Cr元素对高Al系Fe-Mn-Al-C低密度钢的影响综述

doi:10.13251/j.issn.0254-6051.2023.10.037

摘要/Abstract

摘要： 随着节能环保和经济性的需求,轻量化和高韧化成为汽车钢铁行业的主要发展目标,在不同类型系列钢中,Fe-Mn-Al-C系奥氏体钢因具有高比强度和高强塑积等优异的综合性能而受到青睐。伴随着减重元素Al的添加,促进κ-碳化物的生成,使Fe-Mn-Al-C钢的性能恶化严重,减少或细化κ-碳化物是提高高铝Fe-Mn-Al-C钢使用性能的有效途径。因此,从成分设计的角度出发,综述了Cr元素在物相组成、κ-碳化物、力学性能变形机制和层错能等方面对Fe-Mn-Al-C系低密度钢的影响规律,重点分析Cr含量对κ-碳化物的机理影响,并说明可以通过添加Cr元素改善高铝Fe-Mn-Al-C钢的使用性能。最后结合最新的研究成果,展望了未来Fe-Mn-Al-C钢的发展趋势。

关键词: Fe-Mn-Al-C轻质钢, Cr元素, κ-碳化物, 拉伸性能, 影响因素, 层错能

Abstract: With the needs of energy conservation, environmental protection and economy, the lightweight and high toughness have become the main development goals of the automotive steel industry. Among different types of series steel, Fe-Mn-Al-C austenitic steel is favored because of its excellent comprehensive properties such as high specific strength and high product of strength and elongation. With the addition of weight reduction element Al, the promoted formation of κ-carbide deteriorates the properties of the Fe-Mn-Al-C steel seriously, thus reducing or refining the κ-carbide is an effective way to improve the performance of the high-aluminum Fe-Mn-Al-C steel. Therefore, from the point of view of composition design, effect of Cr element on the Fe-Mn-Al-C low density steel in terms of phase composition, κ-carbide, mechanical properties, deformation mechanism and stacking fault energy were summarized, and the effect of Cr content on the κ-carbide mechanism was emphatically analyzed, then explaining that the performance of the Fe-Mn-Al-C steel with high aluminum could be improved by adding Cr element. Finally, combining with the latest research results, the development trend of Fe-Mn-Al-C steel in the future is prospected.

Key words: Fe-Mn-Al-C light weight steel, Cr element, κ-carbide, tensile properties, influencing factor, stacking fault energy

中图分类号:

TG142.1

赵康, 吴志方, 孙挺, 王毛球, 时捷. Cr元素对高Al系Fe-Mn-Al-C低密度钢的影响综述[J]. 金属热处理, 2023, 48(10): 239-246.

Zhao Kang, Wu Zhifang, Sun Ting, Wang Maoqiu, Shi Jie. A review of effect of Cr element on high Al Fe-Mn-Al-C low density steel[J]. Heat Treatment of Metals, 2023, 48(10): 239-246.

