热变形工艺对铈-硫易切削不锈钢中硫化物形态演变的影响

doi:10.13251/j.issn.0254-6051.2022.10.016

金属热处理 ›› 2022, Vol. 47 ›› Issue (10): 99-106.DOI: 10.13251/j.issn.0254-6051.2022.10.016

热变形工艺对铈-硫易切削不锈钢中硫化物形态演变的影响

王英虎^1,2,3, 郑淮北^1,2, 宋令玺^1,2, 刘庭耀^1,2

1.成都先进金属材料产业技术研究院股份有限公司, 四川成都 610000;
2.海洋装备用金属材料及其应用国家重点实验室, 辽宁鞍山 114009;
3.北京科技大学国家材料服役安全科学中心, 北京 100083

收稿日期:2022-05-07 修回日期:2022-08-16 出版日期:2022-10-25 发布日期:2022-12-15
作者简介:王英虎(1992—),男,工程师,博士研究生,主要研究方向为先进金属材料及加工技术,E-mail:hihihowareyou@163.com

Influence of thermal deformation process on morphology evolution of sulfide in cerium-sulfur containing free-cutting stainless steel

Wang Yinghu^1,2,3, Zheng Huaibei^1,2, Song Lingxi^1,2, Liu Tingyao^1,2

1. Chengdu Advanced Metal Material Industry Technology Research Institute Co., Ltd., Chengdu Sichuan 610000, China;
2. State Key Laboratory of Metal Material for Marine Equipment and Application, Anshan Liaoning 114009, China;
3. National Center for Materials Service Safety, University of Science and Technology Beijing, Beijing 100083, China

Received:2022-05-07 Revised:2022-08-16 Online:2022-10-25 Published:2022-12-15

摘要/Abstract

摘要： 使用Gleeble-3500热模拟试验机、光学显微镜及Phenom Partical X扫描电镜能谱仪研究了热变形工艺对铈-硫易切削不锈钢中硫化物形态演变的影响。铈-硫易切削不锈钢铸坯中的硫化物呈球形、椭球形、纺锤形或短棒状并以簇状形式沿晶界分布,属于第Ⅱ类硫化物。在800~1100 ℃温度范围内,随着变形量的增加,硫化物的分布密度逐渐增加,平均面积逐渐减小。在800~1000 ℃温度范围内,随着变形量从10%增加到70%,长宽比≤3的硫化物所占比例逐渐减小,当变形温度为1100 ℃并且变形量增加到70%时,长宽比≤3的硫化物所占比例又略有增加,硫化物发生熔断或重新形核。在10%~70%变形范围内,硫化物的相对塑性升高,在30%变形量达到峰值后又逐渐降低。在800~1100 ℃温度范围内,当变形量不变时,硫化物的相对塑性随变形温度的增加而降低。高温大变形更容易得到均匀弥散细小的硫化物。

关键词: 热变形工艺, 易切削不锈钢, 硫化物, 长宽比, 相对塑性

Abstract: Influence of thermal deformation process on morphology evolution of sulfide in cerium-sulfur containing free-cutting stainless steel was studied by means of Gleeble-3500, OM and Phenom Partical X SEM-EDS. The sulfides in cerium-sulfur containing free-cutting stainless steel casting billet are spherical, ellipsoidal, spindle shape or short-bar-like, and distributed in clusters along the grain boundary, belonging to a type II sulfide. At the temperature ranging from 800 ℃ to 1100 ℃, the distribution density of sulfide increases and the average area decreases with the increase of deformation. At the temperature ranging amount from 800 ℃ to 1000 ℃, the proportion of sulfide with length-width ratio≤3 gradually decreases with the increase of deformation amount from 10% to 70%. When the deformation temperature is 1100 ℃ and the deformation increases to 70%, the proportion of sulfide with length-width ratio≤3 increases slightly, and the sulfide melts or re-nucleates. When the deformation amount is in the range of 10%-70%, the relative plasticity of sulfide increases and then decreases gradually after reaching the peak value at 30% deformation. At the temperature ranging from 800 ℃ to 1100 ℃, the relative plasticity of sulfide decreases with the increase of deformation temperature when the deformation amount is constant.It is easier to obtain uniformly dispersed fine sulfide at high temperature and large deformation.

