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  • PROCESS RESEARCH
    Effect of I&Q&P process on microstructure and properties of high-boron iron-based wear-resistant alloy
    Wang Kai, Wu Zhifang, Wu Run, Li Mingwei
    2020, 45(7):  1-6.  doi:10.13251/j.issn.0254-6051.2020.07.001
    Abstract ( 74 )   PDF (3678KB) ( 48 )  
    Effect of I&Q&P process on the microstructure and properties of high-boron iron-based wear-resistant alloys was studied by means of optical microscope(OM), scanning electron microscope(SEM), X-ray diffraction(XRD) and rockwell hardness tester. The results show that the as-cast microstructure of the high-boron iron-based alloys consists of ferrite, martensite, retained austenite and eutectic boride. The boride is mainly Fe2B and Fe23(B,C)6. After treated by I&Q&P process, the volume fraction of retained austenite in the alloys is increased from 10.0% to 16.8%, the impact absorbed energy of the alloy is increased from 3.76 J to 6.80 J, the hardness value is decreased from 59.3 HRC to 54.0 HRC, and a new boride Fe3 (B,C) is generated. At the same time, the wear resistance of the alloy is significantly improved.
    Effect of annealing process on microstructure and   properties of pure copper wire T2
    Mao Xiqin, Xiao Qiulei, Ou Meigui, Liang Yu, Long Wei
    2020, 45(7):  7-10.  doi:10.13251/j.issn.0254-6051.2020.07.002
    Abstract ( 93 )   PDF (1931KB) ( 179 )  
    T2 pure copper wire was obtained by cold drawing, then low-temperature long-term annealing (400 ℃×60 min) and high-temperature short-term annealing (at 850 ℃ for 20, 40, 60 s, respectively) tests were carried out. The microstructure, mechanical and electrical properties of the wires in different states were studied by means of OM, SEM, universal testing machine and DC wheat stone bridge. The results show that the fibrous structure of the cold drawn T2 pure copper wire forms recrystallized grains after annealing accompanied by annealing twins. With the increase of annealing time at 850 ℃, the recrystallized grains of the wire grow continuously, and the grains morphologies tend to equiaxed, and the uniformity of wire structure is improved. The average tensile strength of annealed wire is about 57.1% of that of drawn wire, the percentage elongation after breaking was about 10 times of that of drawn wire, after annealing at 400 ℃ for 60 min, the conductivity of the wire is only 0.3% higher than that of the drawn wire; after annealing at 850 ℃ for 20,40 and 60 s, the average conductivity of the wire is 5.2% higher than that of the drawn wire. The mechanical and electrical conductivity properties of the wire after high-temperature short-time annealing are not only better than low-temperature long-time annealing, but have a higher annealing efficiency. In conclusion, the wire annealed at 850 ℃ for 40 s has high mechanical properties and electrical conductivity.
    Effect of solution and aging on microstructure and properties of Cu-Ni-Co-Si alloy
    Zou Jinfeng, Yu Fangxin, Cheng Jianyi, Cai Zhijun
    2020, 45(7):  11-16.  doi:10.13251/j.issn.0254-6051.2020.07.003
    Abstract ( 81 )   PDF (2093KB) ( 28 )  
    Effects of solution and aging on the properties and microstructure of Cu-Ni-Co-Si alloy were investigated by means of hardness and electrical conductivity measurement, optical microscope and transmission electron microscope (TEM). The results show that the Cu-Ni-Co-Si alloy has good comprehensive properties after solution treating at 950 ℃ for 30 min plus aging at 500 ℃ for 480 min, its hardness is 243.55 HV3, electrical conductivity is 42.24%IACS. A few vanadium is beneficial to improve the electrical conductivity of the alloy after two-step aging, and pre-aging is beneficial to improve the electrical conductivity and hardness of the alloy, so that the two-step aging specimen can quickly obtain good comprehensive properties. The main strengthening phases of the Cu-Ni-Co-Si alloy are δ-(Co, Ni)2Si, and the orientation relationship between the matrix and the precipitate phase is [001]m//[110]p, (010)m //(001)p.
    Effect of hot deformation process on flow stress and microstructure of sulfur-containing non-quenched and tempered steel
    Xie Jianfeng, Wu Xiaodong, Luo Rui, Wang Lianjin
    2020, 45(7):  17-22.  doi:10.13251/j.issn.0254-6051.2020.07.004
    Abstract ( 74 )   PDF (3528KB) ( 42 )  
    Single-pass compression tests of sulfur-containing non-quenched and tempered steel were done at 950-1150 ℃ with strain rate of 0.01-5 s-1by Gleeble-3500 thermal simulation machine. Effect of hot deformation process on the flow stress and microstructure was studied. The results show that the peak stress during hot compression increases with the increase of strain rate and decreases with the increase of temperature, the average grain size of dynamic recrystallization decreases with the increase of strain rate and deformation amount, and increases with the increase of temperature.
    Effect of annealing temperature on microstructure and properties of medium manganese TRIP steel
    Zhang Xinyue, Feng Yunli, Cao Kuo
    2020, 45(7):  23-27.  doi:10.13251/j.issn.0254-6051.2020.07.005
    Abstract ( 68 )   PDF (2744KB) ( 34 )  
    Effects of different annealing temperatures on the microstructure and properties of hot rolled medium manganese TRIP steel were investigated by means of optical microscope, scanning electron microscope, electronic universal drawing machine, EBSD and XRD analysis. The results show that the hot rolled microstructure of the steel is δ-ferrite strips, martensite and retained austenite. When the annealing temperature increases from 600 ℃ to 900 ℃, the yield strength decreases from 610.3 MPa to 496.7 MPa, and the tensile strength decreases from 757.3 MPa to 630.4 MPa, while at 700 ℃ the maximum elongation (44.9%) can be obtained. On the whole, when the hot rolled tested steel is annealed at 700 ℃, the comprehensive mechanical properties are the best and the strength-elongation product is the highest, which is 33.8 GPa·%.
    Effect of cryogenic treatment on surface properties of K6509 Co-based alloy
    Wang Xingfu, Li Yonggang, Lei Da, Shi Youjie, Li Xuenan
    2020, 45(7):  28-31.  doi:10.13251/j.issn.0254-6051.2020.07.006
    Abstract ( 71 )   PDF (2031KB) ( 30 )  
    Surface properties of K6509 Co-based alloy specimens cryogenic treated by -196 ℃ liquid nitrogen for 24 h and 48 h were studied and compared with non-cryogenic specimens by means of microstructure analysis, XRD component analysis and hardness analysis, and the changes of surface roughness and morphologies after cryogenic treatment and rolling polishing were analyzed. The results show that some of the carbides in Co-base alloy are roughened and the fine carbides are precipitated after 24 h cryogenic treatment, but after 48 h cryogenic treatment, the fine carbide decreases, the carbide coarsening disappears, and the microstructure becomes uniform. The XRD patterns show that the phase composition does not change during the cryogenic process, but the peak value shift at the eutectic phase containing M27C6 carbide and the eutectic phase containing M7C3 carbides, and the diffraction peak intensity of the M27C6 carbides changes significantly. The hardness is significantly increased by prolonging the cryogenic time, and the hardness is increased by 17.6% after 48 h cryogenic treatment. The combination of reasonable cryogenic time and rolling polishing can significantly improve the surface quality. After 48 h cryogenic treatment and rolling polishing, the surface roughness decreases the most, and the Ra value decreases from 1.215 μm to 0.662 μm, and the surface defects are significantly reduced and the surface consistency is well.
