金属热处理 ›› 2024, Vol. 49 ›› Issue (5): 29-35.DOI: 10.13251/j.issn.0254-6051.2024.05.005

• 材料研究 • 上一篇    下一篇

铜含量对303易切削钢中硫化物形貌及力学性能的影响

王英虎1,2,3, 王婀娜1,2, 蔡晓文1,2   

  1. 1.成都先进金属材料产业技术研究院股份有限公司, 四川 成都 610000;
    2.海洋装备用金属材料及其应用国家重点实验室, 辽宁 鞍山 114009;
    3.北京科技大学 国家材料服役安全科学中心, 北京 100083
  • 收稿日期:2023-11-10 修回日期:2024-03-11 出版日期:2024-05-25 发布日期:2024-06-28
  • 作者简介:王英虎(1992—),男,工程师,博士研究生,主要研究方向为先进金属材料及加工技术,E-mail:hihihowareyou@163.com。

Effect of copper content on morphology of sulfides and mechanical properties of 303 free-cutting steel

Wang Yinghu1,2,3, Wang Enuo1,2, Cai Xiaowen1,2   

  1. 1. Chengdu Institute of Advanced Metallic Material Technology and Industry Co., Ltd., Chengdu Sichuan 610000, China;
    2. State Key Laboratory of Metal Material for Marine Equipment and Application, Anshan Liaoning 114009, China;
    3. National Center for Materials Service Safety, University of Science and Technology Beijing, Beijing 100083, China
  • Received:2023-11-10 Revised:2024-03-11 Online:2024-05-25 Published:2024-06-28

摘要: 以303、303Cu奥氏体易切削不锈钢为研究对象,采用Thermal-Calc热力学计算软件、扫描电镜、Phenom Partical X扫描电镜-能谱仪等研究了铜含量对硫化物形貌和力学性能的影响。结果表明,铸态303钢中长宽比≤3的硫化物占比为94.75%,而铸态303Cu钢中长宽比≤3的硫化物占比为88.37%,硫化物主要呈球形、椭球形、纺锤形或短棒状并以簇状沿晶界分布,属于第II类硫化物。锻态试验钢中的硫化物沿着锻造变形方向伸长,长宽比增大,尺寸增大,单位面积中的数量减少。Thermal-Calc软件计算得出,随着铜含量增加,硫化物的析出温度升高,析出量增加。铜的加入还会使CuS析出,降低材料的力学性能。锻态303Cu钢的抗拉强度为582.5 MPa,屈服强度为363.7 MPa,冲击吸收能量为62.1 J,而锻态303钢的抗拉强度为821.9 MPa,屈服强度为410.4 MPa,冲击吸收能量为147.5 J,锻态303钢具有更加优异的综合力学性能。锻态试验钢的拉伸性能和冲击性能与铸态相比均有明显改善,锻造变形有助于303、303Cu奥氏体易切削不锈钢力学性能的提高。

关键词: Thermal-Calc软件, 铜含量, 303易切削钢, MnS形貌, 力学性能

Abstract: Influence of copper content on sulfide morphology and mechanical properties of 303 and 303Cu austenitic free-cutting steels was investigated by means of Thermal-Calc thermodynamic calculation software, scanning electron microscope(SEM), Phenom Particle X scanning electron microscopy-energy dispersive spectroscopy(SEM-EDS). The results show that the proportion of sulfides with a length-width ratio ≤ 3 in the as-cast 303 steel is 94.75%, while in the as-cast 303Cu steel is 88.37%. Sulfides are predominantly spherical, ellipsoidal, spindle-shaped, or short rod-shaped and distributed along grain boundaries in clusters, characteristic of a type II sulfides. In the forged steels, sulfides are elongated along the forging deformation direction, with increased length-width ratio, dimensions, and decreased quantity per unit area. Thermal-Calc software calculations indicate that with copper content increasing, the precipitation temperature and content of sulfides increase. Additionally, the addition of copper leads to the precipitation of CuS, which reduces the mechanical properties of the material. The as-forged 303Cu steel exhibits a tensile strength of 582.5 MPa, yield strength of 363.7 MPa, and impact absorbed energy of 62.1 J, while the as-forged 303 steel shows superior comprehensive mechanical properties with a tensile strength of 821.9 MPa, yield strength of 410.4 MPa, and impact absorbed energy of 147.5 J. The tensile properties and impact absorbed energy of the as-forged steels are significantly improved compared to that of the as-cast steets, it indicates that forging deformation contributes to enhancing the mechanical properties of the 303 and 303Cu austenitic free-cutting steels.

Key words: Thermal-Calc software, copper content, 303 free-cutting steel, MnS morphology, mechanical properties

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