Effect of rare earth Ce on solidification structure and inclusions of 253MA heat-resistant steel

doi:10.13251/j.issn.0254-6051.2020.01.006

Abstract

Abstract: The solidification structure and the morphology, composition and structure of inclusions of 253MA steel with different content of rare earth Ce were characterized and analyzed by confocal laser scanning microscope, field emission scanning electron microscopy (FESEM) and electron backscatter diffraction (EBSD). The results show that by comparing the solidification structures of two specimens, the equiaxial grain rate and columnar crystal refining effect can be promoted by the addition of cerium. The rare earth inclusions are CeO ₂ and (CeO) ₂ SO ₄, which have fine and near-spherical dispersion distributions. It is found according to the statistical analysis and grading that the increase of rare earth Ce content is beneficial to the increase of D-type spherical inclusions, which helps to improve the high temperature resistance and oxidation resistance of the 253MA steel.

Key words: rare earth Ce, heat-resistant steel 253MA, solidification structure, inclusion

CLC Number:

TG142.13

Yang Lilin, Qi Jianbo, Zhao Liping, Jia Yongjie. Effect of rare earth Ce on solidification structure and inclusions of 253MA heat-resistant steel[J]. HTM, 2020, 45(1): 26-30.

References

[1]韩肈俊. 3种新型奥氏体耐热不锈钢253MA、153MA和353MA评述介绍[J]. 沈阳工程学院学报(自然科学版), 2009, 5(2): 169-174.
Han Zhaojun. A review on three new austenitic heat resistant stainless steel 253MA, 153MA and 353MA[J]. Journal of Shenyang Institute of Engineering(Natural Science), 2009, 5(2): 169-174.
[2]李新梅, 张忠文, 杜宝帅, 等. 长期高温服役后S31042奥氏体耐热钢的微观组织[J]. 金属热处理, 2019, 44(4): 171-174.
Li Xinmei, Zhang Zhongwen, Du Baoshuai, et al. Microstructure of S31042 austenite heat resistant steel after long-term service under high temperature[J]. Heat Treatment of Metals, 2019, 44(4): 171-174.
[3]句光宇, 吕煜, 刘文生, 等. 运行1.2×10⁵ h 15Cr1Mo1V钢主蒸汽管及R317焊缝的组织和性能[J]. 金属热处理, 2019, 44(6): 29-32.
Ju Guangyu, Lü Yu, Liu Wensheng, et al. Microstructure and properties of 15Cr1Mo1V steel main steam pipe and R317 welded joint after 1.2×10⁵ h service[J]. Heat Treatment of Metals, 2019, 44(6): 29-32.
[4]赵莉萍. 金属材料学[M]. 北京: 北京大学出版社, 2012.
[5]Zhang J M, Li S X, Yang Z G, et al. Influence of inclusion size on fatigue behavior of high strength steels in the gigacycle fatigue regime[J]. International Journal of Fatigue, 2007, 29(4): 765-771.
[6]徐光宪. 稀土(上册)[M]. 北京: 冶金工业出版社, 1995.
[7]吴文远. 稀土冶金学[M]. 北京: 化学工业出版社, 2005.
[8]杨吉春, 杨昌桥, 周莉, 等. Ce对IF钢显微组织和力学性能的影响[J]. 稀土, 2014, 35(5): 25-29.
Yang Jichun, Yang Changqiao, Zhou Li, et al. Effect of cerium on microstructures and mechanical properties of IF steel[J]. Chinese Rare Earths, 2014, 35(5): 25-29.
[9]刘靖, 姚晓乐, 贺景春. 稀土La和Ce对25CrMoVB钢夹杂物的影响[J]. 金属热处理, 2012, 37(10): 17-20.
Liu Jing, Yao Xiaole, He Jingchun. Effects of rare earth element La and Ce on inclusions of 25CrMoVB steel[J]. Heat Treatment of Metals, 2012, 37(10): 17-20.
[10]Liu X, Yang J C, Yang L, et al. Effect of Ce on inclusions and impact property of 2Cr13 stainless steel[J]. Journal of Iron and Steel Research, 2010, 17(12): 59-64.
[11]董方, 崔志峰, 沈国慧, 等. 铈对特种防护钢板组织和力学性能的影响[J]. 中国稀土学报, 2016, 34(3): 320-326.
Dong Fang, Cui Zhifeng, Shen Guohui, et al. Effects of cerium on microstructure and mechanical properties of bulletproof steel[J]. Journal of the Chinese Rare Earth Society, 2016, 34(3): 320-326.
[12]黄宇, 谢有, 成国光, 等. 稀土对H13钢中夹杂物的影响[J]. 稀土, 2018, 39(5): 16-23.
Huang Yu, Xie You, Cheng Guoguang, et al. The effect of rare earth on the inclusions in H13 steel[J]. Rare Metals, 2018, 39(5): 16-23.
[13]李言栋, 刘承军, 姜茂发. 铈在253MA耐热钢中赋存状态的热力学分析[J]. 金属功能材料, 2014, 21(3): 15-18.
Li Yandong, Liu Chengjun, Jiang Maofa. Thermodynamic study on the occurrence of cerium in 253MA heat-resistant steel[J]. Metallic Functional Materials, 2014, 21(3): 15-18.
[14]李阳, 杨光, 姜周华. 铈对27%Cr超级铁素体不锈钢凝固组织影响机制研究[J]. 中国稀土学报, 2019(1): 57-63.
Li Y, Yang G, Jiang Z H. Effect of cerium on solidification structure of 27%Cr super ferritic stainless steel[J]. Journal of the Chinese Rare Earth Society, 2019(1): 57-63.