    Effect of tempering temperature on microstructure and properties of 22MnB5 steel for automobile
    Wang Simin, Hu Zhihua, Wang Zhengyun, Luan Daocheng, Wang Nan, Chen Jie
    2020, 45(7):  32-36.  doi:10.13251/j.issn.0254-6051.2020.07.007
    Abstract ( 87 )   PDF (2371KB) ( 54 )  
    Microstructure and properties of 22MnB5 steel for automobile after tempering at 150-300 ℃ were studied by means of optical microscope, SEM, TEM and universal testing machine. The results show that after quenching and tempering, the structure of 22MnB5 steel is mainly tempered martensite, and obvious second phase precipitation is observed under transmission electron microscope, which has good plastic deformation resistance. With the increase of tempering temperature, supersaturated α phase recovers and precipitates carbides, and the mechanical properties gradually decrease. In the tested temperature range, the mechanical properties of the 22MnB5 steel reach the best at 150 ℃, and the tensile strength and hardness are 1583 MPa and 48 HRC respectively.
    Effect of intercritical temperature on microstructure and mechanical properties of medium manganese steel after IQ&P treatment
    Tian Yaqiang, Cao Zhongqian, Pan Hongbo, Song Jinying, Zheng Xiaoping, Chen Liansheng
    2020, 45(7):  37-41.  doi:10.13251/j.issn.0254-6051.2020.07.008
    Abstract ( 74 )   PDF (1538KB) ( 35 )  
    Effect of intercritical temperature on the microstructure and mechanical properties of IQ&P treated 0.1C-7Mn steel was investigated by means of scanning electron microscope and room temperature tensile testing. The results show that the mechanical properties of the steel first increase and then decrease with intercritical temperature increasing. When the intercritical temperature is 660 ℃, the mechanical properties of the steel are optimal, with the strength-elongation product reaching the maximum of 21.2 GPa·%. When the IQ&P process is carried out at higher and lower intercritical temperature, there is no martensite transformation due to the high stability of the retained austenite. In addition, when the intercritical temperature is 660 ℃, there is a clear yield platform in the tensile stress-strain curve, while it disappears when the intercritical temperature goes higher.
    Effect of heat treatment on microstructure and properties of 12Cr steel
    Wang Fenling, Liu Yujiong, Wang Tianjian, Pei Yubing, Gong Xiufang
    2020, 45(7):  42-44.  doi:10.13251/j.issn.0254-6051.2020.07.009
    Abstract ( 74 )   PDF (1959KB) ( 26 )  
    Microstructure and properties of 12Cr steel after different heat treatment were investigated by using OM, tensile test, hardness and impact test at room temperature. The results show that the quenching temperature has a significant effect on the grain size of the 12Cr steel.The grain size of the 12Cr steel gradually grows with the quenching temperature increasing, while the impact property is improved and the hardness is increased significantly. The strength of the 12Cr steel is decreased gradually with tempering temperature increasing. When the quenching temperature rises to 1160 ℃, the grain size is up to 3 grade, when the tempering temperature exceeds 700 ℃, the short-term rupture property of the steel is significantly worse. When quenched at 1100 ℃ and tempered at 680 ℃, the microstructure of the 12Cr steel is tempered lath martensite, and the short-term rupture property is optimal.
    Effect of solution and aging treatment on microstructure and properties of TC6 alloy
    Sun Yueying, Jing Ran, Ye Xi, Zhang Manxue, Xie Niansuo
    2020, 45(7):  45-50.  doi:10.13251/j.issn.0254-6051.2020.07.010
    Abstract ( 82 )   PDF (4517KB) ( 31 )  
    Effect of solid solution and aging treatment on microstructure, phase structure and mechanical properties of TC6 alloy was investigated via optical microscope (OM), scanning electron microscope (SEM), X-ray diffraction (XRD), Vickers hardness tester and mechanical properties testing system. The results show that the TC6 alloy is mainly composed of lamellar α phase, needle-like martensite α′ phase and β phase after solution treatment at 900 ℃. However, after solution treatment at 1000 ℃, the alloy is mainly composed of needle-like martensite α′ phase and β phase. During the aging process at different temperatures, the α′ martensite phase formed under water quenching is decomposed and transformed into α and β phases completely. Also, with the aging temperature increasing, the relative content of β phase increases gradually. By comparison, the overall mechanical properties of the TC6 alloy after solution treatment at 900 ℃ and aging at 500 ℃ are the optimal, with the compressive strength and yield strength being 2000 MPa and 1061 MPa respectively, and the hardness value being 499 HV0.2.
    Hot deformation behavior and processing maps of 022Cr steel
    Li Rongbin, Chen Yongqiang, Jiang Chunxia, Zhang Rulin, Shang Hailong
    2020, 45(7):  51-56.  doi:10.13251/j.issn.0254-6051.2020.07.011
    Abstract ( 60 )   PDF (591KB) ( 39 )  
    Hot deformation behavior of the 022Cr steel was studied by a Gleeble 3180 thermal simulation test machine, and the relationship between deformation resistance and deformation degree, deformation temperature and strain rate was revealed. The thermal compression was performed at temperature in range of 950-1200 ℃ and at strain rate in range of 0.001-5 s-1, and a dynamic deformation model of the 022Cr steel was established by using a dynamic material model (DMM). The results show that as the deformation temperature increases and the strain rate decreases, the flow stress of the 022Cr steel decreases. The deformation activation energy calculated from the data of the flow stress curve is 381.615 kJ/mol. When the strain is not less than 0.5, the optimal deformation conditions of the 022Cr steel for hot working have two regions. The first region is in the temperature range of 1100-1200 ℃, the strain rate is in the range of 0.001-0.01 s-1, and the second region is in the temperature range of 1130-1180 ℃, strain rate range of 1-5 s-1, its power consumption efficiency can reach more than 0.4.
    Effect of Q&P process on microstructure and mechanical properties of 22MnB5 steel
    Liang Xiao, Luo Ping, Li Xianjun, Zhang Wenliang, Xie Huasheng
    2020, 45(7):  57-62.  doi:10.13251/j.issn.0254-6051.2020.07.012
    Abstract ( 70 )   PDF (596KB) ( 30 )  
    Microstructure and mechanical properties of 22MnB5 steel were characterized by means of optical microscope (OM), universal tensile testing machine, scanning electron microscope (SEM), Xray diffraction(XRD) and electron backscattered diffraction (EBSD). The relationship between the volume fraction of retained austenite, the carbon in retained austenite and the mechanical properties of 22MnB5 steel treated by onestep Q&P process were analyzed. The results show that an ultrahighstrength 22MnB5 steel sheet with tensile strength over 1400 MPa and elongation over 15% can be obtained using the onestep Q&P process. As the quenching temperature is increased from 240 ℃ to 300 ℃, the microstructure of 22MnB5 steel can be changed from martensite to martensite+retained austenite complex, and the volume fraction of retained austenite in the specimen is increased gradually. With extending partitioning time at the same partitioning temperature, the volume fraction of retained austenite increases first and then decreases. The average carbon content in retained austenite under different heat treatment processes is 1.49wt%. The onestep Q&P heat treatment process can enrich carbon in the retained austenite, improve the stability of the retained austenite, and the product of strength and elongation can reach 22.14 GPa·%.
