Preparation of graphene nanowalls on tungsten and single crystal silicon plate by thermal treatment of carbon plasma

doi:10.13251/j.issn.0254-6051.2020.07.028

Abstract

Abstract: The graphene nanowalls were prepared directly on the surface of W metal and monocrystalline Si substrate by plasma thermal treatment. The microstructure and components of the samples were characterized by means of XRD, SEM and Raman spectroscopy, and the surface hardness were tested by using micro vickers hardness tester. The results show that the composite layers deposited on the surface of W and Si substrates are consisting of W₂C-WC/graphene and SiC/graphene, respectively, which distribute uniformly. Based on the layer of W₂C-WC/graphene, the surface hardness of metal W is 502.95 HV0.01, which increases by 52.54 HV0.01 and 11.6% compared with the pure metal W of 450.41 HV0.01. Based on the layer of SiC/graphene composite layer, the surface hardness of SiC/ graphene is 836.76 HV0.025, which increases by 24.02 HV0.025 and 2.95% compared with that of single crystal Si substrate of 812.74 HV0.025.

Key words: metal W, WC, SiC, plasma, graphene

CLC Number:

O472

Cheng Yifei, Luo Fei, Liu Dabo, Zhou Haitao, Tian Ye, Hu Chunwen, Luo Bingwei. Preparation of graphene nanowalls on tungsten and single crystal silicon plate by thermal treatment of carbon plasma[J]. Heat Treatment of Metals, 2020, 45(7): 139-142.

References

[1]邹卫武, 顾宝珊, 孙世清, 等. 石墨烯及其复合材料在空气净化领域的应用研究进展[J]. 碳素技术, 2020, 39(1): 6-11.
Zou Weiwu, Gu Baoshan, Sun Shiqing, et al. Research progress of graphene and its composite materials in the field of air purification[J]. Carbon Techniques, 2020, 39(1): 6-11.
[2]Dontschuk N, Stacey A, Tadich A, et al. A graphene field-effect transistor as amoleculespecific probe of DNA nucleobases[J]. Nature Communication, 2015, 6: 6563.
[3]黄卫星, 汪涛, 袁揭, 等. 粉末区熔法制备石墨烯/AlSi12复合材料的组织和性能[J]. 金属热处理, 2019, 44(12): 38-43.
Huang Weixing, Wang Tao, Yuan Jie, et al. Microstructure and properties of grapheme/AlSi12 composites prepared by power zone melting process[J]. Heat Treatment of Metals, 2019, 44(12): 38-43.
[4]Geim A K. Graphene: Status and prospects[J]. Science, 2009, 324(5934): 1530-1534.
[5]王雅珍, 庆迎博, 孟爽, 等. 石墨烯制备及应用研究进展[J]. 化学世界, 2019, 60(7): 385-394.
Wang Yazhen, Qing Yingbo, Meng Shuang, et al. Progress in preparation and application of graphene[J]. Chemical World, 2019, 60(7): 385-394.
[6]Vlassiouk I V, Stehle Y J, Pudasaini P R, et al. Evolutionary selection growth of two-dimensional materials on polycrystalline substrates[J]. Nature Materials, 2018, 17: 318-322.
[7]何延如, 田小让, 赵冠超, 等. 石墨烯薄膜的制备方法及应用研究进展[J]. 材料导报, 2020, 34(3): 5048-5060.
He Yanru, Tian Xiaorang, Zhao Guanchao, et al. Research progress in preparation and application of graphene films[J]. Materials Reports, 2020, 34(3): 5048-5060.
[8]Luo B W, Zhou H T, Liu D B, et al. One-step in-situ reaction synthesis of TiC/graphene composite thin lm for titanium foil surface reinforcement[J]. Vacuum, 2019, 160: 472-477.
[9]Zhou H T, Liu D B, Luo F, et al. Direct deposition of graphene nanowalls on the ceramic powders for the fabrication of a ceramic matrix composite[J]. Chinese Physics B, 2019, 28(6): 27-31.
[10]Berciaud S P, Ryu S, Brus L E, et al. Probing the intrinsic properties of exfoliated graphene: Raman spectroscopy of free-standing monolayers[J]. Nano Letters, 2009, 9(1): 346-352.
[11]Malardal L M, Pimenta M A, Dresselhaus G. Raman spectroscopy in grapheme[J]. Physics Reports, 2009, 473: 51-58.
[12]Jiang L L, Yang T Z, Liu F, et al. Controlled synthesis of large-scale, uniform, vertically standing graphene for high-performance field emitters[J]. Advanced Materials, 2013, 25: 250-255.

