马氏体不锈钢回火过程中碳化物的演变规律及其对耐蚀性的影响

doi:10.13251/j.issn.0254-6051.2023.07.007

金属热处理 ›› 2023, Vol. 48 ›› Issue (7): 38-43.DOI: 10.13251/j.issn.0254-6051.2023.07.007

马氏体不锈钢回火过程中碳化物的演变规律及其对耐蚀性的影响

陈俊¹, 张覃轶^1,2,3, 邓锦强¹, 袁胜福², 周鸿锋³, 伍冬^1,2

1.武汉理工大学材料科学与工程学院, 湖北武汉 430070;
2.阳江合金材料实验室, 广东阳江 529500;
3.阳江拓必拓工业技术研究院有限公司, 广东阳江 529500

收稿日期:2022-12-29 修回日期:2023-05-16 出版日期:2023-07-25 发布日期:2023-09-04
通讯作者: 张覃轶,副教授,博士,E-mail:zhqy@whut.edu.cn
作者简介:陈俊(1997—),男,硕士研究生,主要研究方向为金属材料热处理, E-mail:303673@whu.edu.cnt。

Carbide evolution and its effect on corrosion resistance of martensitic stainless steel during tempering

Chen Jun¹, Zhang Qinyi^1,2,3, Deng Jinqiang¹, Yuan Shengfu², Zhou Hongfeng³, Wu Dong^1,2

1. School of Materials Science and Engineering, Wuhan University of Technology, Wuhan Hubei 430070, China;
2. Yangjiang Advanced Alloys Laboratory, Yangjiang Guangdong 529500, China;
3. Yangjiang Tuobituo Industrial Technology Research Institute Co., Ltd., Yangjiang Guangdong 529500, China

Received:2022-12-29 Revised:2023-05-16 Online:2023-07-25 Published:2023-09-04

摘要/Abstract

摘要： 通过显微组织观察、能谱分析和硬度测试研究了1.4116马氏体不锈钢回火过程中碳化物的演变规律,采用盐雾腐蚀试验和电化学测试研究了不同温度回火后的耐蚀性。结果表明,回火温度超过500 ℃时,大量富Cr碳化物的析出是耐蚀性下降的根本原因。在580 ℃回火时,自腐蚀电位最低,耐蚀性最差,但回火温度超过600 ℃时,自腐蚀电位升高,耐蚀性得到明显改善。在实际生产中,不建议1.4116马氏体不锈钢在500~600 ℃进行回火。

关键词: 马氏体不锈钢, 回火, 碳化物, 耐蚀性

Abstract: Carbide evolution of 1.4116 martensitic stainless steel during tempering was studied by means of microstructure observation, energy spectrum analysis and hardness test, and the corrosion resistance after tempering at different temperatures was studied through salt spray corrosion test and electrochemical test. The results show that when the tempering temperature exceeds 500 ℃, a large number of Cr-rich carbides are precipitated, which is the main reason for the decrease of corrosion resistance. When tempering at 580 ℃, the self-corrosion potential is the lowest and the corrosion resistance is the worst, however, when the tempering temperature exceeds 600 ℃, the self-corrosion potential increases and the corrosion resistance is significantly improved. In actual production, the 1.4116 martensitic stainless steel should not be tempered at 500-600 ℃.

Key words: martensitic stainless steel, tempering, carbide, corrosion resistance

中图分类号:

TG156

陈俊, 张覃轶, 邓锦强, 袁胜福, 周鸿锋, 伍冬. 马氏体不锈钢回火过程中碳化物的演变规律及其对耐蚀性的影响[J]. 金属热处理, 2023, 48(7): 38-43.

Chen Jun, Zhang Qinyi, Deng Jinqiang, Yuan Shengfu, Zhou Hongfeng, Wu Dong. Carbide evolution and its effect on corrosion resistance of martensitic stainless steel during tempering[J]. Heat Treatment of Metals, 2023, 48(7): 38-43.