    High-temperature retrogression and re-aging process of Al-6.8Zn-2.3Mg-2.0Cu-0.15Sc alloy
    Shi Wenjie, Wang Chunhua
    2020, 45(7):  63-67.  doi:10.13251/j.issn.0254-6051.2020.07.013
    Abstract ( 64 )   PDF (595KB) ( 23 )  
    Properties and microstructure evolution laws of Al-6.8Zn-2.3Mg-2.0Cu-0.15Sc alloy in the process of high-temperature retrogression and re-aging (RRA) were studied via technological means such as sclerometer, digital eddy current metal conductometer, transmission electron microscope (TEM), universal tensile testing machine and scanning electron microscope (SEM). The results show that in the retrogressive process at 170 ℃ the alloy has high hardness and excellent electrochemical corrosion resistance. The principal phase η′ of the alloy is fine, dispersed and numerous after the retrogressive process at 170 ℃ for 1 h, and it strengthens the alloy with Orowan mechanism by virtue of dislocation cutting in the process of deformation. Therefore, it achieves the strength of 625.1 MPa and the elongation of 9.6 %, and is superior to one-step aging (T6) G.P. area with the strength of 592.4 MPa and the elongation of 6.5%. The strength is enhanced by 32.7 MPa and the elongation is increased by 47.7%. In addition, the appearance of tensile fracture presentes a complete ductile fracture characteristic via SEM. The excellent RRA process of the Al-6.8Zn-2.3Mg-2.0Cu-0.15 Sc alloy is aging at 140 ℃ for 24 h, regression aging at 170 ℃ for 1 h and re-aging at 160 ℃ for 24 h.
    Optimization of laser quenching process and characteristics of microstructure and properties of 50CrV steel screwdriver cutting edge
    Cui Lujun, Zhang Meng, Guo Shirui, Li Xiaolei, Cui Yinghao, Zheng Bo, Cao Yanlong, Zeng Wenhan
    2020, 45(7):  68-72.  doi:10.13251/j.issn.0254-6051.2020.07.014
    Abstract ( 141 )   PDF (591KB) ( 26 )  
    In order to improve the hardness and wear resistance of screwdriver head and prolong its service life, based on the pre-test of laser quenching thin-walled parts, laser quenching test was carried out on screwdriver cutting edge with high power fiber coupled semiconductor laser. Microstructure, microhardness and wear resistance of the laser quenched area of cutting edge were analyzed by means of optical microscope, microhardness meter and friction and wear tester, and the feasible process parameters of laser quenching for the screwdriver cutting edge were determined. The experimental results show that after laser quenching, the cutting edge consists of three parts: the completely hardened zone, the transition zone and the base material. The microstructure of the completely hardened zone is composed of needle-shaped martensite and retained austenite, and the transition zone is composed of martensite and tempered sorbite. The reasonable process parameters of the laser quenching for cutting edge are laser power 600 W and scanning speed 900 mm/min. After laser quenching, the average hardness of the edge section is 805.7 HV0.3, which is 177.4 HV0.3 higher than that before quenching; and the surface hardness value is 816.7 HV0.3, which is 188.4 HV0.3 higher than that before quenching. After quenching, the surface abrasion loss of the cutting edge is 0.5 mg, which is 27.8% of that of the substrate, and the stable friction coefficient is 0.25, which is 65.8% of that of the substrate. The laser quenching process can effectively improve the microhardness and wear resistance of the screwdriver cutting edge, and can be used to strengthen the surface performance of the screwdriver blade.
    Effect of solid solution and aging on α-phase microstructure evolution and hardness of TC20 titanium alloy
    Wu Lifan, Li Tao, Li Zhenliang
    2020, 45(7):  73-77.  doi:10.13251/j.issn.0254-6051.2020.07.015
    Abstract ( 64 )   PDF (598KB) ( 23 )  
    TC20 alloy specimens treated by different heat treatment processes, as well as first initial solution (840 ℃× 0.5 h) and then different aging treatment (460 ℃× 4 h, 320 ℃× 15 min→460 ℃× 4 h, 320 ℃× 10 min, 460 ℃× 10 min) were tested and characterized by SEM, TEM, XRD and hardness tester,and β→αphase transformation of TC20 alloy during α relative aging was studied. The results show that the hot rolled microstructure is composed of α and β phase, and many small α phases are formed in the solid solution structure. The lamellar-distributed α phase in the specimen is formed at 460 ℃ for 4 h, and the α phase with smaller length-width ratio is formed in the specimen when aged at 320 ℃ for 15 min→460 ℃ for 4 h, and most of the size of fine α phases is close to 100 nm. The second phase formed by the two aging methods is α phase, and the α phase with smaller size is obtained at 320 ℃ for 15 min→460 ℃ for 4 h. When the temperature reaches 460 ℃, a multitude of α phase nucleated in the β matrix can be carried out by ω phase, thus formed a dense and uniform distribution. The ω phase in the alloy is no longer exists after 320 ℃ for 15 min→460 ℃ for 4 h treatment, and more α phase is precipitated at the same time. The alloy hardness is up to 503 HV, which is significantly higher than that of β matrix, and the hardness of the alloy can be improved by the precipitation of α phase substantially.
    Effect of deformation induced precipitation on microstructure and properties of 7A20 aluminum alloy
    Jiang Shaojing
    2020, 45(7):  78-82.  doi:10.13251/j.issn.0254-6051.2020.07.016
    Abstract ( 57 )   PDF (594KB) ( 51 )  
    Effect of pre-deformation temperature and pre-precipitation time on precipitation behavior of the second phase,microstructure and mechanical properties of 7A20 aluminum alloy was investigated by means of OM, SEM, TEM, XRD and tensile tester. The results indicate that the average size of MgZn2 phase in the tested alloy is about 0.1 μm, and the fraction of precipitation phase is the most and distributed uniformly when deformed at 400 ℃. The peak value of yield strength and tension strength of the alloy are 170 MPa and 310 MPa, respectively, after pre-precipitation at 400 ℃ for 2 h, while the elongation reaches 20%. The fracture morphologies all exhibit ductile fracture characteristics. XRD peak of MgZn2 phase precipitates exists in the range of 40°-45° after hot rolling and pre-precipitation. The size of MgZn2 phase is about 0.1-0.2 μm, 0.3-0.8 μm and 0.6-1.0 μm after pre-precipitation for 1 h, 2 h and 4 h, respectively. The density of MgZn2 phase decreases with the increase of pre-precipitation time.
    Annealing process of high purity scandium metal
    Huang Pei, Huang Meisong, Fan Yuchuan, Liu Hua, Zhang Wenyang, Liu Wei
    2020, 45(7):  83-85.  doi:10.13251/j.issn.0254-6051.2020.07.017
    Abstract ( 67 )   PDF (597KB) ( 24 )  
    Effect of annealing temperatures on the hardness and microstructure of high-purity scandium after forging was investigated by using microhardness measurement and optical microscope observation. The results show that the average grain size of the scandium metal generally shows an upward trend as increasing of the annealing temperature under the same annealing time, and the hardness first decreases and then tends to be stable. When the annealing temperature is lower than 725 ℃, the recovery and recrystallization process are relatively slow and the growth of average grain size is limited, while the microhardness continues to decrease with the increase of the annealing temperature, which reaches the lowest point at 725 ℃. While the annealing temperature is above 725 ℃, the higher the annealing temperature, the larger the average grain size, and the microhardness tends to be stable with the increase of annealing temperature. The optimum annealing process for the high purity scandium metal consists of heating at 725 ℃ for 30 min. After annealing at 725 ℃ for 30 min, the high purity scandium metal after forging is fully annealed, the grains is uniform with a grain size of 135 μm, and the hardness value decreases from 169.5 HV2 before annealing to 129.6 HV2 after annealing.
    Optimization of heat treatment process of 980 MPa cold-rolling dual phase steel
    Chen Zhuo, Jin Bin, Wang Chengsi, Liu Jingbao, Kuang Shuang, Liu Liping, Wang Zhao, Li Mengxing, Yang Mingwei, Wang Jinrong
    2020, 45(7):  86-89.  doi:10.13251/j.issn.0254-6051.2020.07.018
    Abstract ( 61 )   PDF (590KB) ( 25 )  
    Effects of soaking temperature, slow cooling temperature and overaging temperature during continuous annealing on mechanical properties and microstructure of DP980 steel were investigated by means of Gleeble-3500 annealing simulator, optical microscope and tensile testing machine. The results indicate that the martensite content of the DP980 steel is increased with the increase of soaking temperature, which leads to the enhancement of yield strength and tensile strength accordingly. The optimal soaking temperature is 780 ℃. Effect of slow cooling temperature on mechanical properties of DP980 steel is investigated based on the control capability of equipment, and 670 ℃ is selected as the optimal temperature. Besides, the overaging temperature has been possessed large adjustment range on yield strength of DP980 steel, which can reduce the yield ratio significantly. With the increase of overaging temperature, the martensite content is remained stable and a little carbide is precipitated, which reduces the martensite strength and improves the plasticity of DP980 steel. The optimal parameters of soaking temperature, slow cooling temperature and overaging temperature are 780, 670, 320 ℃, respectively.