参考文献

[1]唐荻, 米振莉, 陈雨来. 国外新型汽车用钢的技术要求及研究开发现状[J]. 钢铁, 2005, 40(6): 1-4.
Tang Di, Mi Zhenli, Chen Yulai. Technology and research and development of advanced automobile steel abroad[J]. Iron and Steel, 2005, 40(6): 1-4.
[2]Howell R A, Van Aken D C. A literature review of age hardening Fe-Mn-Al-C alloys[J]. Iron Steel Technology, 2009, 6(4): 193-212.
[3]Kim H, Suh D W, Kim N J. Fe-Al-Mn-C lightweight structural alloys: A review on the microstructures and mechanical properties[J]. Science and Technology of Advanced Materials, 2013, 14(1): 014205.
[4]Frommeyer G, Brüx U. Microstructures and mechanical properties of high-strength Fe-Mn-Al-C light-weight triplex steels[J]. Steel Research International, 2006, 77(9/10): 627-633.
[5]Raabe D, Springer H, Gutierrez-Urrutia I, et al. Alloy design, combinatorial synthesis, and microstructure-property relations for low-density Fe-Mn-Al-C austenitic steels[J]. JOM, 2014, 66(9): 1845-1856.
[6]Suh D W, Kim N J. Low-density steels[J]. Scripta Materialia, 2013, 68(6): 337-338.
[7]Liu C M, Cheng H C, Chao C Y, et al. Phase transformation of high temperature on Fe-Al-Mn-Cr-C alloy[J]. Journal of Alloys and Compounds, 2009, 488(1): 52-56.
[8]Sutou Y, Kamiya N, Umino R, et al. High-strength Fe-20Mn-Al-C-based alloys with low density[J]. ISIJ International, 2010, 50(6): 893-899.
[9]Tuan Y H, Lin C L, Chao C G, et al. Grain boundary precipitation in Fe-30Mn-9Al-5Cr-0.7C alloy[J]. Materials Transactions, 2008, 49(7): 1589-1593.
[10]Tsay G D, Lin C L, Chao C G, et al. A new austeniticFeMnAlCrC alloy with high-strength, high-ductility, and moderate corrosion resistance[J]. Materials Transactions, 2010, 51(12): 2318-2321.
[11]Chen M S, Cheng H C, Huang C F, et al. Effects of C and Cr content on high-temperature microstructures of Fe-9Al-30Mn-xC-yCr alloys[J]. Materials Characterization, 2010, 61(2): 206-211.
[12]Tuan Y H, Wang C S, Tsai C Y, et al. Corrosion behaviors of austenitic Fe-30Mn-7Al-xCr-1C alloys in 3.5%NaCl solution[J]. Materials Chemistry and Physics, 2009, 114(2/3): 595-598.
[13]Huang C F, Ou K L, Chen C S, et al. Research of phase transformation on Fe-8.7Al-28.3Mn-1C-5.5Cr alloy[J]. Journal of Alloys and Compounds, 2009, 488(1): 246-249.
[14]Frommeyer G, Drewes E J, Engl B. Physical and mechanical properties of iron-aluminium-(Mn,Si) lightweight steels[J]. Metallurgical Research and Technology, 2000, 97(10): 1245-1253.
[15]刘春泉, 彭其春, 薛正良, 等. Fe-Mn-Al-C系列低密度高强钢的研究现状[J]. 材料导报, 2019, 33(8): 2572-2581.
Liu Chunquan, Peng Qichun, Xue Zhengliang, et al. Research situation of Fe-Mn-AI-C system low-density high-strength steel[J]. Materials Reports, 2019, 33(8): 2572-2581.
[16]王凤权, 孙挺, 王毛球, 等. Fe-Mn-Al-C系奥氏体基低密度钢的研究进展[J]. 钢铁, 2021, 56(5): 89-102.
Wang Fengquan, Sun Ting, Wang Maoqiu, et al. Research progress of Fe-Mn-Al-C system austenitic low density steel[J]. Iron and Steel, 2021, 56(5): 89-102.
[17]Jiménez J A, Frommeyer G. The ternary iron aluminum carbides[J]. Journal of Alloys and Compounds, 2011, 509: 2729-2733.
[18]Yao M J, Dey P, Seol J B, et a1. Combined atom probe tomography and density functional theory investigation of the Al off-stoichiometry of κ-carbides in an austenitic Fe-Mn-A1-C low density steel[J]. Acta Materialia, 2016, 106: 229-238.
[19]张明达, 胡春东, 曹文全, 等. 基于Thermo-Calc的中锰中铝Fe-Mn-AI-C低密度钢类SchaeffIer相图绘制与评估[J]. 工程科学学报, 2016, 38(5): 682-690.