Key words: thermal deformation process, free-cutting stainless steel, sulfide, length-width ratio, relative plasticity

中图分类号:

TG142.7

王英虎, 郑淮北, 宋令玺, 刘庭耀. 热变形工艺对铈-硫易切削不锈钢中硫化物形态演变的影响[J]. 金属热处理, 2022, 47(10): 99-106.

Wang Yinghu, Zheng Huaibei, Song Lingxi, Liu Tingyao. Influence of thermal deformation process on morphology evolution of sulfide in cerium-sulfur containing free-cutting stainless steel[J]. Heat Treatment of Metals, 2022, 47(10): 99-106.

参考文献

[1]杨文, 杨小刚, 张立峰, 等. 钢中MnS夹杂物控制综述[J]. 炼钢, 2013, 29(6): 71-78.
Yang Wen, Yang Xiaogang, Zhang Lifeng, et al. Review of control of MnS inclusions in steel[J]. Steelmaking, 2013, 29(6): 71-78.
[2]Ånmark N, Karasev A, Jönsson P G. The effect of different non-metallic inclusions on the machinability of steels[J]. Materials, 2015, 8(2): 751-783.
[3]Katayama S. Effect of tool materials on surface machined roughness and cutting force of low-carbon resulfurized free-machining steels[J]. ISIJ International, 2007, 30(4): 331-337.
[4]李代钟. 钢中硫化物夹杂物球化和对钢性能的影响[J]. 钢铁研究学报, 1992, 4(2): 97-101.
Li Daizhong. Globularzing of sulfide inclusions and its influence on the properties of steel[J]. Journal of Iron and Steel Research, 1992, 4(2): 97-101.
[5]尤大利, 崔衡, 吴华杰, 等. 汽车用含硫非调质钢中夹杂物的研究[J]. 钢铁钒钛, 2013 (1): 79-84.
You Dali, Cui Heng, Wu Huajie, et al. Research on inclusions in non-quenched and tempered sulfur-bearing steel for autos[J]. Tron Steel Vanadium Titanium, 2013(1): 79-84.
[6]吴华杰, 岳峰, 尤大利, 等. Mn/S对含硫非调质钢中硫化物形态的影响[J]. 北京科技大学学报, 2014, 36(S1): 77-82.
Wu Huajie, Yue Feng, You Dali, et al. Effect of Mn/S on sulfide inclusions in non-quenched and tempered steel containing sulfur[J]. Journal of University of Science and Technology Beijing, 2014, 36(S1): 77-82.
[7]Domizzi G, Anteri G, Ovejero G J. Influence of sulphur content and inclusion distribution on the hydrogen induced blister cracking in pressure vessel and pipeline steels[J]. Corrosion Science, 2001, 43(2): 325-339.
[8]Valdez M E, Wang Y, Sridhar S. In-situ observation of the formation of MnS during solidification of high sulphur steels[J]. Steel Research International, 2004, 75(4): 247-256.
[9]Masayuki H, Hiroshi H, Hideo K. Development of lead free micro alloyed steel for crank shafts[J]. Nippon Steel Technical Report, 2003, 88(1): 76-80.
[10]朱强斌, 李杰, 邓向阳, 等. 镁系易切削钢中夹杂物分析[J]. 钢铁钒钛, 42(2): 179-192.
Zhu Qiangbin, Li Jie, Deng Xiangyang, et al. Inclusion analysis in magnesium free-cutting steel[J]. Iron Steel Vanadium Titanium, 42(2): 179-192.
[11]Ito Y, Matsubara N, Matsubara K. Formation of manganese sulfide in steel[J]. Transactions of the Iron and Steel Insitute of Japan, 1981, 21(7): 477-484.