    Effect of pre-aging treatment on hardening response and microstructure of Al-Zn-Mg-Cu alloy
    Wei Maoyuan, Wang Hongzhen, Zhang Hong, Teng Dunbo
    2020, 45(7):  90-93.  doi:10.13251/j.issn.0254-6051.2020.07.019
    Abstract ( 54 )   PDF (594KB) ( 27 )  
    Effect of pre-aging treatment on mechanical properties and microstructure of Al-Zn-Mg-Cu aluminum alloy was investigated. The micro-hardness and mechanical properties were tested. The microstructure was characterized. The results indicate that the best pre-aging hardening effect of the experimental Al-Zn-Mg-Cu aluminum alloy is achieved while aging at 180 ℃ immediately after solution treatment, during which the peak value reaches 195 HV0.5 and the main hardening phase is η′ phase. The optimal pre-aging treatment is under 120 ℃×10 min. Thus, after 14 days natural aging, the hardness of the alloy is decreased by 13 HV0.5 or 10.7% compared to the solution+natural aging treatment. Finally after bake hardening process, the yield strength and tensile strength of the pre-aged alloy reach 465 MPa and 545 MPa, showing a hardening increase of 170 MPa and 95 MPa,respectively, and the elongation reaches 12.5%.
    Vacuum heat treatment process of BSW T15 steel
    Liu Junxiang, Yin Chengkun, He Longxiang, Cong Peiwu, Xu Yueming
    2020, 45(7):  94-96.  doi:10.13251/j.issn.0254-6051.2020.07.020
    Abstract ( 77 )   PDF (590KB) ( 34 )  
    Effects of quenching temperature and tempering temperature on the properties of BSW T15 steel after vacuum high temperature quenching were studied by means of vacuum quenching and tempering equipment, Rockwell hardness tester and scanning electron microscope, and the cracking reason of the BSW T15 steel during high temperature quenching was analyzed. The results show that the surface hardness is kept in the range of 62.5-64.5 HRC by reducing the quenching temperature by 10 ℃ from 1200 ℃,and the distortion variable is reduced and the quenching cracking is effectively prevented; the distortion variable is reduced to 0.15 mm by adopting appropriate tempering temperature, reasonable tooling and optimized process, and the heat treatment process indexes of the BSW T15 steel meet the process requirements.
    Effect of heat treatment process on microstructure and hardness of 0Cr13 cold-drawn wire
    Duan Luzhao, Cui Juan
    2020, 45(7):  97-100.  doi:10.13251/j.issn.0254-6051.2020.07.021
    Abstract ( 56 )   PDF (596KB) ( 28 )  
    Effect of heat treatment process on the microstructure and hardness of 0Cr13 cold-drawn wire was studied by Leica DM2500 optical microscope and MICROMET 5104 Vickers hardness tester. The results reveal that the cold-drawn 0Cr13 stainless steel wire is recrystallized after heating at 750-830 ℃ for 2 min, and the recrystallization is completed after heating at 845-880 ℃ for 1 min. So with the increase of holding temperature, the recrystallization time shortens gradually. But the martensite is prone to form during the air cooling when holding at up to 920 ℃, and the content of martensite is increased with the increase of heating temperature. The optimum heat treatment process is holding for 1 min at 845-880 ℃, and the hardness of the tested material is about 130-140 HV0.1 when the crystallization is finished.
    MICROSTRUCTURE AND PROPERTIES
    Low temperature toughness of acicular ferrite pipeline steel and redefinition of “effective grain size”
    Niu Yanlong, Liu Yansong, Liu Qingyou, Jia Shujun, Tong Shuai, Wang Bing
    2020, 45(7):  101-110.  doi:10.13251/j.issn.0254-6051.2020.07.022
    Abstract ( 64 )   PDF (695KB) ( 38 )  
    Toughness of the tested steel was investigated by series temperature charpy impact test and drop-weight tear test (DWTT),themisorientation angles of the grain boundaries of various microstructures along the cleavage crack propagation direction were statistized, and the angles between{100} cleavage planes on the cleavage crack propagation path were calculated in five rolling directions (0°, 30°, 45°, 60° and 90°).The effective grain size defined as grain with misorientation angle greater than 15° for high grade acicular ferritic pipeline steel was redefined as the size of cleavage units consisting of grains with {100}cleavage plane less than 35° between grain boundaries, and the quantitative influence of the redefined “effective grain size” on the low temperature toughness properties from Charpy impact test and DWTT were synthetically analyzed. The results show that the microstructure presents a typical acicular ferrite (AF) characteristic with somepolygonal ferrite (QF) and M-A islands, the distribution of high angel grain boundaries mainly distributes in the range of 45°-65° in different directions. The impact absorbed energy(ASTM A370-2017)and percent shear area of DWTT in the five directions increase with the refinement of the above redefined “effective grain size”, the ductile-brittle transition temperature also decreases with the refining of redefined “effective grain size”. The redefined effective grain boundaries can strongly hinder the fracture propagation, and thus the redefined “effective grain” can act as the effective microstructure unit for cleavage.
    Microstructure and mechanical properties of rapidly solidified Cu-5Ag-0.5Zr-0.4Cr-0.35Nb alloy
    Lü Guoliang, Feng Yan, Wang Richu, Peng Chaoqun, Wu Xiang
    2020, 45(7):  111-118.  doi:10.13251/j.issn.0254-6051.2020.07.023
    Abstract ( 59 )   PDF (615KB) ( 24 )  
    Rapidly solidified Cu-5Ag-0.5Zr and Cu-5Ag-0.5Zr-0.4Cr-0.35Nb (wt%) powders were compacted by hot sostatic pressing (HIP) and followed by hot forging and cold rolling.The mechanical properties of the alloy at room temperature and high temperature (500 ℃) were tested, and the microstructure and fracture morphology of the alloy were analyzed. The results show that cold rolled alloy has better room temperature tensile properties, and the ultimate tensile strength and elongation at room temperature of cold rolled Cu-Ag-Zr alloy are 739.3 MPa and 7.1%, respectively, which is related to the dense Cu4AgZr and nano-sized Ag particles in Cu matrix. Apart from Cu4AgZr and Ag particles, the addition of Cr and Nb elements generates high temperature stable Cr2Nb particles, which enhances the tensile strength of the alloy at both room temperature and 500 ℃. The ultimate tensile strength and elongation at room temperature of cold rolled Cu-Ag-Zr-Cr-Nb alloy are 799.1 MPa and 5.3%, respectively. The hot forged alloy has a better weakening resistance at high temperature than that of cold rolled alloy due to larger grain size and finer Ag particles.The hot forged Cu-Ag-Zr-Cr-Nb and Cu-Ag-Zr alloys have a tensile strength of 186.8 MPa and 129.2 MPa at 500 ℃, respectively, while the tensile strength of cold rolled Cu-Ag-Zr-Cr-Nb and Cu-Ag-Zr alloys at 500 ℃ is only 113.1 MPa and 95.4 MPa, respectively.