参考文献

[1]Anjos A D, Scheuer C J, Brunatto S F, et al. Low-temperature plasma nitrocarburizing of the AISI 420 martensitic stainless steel: Microstructure and process kinetics[J]. Surface and Coatings Technology, 2015, 275: 51-57.
[2]Köse C, Kaçar R. The effect of preheat & post weld heat treatment on the laser weldability of AISI 420 martensitic stainless steel[J]. Materialsand Design, 2014, 64: 221-226.
[3]Mesquita T J, Chauveau E, Mantel M, et al. Corrosion and metallurgical investigation of two supermartensitic stainless steels for oil and gas environments[J]. Corrosion Science, 2014, 81: 152-161.
[4]Lu S, Yao K, Chen Y, et al. Effect of quenching and partitioning on the microstructure evolution and electrochemical properties of a martensitic stainless steel[J]. Corrosion Science, 2016, 103: 95-104.
[5]Barlow L D, Du Toit M. Effect of austenitizing heat treatment on the microstructure and hardness of martensitic stainless steel AISI 420[J]. Journal of Materials Engineering and Performance, 2012, 21(7): 1327-1336.
[6]Zeng T Y, Li W, Wang N M, et al. Microstructural evolution during tempering and intrinsic strengthening mechanisms in a low carbon martensitic stainless bearing steel[J]. Materials Science and Engineering A, 2022, 836: 142736.
[7]杨向同, 吕祥鸿, 谢俊峰, 等. 高强15Cr马氏体不锈钢在有机盐完井液中的腐蚀行为[J]. 腐蚀与防护, 2018, 39(12): 901-905.
Yang Xiangtong, Lü Xianghong, Xie Junfeng, et al. Corrosion behavior of high strength 15Cr martensitic stainless steel in organic salt completion fluid[J]. Corrosion and Protection, 2018, 39(12): 901-905.
[8]李晓蔚, 张志明, 李心刚, 等. 微观组织对17-4PH马氏体不锈钢冲击韧性和点蚀敏感性的影响[J]. 腐蚀与防护, 2020, 41(9): 55-59.
Li Xiaowei, Zhang Zhiming, Li Xingang, et al. Influence of microstructure on impact toughness and pitting sensitivity of 17-4PH martensitic stainless steel[J]. Corrosion and Protection, 2020, 41(9): 55-59.
[9]Morsdorf L, Emelina E, Gault B, et al. Carbon redistribution in quenched and tempered lath martensite[J]. Acta Materialia, 2021, 205: 116521.
[10]Gunn R. Duplex Stainless Steels: Microstructure, Propertiesand Applications[M]. Woodhead Publishing, 1997.
[11]Moshkbar Bakhshayesh M, Farzadi A, Doustahadi A, et al. Measurement of degree of sensitization in post-weld heat treated 13Cr-4Ni martensitic stainless steel clad using double loop electrochemical potentiokinetic technique[J]. Engineering Failure Analysis, 2022, 134: 106046.
[12]Kumar B S, Kain V, Vishwanadh B. Effect of tempering treatments on microstructure and intergranular corrosion of 13wt%Cr martensitic stainless steel[J]. Corrosion, 2016, 73(4): 362-378.
[13]Calderón-Hernández J, Hincapíe-Ladino D, Edson B, et al. Relation between pitting potential, degree of sensitization and reversed austenite in a supermartensitic stainless steel[J]. Corrosion, 2017, 73(8): 953-960.
[14]Zhao Y, Liu W, Zhang T, et al. Assessment of the correlation between M₂₃C₆ precipitates and pitting corrosion resistance of 0Cr13 martensitic stainless steel[J]. Corrosion Science, 2021, 189: 109580.
[15]Ma D, Chi H, Zhou J, et al. Microstructure and mechanical properties of martensitic stainless steel 6Cr15MoVn[J]. Journal of Ironand Steel Research, International, 2012, 19(3): 56-61.
[16]Taji I, Moayed M H, Mirjalili M. Correlation between sensitisation and pitting corrosion of AISI 403 martensitic stainless steel[J]. Corrosion Science, 2015, 92: 301-308.
[17]Djebaili H, Zedira H, Djelloul A, et al. Characterization of precipitates in a 7.9Cr-1.65Mo-1.25Si-1.2V steel during tempering[J]. Materials Characterization, 2009, 60(9): 946-952.
[18]Aquino J M, Della Rovere C A, Kuri S E. Intergranular corrosion susceptibility in supermartensitic stainless steel weldments[J]. Corrosion Science, 2009, 51(10): 2316-2323.
[19]Zhang H, Zhao Y L, Jiang Z D. Effects of temperature on the corrosion behavior of 13Cr martensitic stainless steel during exposure to CO₂ and Cl^- environment[J]. Materials Letters, 2005, 59(27): 3370-3374.
[20]王垚, 李春福, 林元华. Cr对Fe-Cr合金耐蚀性能影响的电子理论研究[J]. 金属学报, 2017, 53(5): 622-630.
Wang Yao, Li Chunfu, Lin Yuanhua. Electronic theoretical study of the influence of Cr on corrosion resistance of Fe-Cr alloy[J]. Acta Metallurgica Sinica, 2017, 53(5): 622-630.

马氏体不锈钢回火过程中碳化物的演变规律及其对耐蚀性的影响

Carbide evolution and its effect on corrosion resistance of martensitic stainless steel during tempering

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