Heat Treatment of Metals ›› 2021, Vol. 46 ›› Issue (1): 125-132.DOI: 10.13251/j.issn.0254-6051.2021.01.024

• SURFACE ENGINEERING • Previous Articles     Next Articles

Effect of surface oxidizing at 550 ℃ on wear resistance of Ti-6Al-4V alloy

Yang Jie1,2, Zhang Qingke2, Li Qiong3, Song Zhenlun2, Wu Xiaochun1   

  1. 1. School of Materials Science and Engineering,Shanghai University,Shanghai 200072,China;
    2. Key Laboratory of Marine Materials and Related Technologies,Zhejiang Key Laboratory of Marine Materials and Protective Technologies,Ningbo Institute of Materials Technology and Engineering,Chinese Academy of Sciences,Ningbo Zhejiang 315201,China;
    3. Medtronic Inc,Minneapolis 55432,USA;
    4. Shi-changxu Innovation Center for Advanced Materials,Institute of Metal Research,Chinese Academy of Sciences,Shenyang Liaoning 110016,China;
    5. School of Materials Science and Engineering,University of Science and Technology of China,Shenyang Liaoning 110016,China
  • Received:2020-04-08 Online:2021-01-25 Published:2021-01-26

Abstract: Thermal oxidation (TO) of Ti-6Al-4V alloy was performed at 550 ℃ for 60 h in air,and the surface morphology,microstructure,composition,hardness,scratch performance and wear resistance of the TO treated and untreated alloy were evaluated and compared.The results reveal that the surface roughness of the Ti alloy increases a little after TO,an oxygen-diffusion layer of about 3.5 μm thickness is formed on the surface,and anatase,rutile,brookite TiO2 and Al2O3 phases are detected by X-ray diffraction (XRD).The microhardness and nano hardness of the oxygen-diffusion layer are 804.6 HV0.025 and 14.5 GPa,respectively,which is 143.7% higher than that of the untreated substrate,and no cracking is observed around the indentations.The maximum scratch depth is significantly reduced from 12 μm to 4 μm after TO,and the wear rate decreases from 354.33×10-6 mm3/Nm to 1.44×10-6 mm3/Nm,and the main wear mechanism of the oxygen-diffusion layer is slight abrasive wear.It is concluded that the surface TO treatment considerably increases the surface hardness and wear resistance of the Ti-6Al-4V alloy,but leads no obvious inner microstructure coarsening and softening,thus could be a potential method to improve the surface wear resistance of Ti alloys.

Key words: surface oxidizing, titanium alloy, oxygen-diffusion layer, hardness, wear resistance

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