    Effect of high temperature holding time on microstructure and properties of coarse-grained zone of welded joint of X80 pipeline steel
    Ge Jialin, Zhang Xiaoyong, Ji Lingkang, Li Weiwei, He Xiaodong, Chen Qinglong, Yu Chenyang
    2020, 45(7):  119-123.  doi:10.13251/j.issn.0254-6051.2020.07.024
    Abstract ( 56 )   PDF (615KB) ( 30 )  
    Effect of high temperature holding time on microstructure and properties of X80 pipeline steel in the CGHAZ was studied by means of Gleeble-3500 thermal simulator, microstructure analysis, mechanical test and SEM. The results show that the coarse-grained zone of X80 pipeline steel is mainly composed of granular bainite, bainite ferrite and M/A component.With the increase of high temperature holding time, the diffusion rate of carbon and nitrogen atoms increases, the composition is tended to be more uniform, the cross distribution of granular bainite and bainite ferrite increases, the distribution of M/A island structure and carbon nitrogen compounds is more dispersed, and the toughness value of coarse-grained zone is also increased gradually.When the high temperature holding time is 18 s, the impact toughness of the coarse grain zone is the best, the impact absorbed energy of -10 ℃ is 288 J, and the moderate hardness value is 270 HV0.3. When the high temperature holding time is beyond 18 s, the impact absorbed energy of the coarse-grained zone decreases and the hardness value increases. When the high temperature holding time is 8 s, the impact toughness of coarse-grained zone is the lowest, the impact absorbed energy is only 49 J, the hardness value is the highest, is 283 HV0.3.
    Microstructure and properties of connecting rods made of medium carbon non-quenched and tempered forging steel 43MnS with different sulfide morphologies
    Chen Zhen, Hui Weijun, Wang Zhanhua, Zhang Nian, Zheng Wenchao
    2020, 45(7):  124-129.  doi:10.13251/j.issn.0254-6051.2020.07.025
    Abstract ( 59 )   PDF (614KB) ( 28 )  
    Sulfide morphologies, microstructural characteristics and mechanical properties of different parts of connecting rods made of commercial medium carbon non-quenched and tempered steel 43MnS with sulfide-modification (No.1) and without sulfide-modification (No.2) were studied by using optical microscopy, scanning electron microscopy, tensile testing machine and hardness tester. The results show that the sulfides in No.1 steel connecting rod are distributed relatively uniform and most sulfides exhibit a spindle shape, which are slightly elongated during forging deformation process and have an average aspect ratio (the ratio of length to width of sulfide) of 3.5-3.9. The sulfides in No.2 steel connecting rod are elongated and partially fractured during forging, thus poorly distributed and exhibit a highly elongated shape with a average aspect ratio of 5.5-7.0. The strength and hardness of No.1 steel connecting rod are higher than that of No.2. The fracture mechanism of both kinds of specimens is plastic fracture of dimples, and sulfide inclusions often exist at the bottom of large size dimples. Mainly caused by the forging deformation difference and the cooling rate difference at different parts of the connecting rod, according to the order of the big-end, small-end and shank of the connecting rod, the microstructure is gradually refined, and the content and hardness of both the ferrite and intragranular ferrite are gradually increased.
    Effect of crack tip plastic zone on pulse current crack arresting of 304 stainless steel
    Zhang Zhuwu, Pan Guangguo, Jiang Yan, Xu Chengwei
    2020, 45(7):  130-134.  doi:10.13251/j.issn.0254-6051.2020.07.026
    Abstract ( 58 )   PDF (616KB) ( 24 )  
    Microstructure observation and nano-indentation test were carried out on crack arresting specimens of 304 stainless steel with and without plastic zone near the crack tip. The results show that phase transformation and recrystallization are found to occur at the crack tip of 304 stainless steel with plastic zone after pulse current arrest, and the solidification zone, fine grain zone and deformation-induced martensite zone are formed under the co-action of the temperature field and the stress field. However, the solidification zone is only occurred in the specimen without the plastic zone. The nano-indentation test shows that the fatigue crack tip of 304 stainless steel has large residual stress, which decays rapidly with the increment of the distance from the crack tip. After pulse current crack arrest, the formation of deformation-induced martensite leads to the increase of both the volume expansion and the compressive stress around the arrest crack, which is beneficial to suppress the crack propagation.
    Effect of sintering temperature on microstructure and biological activity of Sr-HA/Ti composites
    Li Gang, Wang Ying, Tian Zongwei, Meng Chao
    2020, 45(7):  135-138.  doi:10.13251/j.issn.0254-6051.2020.07.027
    Abstract ( 57 )   PDF (623KB) ( 26 )  
    Strontium-doped hydroxyapatite (Sr-HA) powders were prepared by sol-gel method. The Sr-HA powders and Ti powders were compacted into compacts at a mass ratio of 2∶8, then prepared into Sr-HA/Ti biocomposites by sintering under atmospheric environment, and the effect of sintering temperature on the structure and biological activity of the Sr-HA/Ti biocomposites was studied. The results show that: the Sr-HA/Ti composites after sintering are mainly composed of Sr-HA, Ti, TiO2 and CaO phases. When the sintering temperature reaches 950 ℃, the surface oxidation of the composites is serious and the decomposition of Sr-HA phase increases. The pore size of Sr-HA/Ti composites sintered under atmospheric conditions can meet the basic requirement of bone tissue growth, and the metallurgical bonding of the composites after sintering is good. With the increase of sintering temperature, the number of pores on the surface of the composites increases, the pore diameter decreases, and the fine pores are evenly distributed between the titanium dioxide and α-Ti grid structure. After immersiing in simulated body fluids for 14 days, the ceramic phases depositing on the surface of the sample sintered at 850 ℃ are the best, and the Ca5(PO4)3-x(CO3) xOH phase beneficial to osteogenesis is formed on the surface of the composites.
    MATERIALS RESEARCH
    Preparation of graphene nanowalls on tungsten and single crystal silicon plate by thermal treatment of carbon plasma
    Cheng Yifei, Luo Fei, Liu Dabo, Zhou Haitao, Tian Ye, Hu Chunwen, Luo Bingwei
    2020, 45(7):  139-142.  doi:10.13251/j.issn.0254-6051.2020.07.028
    Abstract ( 64 )   PDF (615KB) ( 27 )  
    The graphene nanowalls were prepared directly on the surface of W metal and monocrystalline Si substrate by plasma thermal treatment. The microstructure and components of the samples were characterized by means of XRD, SEM and Raman spectroscopy, and the surface hardness were tested by using micro vickers hardness tester. The results show that the composite layers deposited on the surface of W and Si substrates are consisting of W2C-WC/graphene and SiC/graphene, respectively, which distribute uniformly. Based on the layer of W2C-WC/graphene, the surface hardness of metal W is 502.95 HV0.01, which increases by 52.54 HV0.01 and 11.6% compared with the pure metal W of 450.41 HV0.01. Based on the layer of SiC/graphene composite layer, the surface hardness of SiC/ graphene is 836.76 HV0.025, which increases by 24.02 HV0.025 and 2.95% compared with that of single crystal Si substrate of 812.74 HV0.025.
    Simulation study of precipitate phases and variation of strength and toughness of Co-containing stainless steel
    Chen Wanwan, Zou Dening, Li Jiao, Zhang Yingbo, Li Yunong
    2020, 45(7):  143-147.  doi:10.13251/j.issn.0254-6051.2020.07.029
    Abstract ( 63 )   PDF (623KB) ( 37 )  
    Influence of Co addition on the microstructure and mechanical properties of maraging stainless steel was studied by using numerical simulation, microstructure characterization and performance test. According to the thermodynamic and kinetic calculation with Thermo-Calc software, the results show that with addition of 6wt%Co,the precipitation temperature of ε-Cu phase rises and the incubation time becomes longer, and under the same aging condition the average radius of ε-Cu precipitates decreases. The optical microscopy (OM) and transmission electron microscopy (TEM) analysis results show that for the Co-containing tested steel after solution treatment and aging, the ultra-low carbon lath martensite is refined obviously, the dispersed ε-Cu phase size becomes smaller and the precipitation amount increases gradually, and the film-like inverted austenite increases in amount and in size. Owing to the dislocation strengthening of lath martensite, the precipitation strengthening of ε-Cu phase and the toughening effect of the inverted austenite phase, the strength, hardness, elongation and impact absorbed energy of the tested Co-containing steel reach 1350 MPa, 433 HV0.5, 16% and 75 J, respectively.