[12]Ito Y, Yonezawa N, Matsubara K. Formation of manganese sulfide in low carbon steel[J]. Tetsuto Hagane, 1982, 68(10): 1569-1577.
[13]Liu H, Chen W. Effect of total oxygen content on the machinability of low carbon resulfurized free cutting steel[J]. Steel Research International, 2012, 83(12): 1172-1179.
[14]Shao X, Wang X, Jiang M. Effect of heat treatment conditions on shape control of large-sized elongated MnS inclusions in resulfurized free-cutting steels[J]. ISIJ International, 2011, 51(12): 1995-2001.
[15]孙荣耀, 郝士明. 稀土元素改善工具钢切削性能的研究[J]. 钢铁, 1982, 17(5): 58-63.
Sun Rongyao, Hao Shiming. Investigation on the improvement of cutting properties of tool steels by the addition of rare earth elements[J]. Iron and Steel, 1982, 17(5): 58-63.
[16]范磊, 李晨, 姜茂发. 稀土对高硫易切削钢中夹杂物的影响研究[J]. 钢铁钒钛, 2020, 41(6): 119-123.
Fan Lei, Li Chen, Jiang Maofa. Experimental study on the effect of rare earth on inclusions in high-sulfur free-cutting steel[J]. Iron Steel Vanadium Titanium, 2020, 41(6): 119-123.
[17]陈俊东, 关晓光, 汪云辉. 热变形工艺对低硫易切削钢中硫化锰形态演变的影响[J]. 金属热处理, 2019, 44(2): 132-137.
Chen Jundong, Guan Xiaoguang, Wang Yunhui. Influence of thermal deformation process on morphology evolution of MnS inclusion in low-sulphur free-cutting steel[J]. Heat Treatment of Metals, 2019, 44(2): 132-137.
[18]王利军, 李永超, 王成杰, 等. 铌-钛微合金化中碳硼钢连铸坯的高温力学性能[J]. 特殊钢, 2020, 41(3): 67-71.
Wang Lijun, Li Yongchao, Wang Chengjie, et al. High temperature mechanical property of casting bloom of Nb-Ti microalloying medium-carbon-boron steel[J]. Special Steel, 2020, 41(3): 67-71.
[19]邹虎, 王东兴, 陈永峰, 等. 低碳含碲硫易切削钢的研究与实践[J]. 中国冶金, 2020, 30(12): 77-81.
Zou Hu, Wang Dongxing, Chen Yongfeng, et al. Research and practice of low carbon free-cutting steel containing tellurium and sulfur[J]. China Metallurgy, 2020, 30(12): 77-81.
[20]Malkiewicz T, Rudnik S. Deformation of non-inclusions during rolling of steel[J]. Journal of the Iron and Steel Institute, 1963, 201(1): 33-38.
[21]李梦龙. 易切削非调质钢中硫化物生成行为与均匀化控制研究[D]. 北京: 北京科技大学, 2015.
Li Menglong. Study on formation behavior and homogenization control of sulfide inclusions in free-cutting non-quenched and tempered steel[D]. Beijing: University of Science and Technology Beijing, 2015.
[22]陈登国, 廖桑桑, 徐李军, 等. 含硫易切削模具钢高温热塑性行为探讨[J]. 中国冶金, 2020, 30(5): 58-64.
Chen Dengguo, Liao Sangsang, Xu Lijun, et al. Discussion of high temperature ductility behavior of sulfur-containing free-cutting die steel[J]. China Metallurgy, 2020, 30(5): 58-64.

热变形工艺对铈-硫易切削不锈钢中硫化物形态演变的影响

Influence of thermal deformation process on morphology evolution of sulfide in cerium-sulfur containing free-cutting stainless steel

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