低碳含Cu中厚钢板富Cu相的时效析出行为

doi:10.13251/j.issn.0254-6051.2023.02.015

金属热处理 ›› 2023, Vol. 48 ›› Issue (2): 94-102.DOI: 10.13251/j.issn.0254-6051.2023.02.015

低碳含Cu中厚钢板富Cu相的时效析出行为

孙铭璇¹, 孟利¹, 张宁¹, 张波¹, 梁丰瑞², 罗小兵²

1.钢铁研究总院有限公司冶金工艺研究所, 北京 100081;
2.钢铁研究总院有限公司工程用钢研究院, 北京 100081

收稿日期:2022-08-07 修回日期:2022-11-22 出版日期:2023-02-25 发布日期:2023-03-22
通讯作者: 孟利,高级工程师,博士,E-mail:li_meng@126.com
作者简介:孙铭璇(1998—),女,硕士研究生,主要研究方向为钢组织性能及强韧化机制,E-mail:15652712727@163.com。
基金资助:
国家重点研发计划(2017YFB0903901)

Aging precipitation behavior of Cu-rich particles of low-carbon Cu-bearing medium and heavy steel plate

Sun Mingxuan¹, Meng Li¹, Zhang Ning¹, Zhang Bo¹, Liang Fengrui², Luo Xiaobing²

1. Metallurgical Technology Institute, Central Iron and Steel Research Institute Co., Ltd., Beijing 100081, China;
2. Research Institute of Engineering Steels, Central Iron and Steel Research Institute Co., Ltd., Beijing 100081, China

Received:2022-08-07 Revised:2022-11-22 Online:2023-02-25 Published:2023-03-22

摘要/Abstract

摘要： 将某低碳含Cu中厚钢板在680 ℃分别时效不同时间(15、30、45、75、90、120 min)后,利用场发射扫描电镜(SEM)和能谱仪(EDS)分析了中厚钢板不同位置富Cu相的析出和长大机制。结果表明,经时效处理后,试验钢板表面及心部富Cu相呈球状或短棒状,尺寸均主要在5~60 nm之间,但心部富Cu相的平均尺寸要大于表面富Cu相。随着时效时间的延长,表面和心部的富Cu相均发生长大,呈现平均尺寸增加、粒子总数目减少的趋势。基于理论计算,富Cu相平均尺寸的变化满足Ostwald熟化机制,且心部富Cu相长大速率小于表面富Cu相。

关键词: 含Cu钢, 中厚板, 时效, 富Cu相, Ostwald熟化

Abstract: A low-carbon Cu-bearing medium and heavy steel plate was aged at 680 ℃ for different time (15, 30, 45, 75, 90, 120 min). The precipitation and growth mechanism of Cu-rich particles at different positions of medium and heavy steel plate were analyzed by field emission scanning electron microscopy (SEM) and energy disperse spectroscopy (EDS). The results show that after aging treatment, the Cu-rich particles on surface and in core of the tested steel plate are spherical or short rod-shaped, and the size is mainly in the range of 5-60 nm, but the average size of Cu-rich particles in the core is larger than that on the surface. With the increase of aging time, the Cu-rich particles on the surface and in the core grow at the same time, showing a trend of the average size increasing and the total number of particles decreasing. Based on the theoretical calculation, the change of average size of Cu-rich particles satisfies the Ostwald ripening mechanism, and the growth rate of Cu-rich particles in the core is smaller than that on the surface.

Key words: Cu-bearing steel, medium and heavy steel plate, aging, Cu-rich phase, Ostwald ripening

中图分类号:

TG142.33

孙铭璇, 孟利, 张宁, 张波, 梁丰瑞, 罗小兵. 低碳含Cu中厚钢板富Cu相的时效析出行为[J]. 金属热处理, 2023, 48(2): 94-102.

Sun Mingxuan, Meng Li, Zhang Ning, Zhang Bo, Liang Fengrui, Luo Xiaobing. Aging precipitation behavior of Cu-rich particles of low-carbon Cu-bearing medium and heavy steel plate[J]. Heat Treatment of Metals, 2023, 48(2): 94-102.

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低碳含Cu中厚钢板富Cu相的时效析出行为

Aging precipitation behavior of Cu-rich particles of low-carbon Cu-bearing medium and heavy steel plate

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