    Effect of La content on oxidation resistance of Fe-based corrosion resistant alloy
    Li Dongsheng, Chai Dengpeng, Hou Guanghui, Li Zhiyuan, Liu Ying, Liu Dan
    2020, 45(7):  148-152.  doi:10.13251/j.issn.0254-6051.2020.07.030
    Abstract ( 66 )   PDF (614KB) ( 29 )  
    Oxidation resistance of Fe-base corrosion resistant alloys with different La content at 850 ℃ was studied by using XRD, SEM and EDS techniques. The results show that at 850 ℃, with the increase of La content, the anti-oxidation property of the alloy is reduced to a certain extent, but the adhesion of the oxide film to the matrix is greatly improved. The oxide film can be fixed on the alloy matrix tightly with the increase of La content by promoting the internal diffusion of oxygen and make the inner oxide layer become dendritic and go deep into the alloy matrix. The oxide film is mainly composed of three layers: the outer layer is the mixed layer of Fe2O3 and CuO, and contains a small amount of NiFe2O4; the middle layer is a protective layer dominated by NiFe2O4, and contains a small amount of Fe2O3 and NiO; the inner layer is an inner oxidation zone dominated by Fe2O3 and contains a small amount of NiO oxide.
    Forming process and three-body wear properties of in-situ synthesized (Ti,W)C reinforced high chromium cast iron composite
    Wei Dan, Luo Tiegang, Zheng Zhibin, Zheng Kaihong, Wang Juan, Long Jun
    2020, 45(7):  153-158.  doi:10.13251/j.issn.0254-6051.2020.07.031
    Abstract ( 58 )   PDF (619KB) ( 35 )  
    (Ti,W)C particle reinforced high chromium cast iron composite was prepared by in-situ synthesis and casting method. XRD, EDS, SEM and other detection methods were used to study the reaction process and three-body wear resistance of the composite. The results show that there is a reaction-melting-precipitation mechanism and a reaction-solid solution mechanism in the reaction process of the reinforcing phase (Ti,W)C particles. The interface between the (Ti,W)C particles and the matrix is metallurgical bonding. The wear resistance of the composite is 1.4 times that of the high chromium cast iron, and the wear mechanism is abrasive wear-adhesive wear.
    Effect of In on structure and electrochemical properties of Al-Mg-Ga-Sn-(In) aluminum alloy anodes
    Zhu Lingli, Li Yun, Liu Hui, Lü Zhengfeng,Yu Kun
    2020, 45(7):  159-162.  doi:10.13251/j.issn.0254-6051.2020.07.032
    Abstract ( 66 )   PDF (615KB) ( 29 )  
    Nine aluminum-air battery anode materials were designed by adding alloy elements Mg, Ga, Sn and In into Al through orthogonal test. The electrochemical properties of aluminum alloy anodes were optimized by means of the potentiodynamic polarization test, hydrogen evolution test and constant current discharge test, the microstructure and components of aluminum alloy anode were observed by SEM and EDS. The results show that the aluminum alloy anodes without In element including No.1 alloy (Al-0.5Mg-0.05Sn-0.05Ga), No.5 alloy (Al-Mg-0.1Sn-0.2Ga) and No.9 alloy (Al-2Mg-0.2Sn-0.1Ga) have poor discharge performance and higher self-corrosion rate, while No.7 anode alloy (Al-2Mg-0.05Sn-0.2Ga-0.05In) has the best discharge voltage (average voltage to -1.968 V) and corrosion resistance (self-corrosion rate to 0.193 mL·cm-2·min-1). After removing the corrosion products, it is found that the corrosion surface of No.5 alloy is full of deep corrosion pits which increases the self-corrosion, while the corrosion surface of No.7 alloy has shallow corrosion pits, which slows down the ion transfer in the electrolyte and the self-corrosion rate. Therefore, No.7 aluminum alloy is suitable for the anodic material of aluminum-air battery.
    Effect of Cr content on hardenability of 65Mn steel
    Sun Yiqiang
    2020, 45(7):  163-166.  doi:10.13251/j.issn.0254-6051.2020.07.033
    Abstract ( 77 )   PDF (617KB) ( 43 )  
    To study the effect of Cr on the hardenability of 65 Mn steel, the end quenching test of four groups of specimens with Cr content of between 0%-0.5%(mass fraction) was carried out. The hardness and microstructure of the quenched specimens were tested. The results show that with the decrease of cooling rate, the martensite content in the quenched specimens is reduced from 100% to 0%, and the hardness is reduced from 62 HRC to 23 HRC. The Cr content significantly improves the hardenability of 65Mn steel, and the 0.1% Cr can improve about 50% of the hardened zone depth.
    Fatigue performance and crack initiation of 16Cr3NiWMoVNbE gear steel
    Li Jianxin, Luo Zhiqiang, Cheng Shichao, Yang Maosheng, Sun Yong, Pang Xuedong
    2020, 45(7):  167-172.  doi:10.13251/j.issn.0254-6051.2020.07.034
    Abstract ( 103 )   PDF (624KB) ( 39 )  
    Gear steel 16Cr3NiWMoVNbE was prepared by VIM+VAR process. The fatigue limit and S-N curve of the test steel were measured. The fatigue crack initiation type and influencing factors were analyzed by observing the fracture. The results show that the ultimate fatigue strength is 773 MPa, and the fatigue cracks originate from resident slip bands, surface defects, near-surface inclusions, and sub-surface inclusions. Initiated fatigue cracks on the surface resident slip band account for 13%, initiation cracks on surface defects account for 33.3%, initiation of near-surface inclusions accounts for 40%, and initiation of sub-surface inclusions accounts for 13%. When fatigue cracks originate from internal inclusions, the fatigue life decreases with increasing stress; under certain actual stresses, the fatigue life decreases with increasing inclusion size. With the increase of actual stress, the critical size of the inclusions induced by fatigue cracks decreases.
    Microstructure and mechanical properties of extrusion state Al-Zn-Mg-Cu alloy after spray forming
    Pan Haicheng, Chen Yegao, Sun Xiaoxia, Fan Jun
    2020, 45(7):  173-176.  doi:10.13251/j.issn.0254-6051.2020.07.035
    Abstract ( 50 )   PDF (626KB) ( 24 )  
    Optimized microstructure characteristics and the mechanical properties of the Al-5.72Zn-2.36Mg-1.66Cu aluminium alloy prepared by spray forming and continuous extrusion were studied. The results show that the microstructure of the alloy matrix is uniformly refined and the morphology of the grains tends to be rounded. And the average grain size of the alloy is about 10 μm. The different effects of the solid solution strengthening and second-phase dispersion strengthening will be generated when the cooling condition of the alloy is changed by the rapid solidification. Thus,the overall properties of the alloy are also improved by spraying. The yield strength and tensile strength of the alloy are increased by about 20% on average, and the elongation is increased slightly.
