热处理对稀土5Cr钢组织及析出相的影响

doi:10.13251/j.issn.0254-6051.2022.12.009

金属热处理 ›› 2022, Vol. 47 ›› Issue (12): 56-61.DOI: 10.13251/j.issn.0254-6051.2022.12.009

热处理对稀土5Cr钢组织及析出相的影响

李涛^1,2, 许涛², 韩强¹, 孙昊¹, 白岩松¹, 梁占磊¹

1.内蒙古科技大学材料与冶金学院, 内蒙古包头 014010;
2.内蒙古科技大学分析测试中心, 内蒙古包头 014010

收稿日期:2022-07-06 修回日期:2022-10-11 出版日期:2022-12-25 发布日期:2023-01-05
通讯作者: 韩强,副教授,硕士, E-mail:qiang.han163@163.com
作者简介:李涛(1974—),女,教授,博士,主要研究方向为先进金属材料的基础研究及组织控制、金属材料的自然环境腐蚀与防护,E-mail:836450192@qq.com。
基金资助:
内蒙古自然科学基金(2021LHMS05028);内蒙古科技计划(2020GG0207)

Effect of heat treatment on microstructure and precipitates of 5Cr steel with RE addition

Li Tao^1,2, Xu Tao², Han Qiang¹, Sun Hao¹, Bai Yansong¹, Liang Zhanlei¹

1. School of Materials and Metallurgy, Inner Mongolia University of Science and Technology, Baotou Inner Mongolia 014010, China;
2. Instrumental Analysis Center, Inner Mongolia University of Science and Technology, Baotou Inner Mongolia 014010, China

Received:2022-07-06 Revised:2022-10-11 Online:2022-12-25 Published:2023-01-05

摘要/Abstract

摘要： 以稀土5Cr钢为对象,研究了热处理工艺(870、900、930 ℃保温50 min水淬,670、690、710 ℃保温90 min回火)对其组织及第二相析出行为的影响。结果表明,试验钢经870 ℃淬火后,组织未完全奥氏体化;随着淬火温度的升高,试验钢完全奥氏体化,原始奥氏体平均晶粒尺寸从900 ℃的13.49 μm增大到930 ℃的15.01 μm,且组织均匀性明显下降。合适的淬火温度为900 ℃。在670~710 ℃回火后,组织分布为回火屈氏体、回火屈氏体+回火索氏体、回火索氏体。回火后第二相为分布在基体上的Cr₇C₃碳化物及在界面聚集的Cr₂₃C₆碳化物。随着回火温度的升高,Cr₂₃C₆碳化物比例逐渐增加。为避免回火过程中M₂₃C₆型碳化物的聚集和粗化,合适的回火温度为690 ℃。

关键词: 稀土5Cr钢, 热处理, 组织, 析出相

Abstract: Taking 5Cr steel with RE addition as the object, the effect of heat treatment (water quenching at 870, 900, 930 ℃ for 50 min , and then tempering at 670, 690, 710 ℃ for 90 min) on microstructure and second-phase precipitation behavior of the tested steel was studied. The results show that after quenching at 870 ℃, the structure is not completely austenitized. The tested steel is completely austenitized with the increase of quenching temperature, and the prior-austenite average grain size is increased from 13.49 μm at 900 ℃ to 15.01 μm at 930 ℃, while the microstructure uniformity is obviously reduced. By selecting the proper quenching temperature as 900 ℃, and after tempering at 670-710 ℃, the microstructure is tempered troostite, tempered troostite + tempered sorbite and tempered sorbite in turn. The second phases after tempering are Cr₇C₃ carbide distributed on the matrix and Cr₂₃C₆ carbide aggregated at the interface. With the increase of tempering temperature, the proportion of Cr₂₃C₆ carbide increases gradually. In order to avoid the aggregation and coarsening of M₂₃C₆ carbides during tempering, the appropriate tempering temperature is 690 ℃.

Key words: 5Cr steel with RE addition, heat treatment, microstructure, precipitates

中图分类号:

TG162.83

李涛, 许涛, 韩强, 孙昊, 白岩松, 梁占磊. 热处理对稀土5Cr钢组织及析出相的影响[J]. 金属热处理, 2022, 47(12): 56-61.

Li Tao, Xu Tao, Han Qiang, Sun Hao, Bai Yansong, Liang Zhanlei. Effect of heat treatment on microstructure and precipitates of 5Cr steel with RE addition[J]. Heat Treatment of Metals, 2022, 47(12): 56-61.

