, 55(7): 385-388.
[11] 刘静静, 李远兵, 李亚伟, 等. 隔热材料的热导率与孔径分布的相关性研究[J]. 耐火材料, 2016, 50(5): 335-339.
Liu Jingjing, Li Yuanbing, Li Yawei, et al. Correlation of thermal conductivity and pore size distribution of insulating refractories[J]. Refractories, 2016, 50(5): 335-339.

脉冲频率对铝基PEO涂层隔热性能的影响规律及作用机理

Effect and mechanism of pulse frequency on thermal property of aluminum based plasma electrolytic oxidation coating

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