Zhang Mingda, Hu Chundong, Cao Wenquan, et al. Plotting and evaluation on the Schaeffler diagram of Fe-Mn-Al-C low-density alloys with medium manganese and aluminum contents based on Thermo-Calc software[J]. Chinese Journal of Engineering, 2016, 38(5): 682-690.
[20]王伟胜, 朱航宇, 宋明明, 等. Fe-23Mn-xAl-0.7C低密度钢中非金属夹杂物形成机理[J]. 钢铁, 2020, 55(10): 29-36.
Wang Weisheng, Zhu Hangyu, Song Mingming, et al. Formation mechanism of non-metallic inclusions in Fe-23Mn-xAl-0.7C lightweight steels[J]. Iron and Steel, 2020, 55(10): 29-36.
[21]Park K T, Jin K G, Han S H, et al. Stacking fault energy and plastic deformation of fully austenitic high manganese steels: Effect of Al addition[J]. Materials Science and Engineering A, 2010, 527(16/17): 3651-3661.
[22]Springer H, Raabe D. Rapid alloy prototyping: Compositional and thermo-mechanical high throughput bulk combinatorial design of structural materials based on the example of 30Mn-1.2C-xAl triplex steels[J]. Acta Materialia, 2012, 60(12): 4950-4959.
[23]Gutierrez-Urrutia I, Raabe D. Influence of Al content and precipitation state on the mechanical behaviour of austenitic high-Mn low-density steels[J]. Scripta Materialia, 2013, 68(6): 343-347.
[24]Yoo J D, Park K T. Microband-induced plasticity in a high Mn-Al-C light steel[J]. Materials Science and Engineering A, 2008, 496(1/2): 417-424.
[25]Ren P, Chen X P, Mei L, et a1. Intragranular brittle precipitates improve strain hardening capability of Fe-30Mn-11Al-1.2C low density steel[J]. Materials Science and Engineering A, 2020, 775: 138984.
[26]Yoo J D, Hwang S W, Park K T. Origin of extended tensile ductility of a Fe-28Mn-10Al-1C steel[J]. Metallurgical and Materials Transactions A, 2009, 40: 1520-1523.
[27]Moon J, Park S J, Jang J H, et al. Investigations of the microstructure evo1ution and tensile deformation behavior of austenitic Fe-Mn-Al-C lightweight steels and the effect of Mo addition[J]. Acta Materialia, 2018, 147: 226-235.
[28]Park K T. Tensile deformation of low-density Fe-Mn-Al-C austenitic steels at ambient temperature[J]. Scripta Materialia, 2013, 68(6): 375-379.
[29]Chang K M, Chao C G, Liu T F. Excellent combination of strength and ductility in a Fe-9Al-28Mn-1.8C alloy[J]. Scripta Materialia, 2010, 63(2): 162-165.
[30]Andryushchenko V A, Gavrilyuk V G, Nadutov V M. Atomic and magnetic ordering in the κ-phase of Fe-Al-C alloys[J]. The Physics of Metals and Metallography, 1985, 60(4): 50-55.
[31]Yang J, La P, Liu W, et al. Microstructure and properties of Fe₃Al-Fe₃AlC_0.5 composites prepared by self-propagating high temperature synthesis casting[J]. Materials Science and Engineering A, 2004, 382(1/2): 8-14.
[32]Bentley A P. Ordering in Fe-Mn-Al-C austenite[J]. Journal of Materials Science Letters, 1986, 5: 907-908.
[33]Chu S M, Kao P W, Gan D. Growth kinetics of κ-carbide particles in Fe-30Mn-10Al-1C-1Si alloy[J]. Scripta Metallurgica et Materialia, 1992, 26(7): 1067-1070.
[34]Cheng W C, Cheng C Y, Hsu C W, et al. Phase transformation of the L12 phase to kappa-carbide after spinodal decomposition and ordering in an Fe-C-Mn-Al austenitic steel[J]. Materials Science and Engineering A, 2015, 642: 128-135.
[35]Zhang J, Jiang Y, Zheng W, et al. Revisiting the formation mechanism of intragranular κ-carbide in austenite of a Fe-Mn-Al-Cr-C low-density steel[J]. Scripta Materialia, 2021, 199(3): 113836.