    SURFACE ENGINEERING
    Microstructure of VC layer prepared by TD salt-bath vanadizing on 40Cr steel surface
    Lei Fengrong, Li Hui
    2020, 45(7):  177-182.  doi:10.13251/j.issn.0254-6051.2020.07.036
    Abstract ( 63 )   PDF (620KB) ( 28 )  
    In order to prolong the service life of gear steel, 40Cr steel was selected as substrate material to prepare the VC (vanadium carbide) vanadizing layer by TD (thermal diffusion) salt-bath vanadizing. The thickness of the VC layers formed by vanadizing in salt-bath at 900-1050 ℃ for 6 h was measured, and the microstructure, phases and hardness of the VC vanadizing layers were analyzed by metallographic microscope, scanning electron microscope, X-ray diffraction and Vickers indenter. The results show that the thickness of the VC layers on 40Cr surface is 5-50 μm, and the treatment temperature difference causes migration of the vanadizing layer microstructure in different degrees. The vanadizing layers are mainly composed of VC phase and a small amount of α-Fe phase, and the VC grain growth has two preferential orientations of VC(111) and VC(200). The preferential orientations are weakened with the increase of treatment temperature, and the surface hardness of the substrate is improved in different degrees by the vanadizing layers.
    Effect of aluminum content on microstructure and properties of   hot-dip galvanizing coating on IF steel
    Gong Li, Jia Juan, Xiong Wei, Cheng Zhaoyang, Bi Yunjie
    2020, 45(7):  183-188.  doi:10.13251/j.issn.0254-6051.2020.07.037
    Abstract ( 58 )   PDF (618KB) ( 26 )  
    Hot dip galvanizing coatings were prepared on IF steel by adding 0.2%, 1.0% and 5.0%Al (mass fraction) to the hot dip galvanizing bath, and the microstructure of the coatings was observed with the help of stereomicroscope and SEM. The three-point bending test was carried out by universal testing machine to study the effect of different Al contents on the microstructure and properties of the hot-dip galvanized coatings. The results show that the surface of the hot-dip galvanized coatings is flat but with reticular grooves, where are α(Al)+η(Zn) and Fe-Al-Zn intermetallic compounds. With the increase of aluminum content, the tortoise shell on the surface of the coatings gradually becomes smaller, and the thickness of the coatings gradually increases. Due to the high hardness and brittleness, the crack originates from the intermetallic compounds during bending. With the increase of Al content, the cracks gradually increase and arrange in parallel.
    Microstructure and properties of laser clad titanium-based   cermet composite coating
    Tan Jinhua, Sun Ronglu, Niu Wei, Liu Yanan, Hao Wenjun
    2020, 45(7):  189-193.  doi:10.13251/j.issn.0254-6051.2020.07.038
    Abstract ( 67 )   PDF (618KB) ( 36 )  
    In order to improve the wear-resistance and anti-friction properties of TC4 alloy, a titanium-based composite coating was prepared on the TC4 alloy surface by laser cladding technique with TC4+h-BN mixed powder. The macroscopic morphology and microstructure of the clad layer were studied by using XRD, SEM, EDS, etc., and the hardness of the clad layer, heat affected zone and matrix was tested by microhardness tester. The friction coefficient and the wear mass loss of the clad layer and matrix were respectively determined by friction and wear tester and electronic precision balance. The results show that the clad layer is mainly composed of rod phase TiB, Ti-B-N ternary eutectic structure and substrate α-Ti. The hardness of the clad layer is between 1000 HV0.5 and 1200 HV0.5. The wear mechanism of the clad layer and the TC4 matrix is slight abrasive wear and severe abrasive wear, respectively. The friction coefficient and the wear mass loss of the clad layer are reduced by 0.04 and by 7 mg from that of the substrate, thus the wear resistance and friction reduction performance of the clad layer are improved compared with the substrate.
    Optimization of alternating current field enhanced pack boron-aluminizing boriding-based
    Cai Shoulu, Xie Fei, Pan Jianwei, Zou Weidong
    2020, 45(7):  194-197.  doi:10.13251/j.issn.0254-6051.2020.07.039
    Abstract ( 55 )   PDF (619KB) ( 26 )  
    Alternating current field enhanced pack boron-aluminizing (ACFPBA)in which the inward diffusion of boron dominated was carried out at 750 ℃ with different pack agent. By observing and analyzing the case microstructure, phase, thickness and microhardness distribution along the depth of cases, it is found that the aluminium powder in the agent can promote the ACFPBA. The promotion extent is related not only with the Al content in the agent, but also with the ferroboron content. When the optimum aluminium powder content is employed, the promotion effect with agent containing lower ferroboron content is better than that with agent containing higher ferroboron content. An ACF enhanced boriding case with Fe2B single-phase is obtained with agent containing lower ferroboron content. However, adding more than 0.5% aluminium powder to the agent, the obtained case is composed of duplex-phase of FeB and Fe2B. And the hardness of the near surface region is increased. When other treating parameters are the same, adding 1% aluminium powder into the agent containing 6% ferroboron leads to an about 70 μm thick case after 4 h ACFPBA and the case's hardness curve distributes more gently. However, the case thickness by corresponding ACF enhanced boriding is only about 26 μm.
    TEST AND ANALYSIS
    Effect of ion milling on retained austenite content and stability in TRIP780 steel
    Cui Guibin, Ju Xinhua, Meng Yang, Yang Rui
    2020, 45(7):  198-201.  doi:10.13251/j.issn.0254-6051.2020.07.040
    Abstract ( 55 )   PDF (616KB) ( 24 )  
    Effect of ion milling on the content and stability of retained austenite in TRIP780 steel was investigated. Firstly, TRIP780 steel specimens were prepared by electropolishing to remove the stress layer on their surface, then ion milled and the retained austenite in the specimens was examined by field emission scanning electron microscope. The retained austenite content in the TRIP780 steel before and after ion milling was further analyzed qualitatively and quantitatively by electron backscatter diffraction (EBSD).The results show that, compared with electropolishing, the ion milling can also remove the stress layer on the specimen surface, however, the retained austenite content in the TRIP780 steel specimen after ion milling is greatly reduced from the original 10.1% to 0.02%, and the Kikuchi pattern of the retained austenite after ion milling is obviously worse or even blurred. The retained austenite content in the ion-milled TRIP780 steel decreases significantly, and the phase structure changes from the original face-centered cubic to the body-centered cubic (fcc→bcc), thus indicating the retained austenite is extremely unstable after ion bombardment and is prone to phase transformation, which is also verified in the quasi-in-situ experiment of retained austenite. The ion milling induces lattice distortion, resulting in a significant decrease in the clarity and resolution of the Kikuchi pattern.
    Fracture failure analysis of 3Cr13 steel diesel cycle pump spindle
    Zou Longjiang, Qi Lin, Shi Shuyan, Liu Shutan
    2020, 45(7):  202-205.  doi:10.13251/j.issn.0254-6051.2020.07.041
    Abstract ( 72 )   PDF (567KB) ( 29 )  
    Fracture reason of the main shaft of diesel circulating pump of the 3Cr13 steel was analyzed by means of X-ray fluorescence spectrometer, metallographic microscope, brinell hardness tester, tensile testing machine, impact testing machine and scanning electron microscope etc. The results show that the chemical composition, hardness and mechanical properties of the 3Cr13 steel meet the technical requirements, and the impact energy is seriously low. Granular reticular carbide in the microstructure increases the brittleness of the material. The stress concentration is easily formed because of the lack of proper transition fillet at the right-angle transition of shaft diameter change step. The type of fracture belongs to fatigue fracture, and the stress concentration caused by the machining defects in the right-angle transition at the step where the shaft diameter changes is the main reason for the rapid fatigue fracture.