[1]	Luo Diqiang, Yu Yinhong, Zhang Zhenming, Feng Xiaoming, Liu Min, Lai Chaobin. Effect of yttrium-based rare earth on inclusions and cryogenic temperature impact property of high strength shipbuilding steel [J]. Heat Treatment of Metals, 2022, 47(3): 142-146.
[2]	Wu Hao, Deng Xiangtao, Li Chengru, Sui Yi, Zhang Tao, Ji Wenbo, Wang Zhaodong. Analysis on cold bending fracture of wear-resistant steel NM400 [J]. Heat Treatment of Metals, 2021, 46(9): 262-267.
[3]	Liu Yue, Han Shun, Li Yong, Wang Chunxu, Gao Yuanhang, Wang Rui, Li Jianxin. Effect of rare earth lanthanum on fatigue property of 300M steel [J]. Heat Treatment of Metals, 2021, 46(2): 14-19.
[4]	Zhang Jiawen, Fu Tianliang, Wu Hao, Wang Zhaodong. Cause analysis on quenching cracking of 40CrNiMo7 steel forged shaft [J]. Heat Treatment of Metals, 2021, 46(2): 213-217.
[5]	Bao Shun, Liu Rongpei, Wang Baoshun, Wu Minghua, Luo Youxin, Yao Liang, Feng Han, Song Zhigang. Effect of cerium additive on low temperature impact properties of S32750 super duplex stainless steel [J]. Heat Treatment of Metals, 2021, 46(11): 42-47.
[6]	Zhang Zhenwei, Zhu Yujin, Jiang Rui, Zhao Jie, Chen Yun, Li Yulei, Ding Boyuan. Metallographic examination of aluminum alloy piston of an internal combustion engine [J]. Heat Treatment of Metals, 2021, 46(11): 258-261.
[7]	Guo Ran, Wang Fuming, Sun Lijuan. Analysis on cause of cold bending fracture of HRB400 hot-rolled ribbed bar [J]. Heat Treatment of Metals, 2021, 46(10): 257-261.
[8]	Zhang Jian, Huang Daosi, Zhao Longzhi, Jiao Haitao, Tang Yanchuan, Liu Dejia, Zhao Mingjuan, Li Jin. Effect of rare earth Ce on properties of high-boron bainite coating prepared by laser cladding [J]. Heat Treatment of Metals, 2021, 46(1): 133-137.
[9]	He Liangliang, Wang Yuandong, Wang Mengmeng, Hou Shengwen, Wang Yan. Failure analysis of gear fracture cracking during bench test [J]. Heat Treatment of Metals, 2021, 46(1): 235-238.
[10]	Li Mingyang, Wang Fuming, Li Ming, Gong Shuo. Effect of inclusions on fatigue life of engineering machinery structural steel Q345FCA [J]. Heat Treatment of Metals, 2020, 45(8): 7-11.
[11]	Li Jianxin, Luo Zhiqiang, Cheng Shichao, Yang Maosheng, Sun Yong, Pang Xuedong. Fatigue performance and crack initiation of 16Cr3NiWMoVNbE gear steel [J]. Heat Treatment of Metals, 2020, 45(7): 167-172.
[12]	Chen Wei, Wang Yong, Han Jian. Cause analysis on spalling of working roll during cold rolling [J]. Heat Treatment of Metals, 2020, 45(6): 232-235.
[13]	Sun Xuejiao. Causes analysis on anormal elongation of low-alloyed high strength steel [J]. Heat Treatment of Metals, 2020, 45(5): 262-265.
[14]	Meng Xiaoliang, Yu Yanchong, Kang Jian, Su Cheng, Wang Shebin. Effect of rare earth on inclusions and low temperature impact properties of A572.Gr65 steel [J]. Heat Treatment of Metals, 2020, 45(11): 15-18.
[15]	Yang Zhirong, Yan Desheng, Yang Huaijun. Effect of inclusions on impact performance of 15MnB steel [J]. Heat Treatment of Metals, 2020, 45(11): 32-37.