[1]	Zhao Zishuo, Wu Meiping, Miao Xiaojin, Cui Chen, Gong Yuling. Effect of laser power on microstructure and corrosion resistance of FeCoNiCrMo high-entropy alloy/graphene oxide composite coating [J]. Heat Treatment of Metals, 2022, 47(4): 251-257.
[2]	Zhou Zhongping, Zhang Xiaojuan, Bai Lu, Yu Fangyin, Min Yong'an. Microstructure and properties of T250 steel after plasma nitriding [J]. Heat Treatment of Metals, 2022, 47(3): 210-214.
[3]	Zhang Mengliang, Tang Wenbo, Li Baiqi, Wang Xiaosheng, Li Wenqiang, Wang Tengfei. Microstructure and properties of additional and in situ synthesized WC particle reinforced iron-based coatings prepared by plasma cladding [J]. Heat Treatment of Metals, 2022, 47(2): 200-204.
[4]	Sun Dingbang, Wang Yongsheng, Gao Jie, He Zhiyong, Wu Yanxia, Zhou Bing, Ma Yong, Yu Shengwang. Effect of plasma surface metallizing Nb on diffusion welding performance of γ-TiAl alloy [J]. Heat Treatment of Metals, 2022, 47(2): 213-218.
[5]	Zhang Pengqi, Shang Hongbao, Li Li, Zhou Zhiqiang. Application of plasma hardening process for 316L stainless steel valve inner parts [J]. Heat Treatment of Metals, 2022, 47(1): 212-216.
[6]	Li Zhu, Zhang Qingyong, Kong Linghua, Lian Guofu, Yang Jinwei. Characterization of hardness for GCr15 steel based on laser-induced breakdown spectroscopy [J]. Heat Treatment of Metals, 2022, 47(1): 284-289.
[7]	Gong Hao, Kong Debin, Guo Lina, Han Hongwen, Gong Jingjing, Fang Hongjie. Influence of intermediate annealing on microstructure and properties of cold rolled AlMgSiCu aluminum alloy sheet [J]. Heat Treatment of Metals, 2021, 46(9): 129-132.
[8]	Li Li, Ye Hong, Liu Yue, She Hongyan, Qu Wei, Shen Dachen, Chen Li. Microstructure and wear resistance of laser clad Ni/Ni-WC gradient coating on Cr12MoV steel [J]. Heat Treatment of Metals, 2021, 46(9): 223-228.
[9]	Zhou Jianbo, Zhang Jing, Zhang Leitao, Li Haitao, Fan Shuaiqi, Xu Jinfu. Effect of laser process parameters on crack rate and microstructure of Ni60/WC clad coating [J]. Heat Treatment of Metals, 2021, 46(9): 252-257.
[10]	Li Jingyang, Wang Wenbo, Qin Lin, He Longbin, La Lingmin, Zhang Jianlin, Duan Xinglu. Friction and wear properties of nitrided layer of TD3 titanium alloy [J]. Heat Treatment of Metals, 2021, 46(9): 258-261.
[11]	Ren Junpeng, Wang Yu, Dong Cuige, Zhao Jun. Effect of Cu addition on microstructure and properties of SiC_p/Al-Si composites [J]. Heat Treatment of Metals, 2021, 46(8): 36-41.
[12]	Xu Hongyang, Meng Wenglu, Lu Jinbin, Ma Mingxing. Phase and stability analysis of CrCuFeNiTi high entropy alloy coating based on first principles [J]. Heat Treatment of Metals, 2021, 46(7): 60-64.
[13]	Zhu Jianwei, Qi Shaobao, Li Guodong, Wang Zhijian, Ma Fei, Qi Tonghui, Li Zhijie, Li Guang, Xia Yuan. Effect and mechanism of pulse frequency on thermal property of aluminum based plasma electrolytic oxidation coating [J]. Heat Treatment of Metals, 2021, 46(7): 195-200.
[14]	Luo Jiandong, Yang Yingyi, Lin Yuzhou. Effect of plasma diffusion process on surface microstructure and magnetic properties of 316L stainless steel [J]. Heat Treatment of Metals, 2021, 46(7): 207-211.
[15]	Chen Zixin, Zhou Houming, Xu Caixing, Da Limei, Zhu Yuxu, He Fangjia, Wang Zeda. Laser cladding remanufacturing process of aircraft landing gear based on 30CrMnSiNi2A steel [J]. Heat Treatment of Metals, 2021, 46(6): 45-52.