参考文献

[1]吕祥鸿, 赵国仙, 张建兵, 等. 超级13Cr马氏体不锈钢在CO₂及H₂S/CO₂环境中的腐蚀行为[J]. 工程科学学报, 2010, 32(2): 207-212.
Lü Xianghong, Zhao Guoxian, Zhang Jianbing, et al. Corrosion behaviors of super 13Cr martensitic stainless steel under CO₂ and H₂S/CO₂ environment [J]. Chinese Journal of Engineering, 2010, 32(2): 207-212.
[2]高建忠. 我国石油管材国产化回顾与思考[J]. 石油管材与仪器, 2021, 7(2): 1-8, 14.
Gao Jianzhong. Retrospect and experiences of petroleum tubular goods localization [J]. Petroleum Tubular Goods & Instruments, 2021, 7(2): 1-8, 14.
[3]Kermani M B, Gonzales J C, Turconi G L, et al. Development of superior corrosion resistance 3%Cr steels for downhole applications [C]//NACE Annual Conference & Exposition. 2003: 03116.
[4]Bosch C, Jansen J P, Poepperling R K. Influence of chromium contents of 0.5 to 1.0% on the corrosion behavior of low alloy steel for large-diameter pipes in CO₂ containing aqueous media [C]//NACE Annual Conference & Exposition. 2003: 03118.
[5]王吉连. Cr3钢在含CO₂/H₂S介质中腐蚀研究[D]. 北京: 北京化工大学, 2010.
Wang Jilian. The corrvsion research of Cr3 steel in solutions containing CO₂ and H₂S[D]. Beijing: Beijing University of Chemical Technology, 2010.
[6]冯耀荣, 李鹤林, 徐婷, 等. 我国油井管标准化技术进展及展望[J]. 石油管材与仪器, 2021, 7(3): 1-6.
Feng Yaorong, Li Helin, Xu Ting, et al. Progress and prospect of standardization technology for oil country tubular goods in China [J]. Petroleum Tubular Goods & Instruments, 2021, 7(3): 1-6.
[7]孙深, 李阳, 孙萌, 等. Ce对汽车气门弹簧钢65Si2CrV组织性能的影响[J]. 材料热处理学报, 2020, 41(10): 51-59.
Sun Shen, Li Yang, Sun Meng, et al. Effect of Ce on microstructure and properties of automotive valve spring steel 65Si2CrV [J]. Transactions of Materials and Heat Treatment, 2020, 41(10): 51-59.
[8]米丰毅, 王向东, 汪兵, 等. 稀土对低碳钢耐工业大气腐蚀性的影响[J]. 钢铁研究学报, 2010, 22(8): 36-40.
Mi Fengyi, Wang Xiangdong, Wang Bing, et al. Effect of rare earths on resistance to industrial atomospheric corrosion of low carbon steel [J]. Journal of Iron and Steel Research, 2010, 22(8): 36-40.
[9]刘晓, 马利飞, 李运刚. 稀土镧和铈对双相不锈钢耐腐蚀性能的影响[J]. 材料热处理学报, 2016, 37(1): 112-118.
Liu Xiao, Ma Lifei, Li Yungang. Effect of La and Ce on corrosion resistance of duplex stainless steel [J]. Transactions of Materials and Heat Treatment, 2016, 37(1): 112-118.
[10]刘洪源, 吴光亮, 张永集. 工程机械用Q1100钢的热处理工艺[J]. 金属热处理, 2021, 46(11): 64-70.
Liu Hongyuan, Wu Guangliang, Zhang Yongji. Heat treatment process of Q1100 steel for construction machinery[J]. Heat Treatment of Metals, 2021, 46(11): 64-70.
[11]刘宗昌, 任慧平, 宋义全, 等. 金属固态相变教程[M]. 北京: 冶金工业出版社, 2011.
[12]杨飞飞, 张忠铧, 刘华松, 等. 高强度油井管用钢带状偏析及其条带型混晶现象研究[J]. 钢铁研究学报, 2021, 33(9): 979-986.
Yang Feifei, Zhang Zhonghua, Liu Huasong, et al. Banded segregation and its related band-typed mixed grain structure in high strength oil well pipe steel [J]. Journal of Iron and Steel Research, 2021, 33(9): 979-986.
[13]王磊, 路昊青, 张宝燕, 等. 热处理工艺调控9CrV钢显微组织及力学性能[J]. 材料热处理学报, 2021, 42(11): 69-76.
Wang Lei, Lu Haoqing, Zhang Baoyan, et al. Microstructure and mechanical properties of 9CrV steel controlled by heat treatment process [J]. Transactions of Materials and Heat Treatment, 2021, 42(11): 69-76.
[14]王春芳, 厉勇, 李南, 等. 热处理对AISI4340钢临界点及CCT曲线的影响[J]. 钢铁, 2017, 52(3): 70-75.
Wang Chunfang, Li Yong, Li Nan, et al. Effect of heat treatment process on critical transformation and CCT curve of AISI4340 steel [J]. Iron & Steel, 2017, 52(3): 70-75.
[15]刘宗昌, 李一鸣, 冯佃臣, 等. 合金钢显微组织辨识[M]. 北京: 高等教育出版社, 2017.
[16]黄顶俊, 杨弋涛. 5Cr8Mo2SiV钢淬火和回火过程中碳化物的析出[J]. 金属热处理, 2017, 42(3): 98-103.
Huang Dingjun, Yang Yitao. Carbide precipitation behavior of 5Cr8Mo2SiV steel during quenching and tempering [J]. Heat Treatment of Metals, 2017, 42(3): 98-103.
[17]Wang Y J, Liu Z C, Duan B Y. Quenching and tempering processes and microstructure of H13 steel [J]. Heat Treatment, 2013, 28(4): 26-31.
[18]Hu X B, Li L, Wu X C. Coarsening kinetics of carbides in 4Cr5MoSiV1 hot work tool steel during thermal fatigue [J]. Transactions of Materials and Heat Treatment, 2005, 26(1): 57-61.
[19]赵永刚. 含Cr钢在粉砂-CO₂环境中腐蚀机理研究[D]. 北京: 北京科技大学, 2021.
Zhao Yonggang. Investigation on the corrosion mechanism of Cr alloy steel in the silty sand-CO₂ environment [D]. Beijing: University of Science and Technology Beijing, 2021.
[20]黄宇, 成国光, 李世健, 等. Ce微合金化H13钢中一次碳化物的析出机理及热稳定性研究 [J]. 金属学报, 2019, 55(12): 1487-1494.
Huang Yu, Cheng Guoguang, Li Shijian, et al. Precipitation mechanism and thermal stability of primary carbide in Ce microalloyed H13 steel [J]. Acta Metallurgica Sinica, 2019, 55(12): 1487-1494.
[21]易善伟, 历长云, 胡小强, 等. 热处理工艺对新型低温油井管用钢组织和性能的影响 [J]. 材料热处理学报, 2018, 39(6): 68-75.
Yi Shanwei, Li Changyun, Hu Xiaoqiang, et al. Effect of heat treatment on microstructure and mechanical properties of new low-temperature oil well steel [J]. Transactions of Materials and Treatment, 2018, 39(6): 68-75.