    Structure-defect analysis of crack failure in 42CrMo wind power spindle
    Yuan Jingzhi, Shi Yuezhi, Xu Wenhua, Chen Lubin, Lü Yupeng
    2020, 45(7):  206-209.  doi:10.13251/j.issn.0254-6051.2020.07.042
    Abstract ( 60 )   PDF (564KB) ( 40 )  
    Microstructure and composition of the cracked 42CrMo steel wind turbine spindle were analyzed by means of optical microscope, SEM and EPMA. The results show that there are a large number of sulfide and nitride inclusions near the cracks of the main shaft, and there is an obvious gap between the inclusions and the matrix, which is easy to produce cracks by the mechanism of interface debonding and cracking. At the same time, the micro area component segregation at the inclusion and the shrinkage defects near the cracks work together to eventually lead to the cracks of the main shaft.
    Cause analysis and prevention of oil drill pipe puncture failure
    Li Shumei, Zhang Weidong, Li Guibian, Ma Xinhua, Liu Guitong, Gao Suheng, Bao Yuguang
    2020, 45(7):  210-213.  doi:10.13251/j.issn.0254-6051.2020.07.043
    Abstract ( 57 )   PDF (565KB) ( 30 )  
    Early perforation failure of a drill pipe occurred in the process of using in the oil field. The macroscopic morphology, chemical composition, microstructure, mechanical properties and hardness of the failed drill pipe were analyzed by physical and chemical testing technology. The results show that under the action of corrosive medium in the process of drilling, a corrosion pit forms at the pricking point of inner wall of the drill pipe. Under the action of complex alternating stress load, microcracks form at the bottom of the corrosion pit on the surface of the drill pipe and propagates rapidly, resulting in the corrosion fatigue failure of the drill pipe. In order to prevent this kind of failure, it is necessary to strictly control the steel pipe rolling process, select the appropriate rolling tool size, improve the surface quality of the inner and outer walls of the steel pipe, and avoid the corrosion fatigue failure of the drill pipe used in the oil field.
    Cause analysis of unqualified hardness of 14Cr17Ni2 stainless steel blade
    Li Li, Zhang Quanxin, Zhu Bin
    2020, 45(7):  214-218.  doi:10.13251/j.issn.0254-6051.2020.07.044
    Abstract ( 96 )   PDF (566KB) ( 31 )  
    Rods and blades of 14Cr17Ni2 stainless steel were investigated by direct reading spectrometer, optical microscope and hardness tester. Meanwhile, their chemical compositions, high magnification observation of microstructure, hardness were analyzed after different heat treatments. the reasons for unqualified hardness were discussed in combination with the manufacturing process of the blade, and the improvement measures were thus proposed. The results show that the high temperature in the process of hot working and heat treatment for steel rods leads to the increase of the content of ferrite in blades, which is the direct cause of the unqualified hardness of blades after heat treatment. By adjusting the composition of steel, properly increasing the value of nickel equivalent, and reasonably controlling the hot working and heat treatment process of the steel billets and blades, the required hardness of the blades is realized.
    Analysis on quenching cracks of SA-387Gr.91 steel spherical head
    Yang Hongquan, Xu Xiangjiu, Zhou Jingcao
    2020, 45(7):  219-223.  doi:10.13251/j.issn.0254-6051.2020.07.045
    Abstract ( 65 )   PDF (562KB) ( 24 )  
    A large number of cracks were found on the inner surface of SA-387Gr.91 steel spherical head after quenching and tempering processes which were used for improving the hardness. The chemical composition, microstructure, hardness and fracture appearance of the cracks and the nearby base metal were detected and analyzed. The results show that the cracks are quenching ones, and they are not related to the chemical composition and the metallurgical quality of the base metal. The prior austenite grain size of the base metal is too large and the microhardness is above standard value. It is revealed the by the experimental results that the cracks are mainly caused by coarse grains resulted from too high hot stamping temperature and the high cooling rate resulted from inappropriate quench medium. By lowering the hot stamping temperature, changing water cooling to forced air cooling and lowering the tempering temperature, no quenching cracks ever appear in the spherical head, and the surface hardness meet the expected requirements.
    Failure cause analysis of crankshaft blank in cold straightening process
    Cong Jianchen, Yu Xiaodong, Ma Mingzhu, Wu Yongchen, Zhang Huadong
    2020, 45(7):  224-227.  doi:10.13251/j.issn.0254-6051.2020.07.046
    Abstract ( 68 )   PDF (562KB) ( 30 )  
    A 45 steel crankshaft blank fractured in the cold straightening process to eliminate the slight deformation after forging.The spectrometer, Brinell hardness tester, metallographic microscope, tensile testing machine, scanning electron microscope and so forth were used to analyze the chemical composition, mechanical properties, microstructure, and fracture morphology characteristics of the fractured blank. The results show that the matrix structure near the fracture is coarse, and the Widmannstatten microstructure appears; the mechanical properties such as plasticity and impact toughness are low, which indicates the microstructure is overheated. This is the direct cause of brittle fracture of the forged billet. By adjusting the induction heating parameters in pre-forging process, the post-forging controlled cooling process and the normalizing process, the overheating structure is eliminated.
    Aging problem and counter method for 1Cr25Ni20Si2 steel nitriding tank
    Zhu Ruifang, Mi Xiujuan
    2020, 45(7):  228-230.  doi:10.13251/j.issn.0254-6051.2020.07.047
    Abstract ( 56 )   PDF (565KB) ( 27 )  
    When 1Cr25Ni20Si2 steel nitriding tank was used as a retort in a gas nitriding furnace, the aging phenomenon would occur with the increase of the nitriding time, resulting in that the nitriding of workpiece could not be carried out. Though many different methods were used to solve the aging problem, they were not effective enough, but it was found that high temperature tempering in the failed nitriding furnace could effectively denitrify and solve the aging problem of retort.
    NUMERICAL SIMULATION
    Numerical simulation on distortion behavior of large diameter ratio thin-walled shell during high pressure gas quenching
    Zhang Xiaojuan, Zhang Jian, Ni Linyu, Zhou Zhongping, Zhang Jun, Li Junwan, Min Yongan
    2020, 45(7):  231-237.  doi:10.13251/j.issn.0254-6051.2020.07.048
    Abstract ( 188 )   PDF (565KB) ( 153 )  
    A theoretical framework of metal-thermal-force coupled model of the large diameter ratio thin-walled shell was established,which is made of 30Cr3SiNiMoVA steel. The heat transfer coefficient curve at different positions was calculated through inverse heat transfer method. The distortion behavior was investigated though analyzing the evolution of the temperature field and the structure field during high pressure gas quenching process. The results show that the cooling speed on the same heat exchange surface of the shell is thin-walled position greater than top than step in the middle, and the temperature in the positive side changes more sharply. There are two peak values of the stress curves, the first one is due to the heat stress induced by the temperature, and the second one is due to the structure stress induced by the martensitic transformation. After quenching, the height of the positive side and negative side are increased by 2.08 mm (0.082%) and 2.33 mm (0.092%) respectively, and the outer diameter at the thin wall position and step in the middle are increased by 0.81 mm (0.270%) and 0.57 mm (0.186%), respectively. The measured results are basically in agreement with the simulation, and the error is less than 10%.
    Numerical simulation of temperature field in vacuum annealing treatment of Zr-4 alloy sheet
    Zhang Hongzhi, Yang Pan, Guo Dongxu, Wu Yu, Zhao Yong, Qiang Rui, Tan Xiaolian
    2020, 45(7):  238-242.  doi:10.13251/j.issn.0254-6051.2020.07.049
    Abstract ( 75 )   PDF (562KB) ( 50 )  
    Heat transfer mode of Zr-4 alloy sheet during vacuum annealing is analyzed, and the radial heat transfer coefficient of Zr-4 alloy sheet is calculated. The temperature field of Zr-4 alloy sheet during annealing was simulated by using ABAQUS, and the influence of fixture on annealing of Zr-4 alloy sheet was analyzed. The numerical simulation results were verified by experimental measurement. The results show that the fixture can improve the uniformity of temperature distribution of zirconium alloy sheet, and the numerical simulation results are in good agreement with the measured results.