[36]Acselrad O, Kalashnikov I S, Silva E M, et al. Diagram of phase transformations in the austenite of hardened alloy Fe-28%Mn-8. 5%Al-1%C-1.25%Si as a result of aging due to isothermal heating[J]. Metal Science and Heat Treatment, 2006, 48(11): 543-553.
[37]Li M C, Chang H, Kao P W, et al. The effect of Mn and Al contents on the solvus of κ phase in austenitic Fe-Mn-Al-C alloys[J]. Materials Chemistry and Physics, 1999, 59(1): 96-99.
[38]Kim K W, Park S J, Moon J, et al. Characterization of microstructural evolution in austenitic Fe-Mn-Al-C lightweight steels with Cr content[J]. Materials Characterization, 2020, 170: 110717.
[39]Zhang Jianlei, Liu Yuxiang, Hu Conghui. The effect of Cr content on intragranular κ-carbide precipitation in Fe-Mn-Al-(Cr)-C low-density steels: A multiscale investigation[J]. Materials Characterization, 2022, 186: 111801.
[40]Liu Mingxiang, Zhou Junye, Zhang Jiankang. Ultra-high strength medium-Mn lightweight steel by dislocation slip band refinement and suppressed intergranular κ-carbide with Cr addition[J]. Materials Characterization, 2022, 190: 112042.
[41]Liu Jinxu, Wu Huibin, He Jinshan. Effect of κ-carbides on the mechanical properties and superparamagnetism of Fe-28Mn-11Al-1.5/1.7C-5Cr lightweight steels[J]. Materials Science and Engineering A, 2022, 849: 143462.
[42]Liu Yuxiang, Liu Mingxiang, Zhang Jianlei. Microstructure and mechanical properties of a Fe-28Mn-9Al-1.2C-(0,3,6,9)Cr austenitic low-density steel[J]. Materials Science and Engineering A, 2021, 821: 141581.
[43]Moon J, Ha H Y, Park S J, et al. Effect of Mo and Cr additions on the microstructure, mechanical properties and pitting corrosion resistance of austenitic Fe-30Mn-10. 5Al-1. 1C lightweight steels[J]. Journal of Alloys and Compounds, 2019, 715: 1136-1146.
[44]Aaronson H I, LeGous F K. An assessment of studies on homogeneous diffusional nucleation kinetics in binary metallic alloys[J]. Metallurgical Transactions A, 1992, 23(7): 1915-1945.
[45]Moon J, Ha H Y, Kim K W, et al. A new class of lightweight, stainless steels with ultra-high strength and large ductility[J]. Scientific Reports, 2020, 10(1): 12140.
[46]Chu S M, Kao P W, Gan D. Growth kinetics of κ-carbide particles in Fe30Mn10Al1C-1Si alloy[J]. Scripta Metallurgica et Materialia, 1992, 26(7): 1067-1070.
[47]Seol J B, Raabe D, Choi P, et al. Direct evidence for the formation of ordered carbides in a ferrite-based low-density Fe-Mn-Al-C alloy studied by transmission electron microscopy and atom probe tomography[J]. Scripta Materialia, 2013, 68(6): 348-353.
[48]Zhang Jianlei, Hu Conghui, Zhang Yunhu, et al. Microstructures, mechanical properties and deformation of near-rapidly solidified low-density Fe-20Mn-9Al-1.2C-xCr steels[J]. Materials and Design, 2020, 186: 108307.
[49]Ding H, Han D, Zhang J, et al. Tensile deformation behavior analysis of low density Fe-18Mn-10Al-xC steels[J]. Materials Science and Engineering A, 2016, 652: 69-76.
[50]Welsch E, Ponge D, Hafez Haghighat S M, et al. Strain hardening by dynamic slip band refinement in a high-Mn lightweight steel[J]. Acta Materialia, 2016, 116: 188-199.
[51]Jarlöv Asker, Ji Weiming, Zhu Zhiguang, et al. Molecular dynamics study on the strengthening mechanisms of Cr-Fe-Co-Ni high-entropy alloys based on the generalized stacking fault energy[J]. Journal of Alloys and Compounds, 2022, 905: 164137.
[52]Yoo J D, Park K T. Microband-induced plasticity in a high Mn-Al-C light steel[J]. Materials Science and Engineering A, 2018, 496: 417-424.