热处理对稀土5Cr钢组织及析出相的影响

Effect of heat treatment on microstructure and precipitates of 5Cr steel with RE addition

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	王志文, 杨荣东, 黄元春, 李辉. 时效处理对挤压成型2195铝锂合金组织和力学性能的影响[J]. 金属热处理, 2022, 47(9): 6-11.
[2]	高星, 张宁, 丁燕, 蒋波. 热处理时间对激光选区成形TC4钛合金组织及力学性能的影响[J]. 金属热处理, 2022, 47(9): 12-17.
[3]	王凯, 王荣吉, 周童, 彭松. Fe-Mn-C-Al系TWIP钢热处理工艺参数优化[J]. 金属热处理, 2022, 47(9): 31-35.
[4]	林凌峰, 袁鸽成, 杨濂, 丁灿培. 平均道次压下率对异步轧制-固溶6016铝合金板材显微组织的影响[J]. 金属热处理, 2022, 47(9): 36-40.
[5]	王璐, 王峰, 张明伟, 刘瑞, 傅正元, 刘景顺. 退火工艺对Ti-4Al-2V合金组织及耐蚀性能的影响[J]. 金属热处理, 2022, 47(9): 41-46.
[6]	潘冉, 刘宝胜, 曾元松, 曲海涛, 王东, 慕延宏. 深冷处理对15%SiC_p/2009铝基复合材料组织与力学性能的影响[J]. 金属热处理, 2022, 47(9): 65-70.
[7]	张浩泽, 王隽生, 宫鹏辉, 詹海艺, 王凯. 热处理对EB铸锭直接轧制TC4合金板材组织和力学性能的影响[J]. 金属热处理, 2022, 47(9): 71-78.
[8]	钟立伟, 冯朝辉, 高文理, 陈军洲, 陆政. 多轴锻造与T852热处理对Al-Cu-Li合金组织及力学性能的影响[J]. 金属热处理, 2022, 47(9): 79-86.
[9]	季德静, 杨维宇, 白雅琼. 高强韧工程机械用钢Q690D的淬火工艺优化[J]. 金属热处理, 2022, 47(9): 108-112.
[10]	温方明, 郝晓博, 曹恒, 张强, 李渤渤, 刘茵琪. 热处理工艺对N06600合金热轧板组织与性能的影响[J]. 金属热处理, 2022, 47(9): 113-118.
[11]	艾兵权, 邝霜, 田秀刚, 杨峰, 王玉慧, 逯志强, 王朝, 郝雷. 均热温度对不同成分980 MPa级高强钢组织和性能的影响[J]. 金属热处理, 2022, 47(9): 119-124.
[12]	王世凯, 王睿, 康燕, 于志强, 闫志杰. 淬火温度对Cr5MoVNi钢组织和性能的影响[J]. 金属热处理, 2022, 47(9): 125-129.
[13]	熊维亮, 梁文, 吴腾, 梁亮, 吴浩鸿. 控冷工艺对热轧双相钢组织与性能的影响[J]. 金属热处理, 2022, 47(9): 130-133.
[14]	范朝, 程宗辉, 张志强. 激光热输入对激光增材修复1Cr17Ni2不锈钢组织与力学性能的影响[J]. 金属热处理, 2022, 47(9): 140-145.
[15]	王瑞敏, 刘曼, 周剑华, 张琪, 苏雪, 徐光. R350HT钢轨钢的连续冷却转变曲线[J]. 金属热处理, 2022, 47(9): 153-157.