Effect of La content on oxidation resistance of Fe-based corrosion resistant alloy

doi:10.13251/j.issn.0254-6051.2020.07.030

Abstract

Abstract: Oxidation resistance of Fe-base corrosion resistant alloys with different La content at 850 ℃ was studied by using XRD, SEM and EDS techniques. The results show that at 850 ℃, with the increase of La content, the anti-oxidation property of the alloy is reduced to a certain extent, but the adhesion of the oxide film to the matrix is greatly improved. The oxide film can be fixed on the alloy matrix tightly with the increase of La content by promoting the internal diffusion of oxygen and make the inner oxide layer become dendritic and go deep into the alloy matrix. The oxide film is mainly composed of three layers: the outer layer is the mixed layer of Fe₂O₃ and CuO, and contains a small amount of NiFe₂O₄; the middle layer is a protective layer dominated by NiFe₂O₄, and contains a small amount of Fe₂O₃ and NiO; the inner layer is an inner oxidation zone dominated by Fe₂O₃ and contains a small amount of NiO oxide.

Key words: rare earth La, Fe-based corrosion resistant alloy, high temperature oxidation, oxide film

CLC Number:

TG133+.4

Li Dongsheng, Chai Dengpeng, Hou Guanghui, Li Zhiyuan, Liu Ying, Liu Dan. Effect of La content on oxidation resistance of Fe-based corrosion resistant alloy[J]. Heat Treatment of Metals, 2020, 45(7): 148-152.

References

[1]刘杰, 潘晴川, 车畅, 等. Si含量对铁基高温合金抗氧化性能的影响[J]. 铸造技术, 2017, 38(7): 1547-1550.
Liu Jie, Pan Qingchuan, Che Chang, et al. Effect of Si content on oxidation resistance of iron-based superalloy[J]. Foundry Technology, 2017, 38(7): 1547-1550.
[2]陈晨, 杨志南, 张福成. 40CrNiMoV钢在大尺寸轴承中的应用[J]. 金属热处理, 2017, 42(4): 6-11.
Chen Chen, Yang Zhinan, Zhang Fucheng. Application of 40CrNiMoV steel to heavy section bearing[J]. Heat Treatment of Metals, 2017, 42(4): 6-11.
[3]肖逸锋, 周年丰, 吴靓, 等. Cr含量对WC钢结硬质合金组织及力学性能的影响[J]. 金属热处理, 2017, 42(4): 22-26.
Xiao Yifeng, Zhou Nianfeng, Wu Liang, et al. Effect of chromium content on microstructure and mechanical properties of WC steel bonded carbide[J]. Heat Treatment of Metals, 2017, 42(4): 22-26.
[4]Pan T J, Li Y S, Yang Q, et al. Internal oxidation and phase transformations of multi-phase Fe-Ni-Al and Fe-Ni-Al-Cr alloys induced by KCl corrosion[J]. Corrosion Science, 2011, 53(6): 2115-2121.
[5]王志武, 刘倩倩, 龚雪婷. Fe-Ni合金在600 ℃空气中的氧化行为[J]. 金属热处理, 2016, 41(8) : 6-10.
Wang Zhiwu, Liu Qianqian, Gong Xueting. High-temperature oxidation behavior of Fe-Ni alloy at 600 ℃ in air[J]. Heat Treatment of Metals, 2016, 41(8) : 6-10.
[6]Haugsrud Reidar. On the high-temperature oxidation of Fe, Co, Ni and Cu-based alloys with addition of a less noble element[J]. Materials Science and Engineering A, 2001, 298(1): 216-226.
[7]陈刚, 张弛, 上田光敏, 等. 水蒸气对Fe-Cr-Ni合金在800 ℃时的氧化膜形貌的影响[J]. 金属热处理, 2012, 37(10): 25-28.
Chen Gang, Zhang Chi, Ueda Mitsutoshi, et al. Effect of water vapor on morphology of oxide scales of Fe-Cr-Ni alloy at 800 ℃[J]. Heat Treatment of Metals, 2012, 37(10): 25-28.
[8]赵谦, 王福明, 何煜天, 等. 不同氧含量的Fe-36Ni因瓦合金的晶间内氧化行为[J]. 金属热处理, 2015, 40(11) : 60-63.
Zhao Qian, Wang Fuming, He Yutian, et al. Effect of total oxygen content on intergranular oxidation behavior of Fe-36Ni invar alloy at high temperature[J]. Heat Treatment of Metals, 2015, 40(11) : 60-63.

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[13]	Liu Sheng, Sun Jianzhong, Gao Hongbo, Qiu Gaosong, Liu Chunyan. Effect of microalloying elements on high temperature oxidation of ultra low carbon steels [J]. HTM, 2016, 41(4): 105-109.
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