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  • OVERVIEW
    Research progress on high-energy electropulsing treatment of high-performance metallic materials
    Lu Yanna, Long Jiahui, Jiang Yanbin, Liu Xinhua
    2021, 46(10):  1-11.  doi:10.13251/j.issn.0254-6051.2021.10.001
    Abstract ( 79 )   PDF (631KB) ( 54 )  
    Electropulsing treatment (EPT) is a novel heat treatment with periodic non-equilibrium high-energy input. Effect of EPT on recrystallization, phase transformation and amorphous crystallization of metallic materials was introduced. From the viewpoint of material thermodynamics and dynamics, the roles of electropulsing in reducing thermodynamic energy barrier and accelerating atomic diffusion were elaborated, and mechanisms of recrystallization, phase transformation and amorphous nanocrystallization induced by electropulsing were also revealed, which was conducive to optimize microstructure and improve properties. EPT has a broad application prospect in producing industry of high-performance metallic materials.
    MATERIALS RESEARCH
    Transformation kinetics of 0Cr16Ni5Mo1 martensitic stainless steel during continuous cooling
    Song Yisi, Li Chuanwei, Chen Yihua, Li Ke, Hu Haipeng, Gu Jianfeng
    2021, 46(10):  12-17.  doi:10.13251/j.issn.0254-6051.2021.10.002
    Abstract ( 58 )   PDF (561KB) ( 41 )  
    Based on the dilatometric curves and combined with microstructure characterization and hardness test, the continuous cooling transformation kinetics and microstructure evoluation of the 0Cr16Ni5Mo1 martensitic stainless steel was investigated. The results show that after austenitizing at 1100 ℃ for 60 min, only the martensitic transformation occurs when cooled at 0.5-100 ℃/s, the Ms and Mf temperature are about 212 ℃ and 25.3 ℃ respectively, the microstructure is lath martensite, and the hardness is about 371 HV, which means the cooling rate has no obvious effect on them. The Koistinen-Marburger equation can be used to describe the martensitic transformation, and the transformation kinetic parameter α is about 0.0317.
    Microstructure and texture evolution, properties of 3.4%Si non-oriented silicon steel strip produced by twin-roll strip casting
    Wang Zhilei, Che Shangfeng, Hou Diwen, Fang Feng, Zhang Yuanxiang, Wang Yang, Zhang Xiaoming
    2021, 46(10):  18-25.  doi:10.13251/j.issn.0254-6051.2021.10.003
    Abstract ( 63 )   PDF (563KB) ( 29 )  
    Based on twin-roll strip casting (TSC) technology, 0.35 mm and 0.20 mm high-grade non-oriented silicon steel strips were prepared by single-stage cold rolling and two-stage cold rolling, respectively. Microstructure and texture evolution of non-oriented silicon steel along preparation process were analyzed by means of EBSD, XRD and other detection methods. The results show that the as-cast strip prepared by TSC is mainly composed of coarse columnar crystals and has a strong λ-fiber texture with intensity of 4.76 and without γ-texture. After normalization, some equiaxed grains grow up, and the texture types does not change significantly. The texture of one-stage cold-rolled sheet mainly consisted of α-texture, and the recrystallization texture are mainly consisted of uniform γ-texture and λ-texture concentrated on {001}<120> with intensity of 5.41. The two-stage cold-rolled sheet is mainly composed of λ-texture and γ-texture with high density of shear bands. After recrystallization annealing, the microstructure is relatively coarse, and strong Cube texture is formed with intensity of 6.45. Due to the inheritance of initial favorable texture, the tested steel exhibites high magnetic induction and relatively high strength, and the iron loss value reaches the level of the conventional process. The B50 reaches 1.77 T and P1.0/400 is 20.78 W/kg in 0.35 mm annealed sheet. And the B50 is 1.70 T, P1.0/400 is 13.74 W/kg, which shows obvious advantage of low iron loss under high-frequency in 0.20 mm annealed sheet. The yield strength and the elongation of the two types of non-oriented silicon steel exceed 415 MPa and 15%, respectively.
    Effect of cold rolling and aging process on σ phase precipitation of 2205 duplex stainless steel
    Yuan Aoming, Li Jingkun, Gao Xiaodan, Ren Xueping
    2021, 46(10):  26-30.  doi:10.13251/j.issn.0254-6051.2021.10.004
    Abstract ( 110 )   PDF (556KB) ( 26 )  
    The 2205 duplex stainless steel after solution treatment at 1050 ℃ was treated by aging at 650-1000 ℃. The σ phase precipitation rule under different process conditions was observed by means of OM and SEM. TTP curves of σ phase precipitation were obtained to characterize the precipitation of σ phase. The results show that in the early stage of aging, the σ phase preferentially nucleates at the phase boundary of the two phases of austenite and ferrite. With the increase of aging temperature and the aging time, the σ phase grows, coarsens and extends to the ferrite matrix. The longer the aging time, the more precipitation phases. When the aging time is the same and the temperature reaches 850 ℃, the amount of precipitation reaches the maximum and then decreases with the increase of temperature. The precipitation temperature range of σ phase is 650-950 ℃, and the knee temperature is about 850 ℃. The increase in rolling deformation speeds up the precipitation of σ phase, but it does not affect the knee temperature of the precipitation.
    Effect of Nb on carburizing depth and hardness of 20CrMo gear steel
    Zhang Wei, Shen Kang, Li Huichao, Wang Maoqiu
    2021, 46(10):  31-33.  doi:10.13251/j.issn.0254-6051.2021.10.005
    Abstract ( 100 )   PDF (557KB) ( 27 )  
    According to comparative analysis of the depth and microhardness of the carburizing layer of 20CrMo steel containing Nb and without Nb carburized at different temperatures and carburizing time, the effect of Nb on carbon diffusion rate and final carburized layer quality was determined. The results show that the depth of carburized layer of 20CrMoNb steel with 0.032% Nb is close to that of 20CrMo steel at the same carburizing condition when the carburizing temperature is lower than 1000 ℃. And the maximum hardness difference of effective carburized layer is between 10 and 20 HV0.2, thus the addition of Nb has little effect on depth and hardness of the carburized layer. When the carburizing temperature is higher than 1000 ℃, the addition of Nb will reduce the depth and hordness of the effective carburized layer.
    Effect of heating temperature on solid solution behavior of secondary phases of non-oriented silicon steel for high Ni-Ti new energy vehicles
    Liu Yang, Jin Zili, Ren Huiping, Ji Lin
    2021, 46(10):  34-38.  doi:10.13251/j.issn.0254-6051.2021.10.006
    Abstract ( 51 )   PDF (556KB) ( 19 )  
    Solid solution behaviors of the secondary phases in non-oriented silicon steel for new energy vehicles at different heating temperatures were studied by means of differential scanning calorimetry (DSC), plasma mass spectrometer and transmission electron microscope. The results show that when heated to 1076.2 ℃, the tested steel undergoes significant phase transformation. Under the condition of holding for 40 min, with the increase of heating temperature, the amount of Nb and Ti elements in solid solution gradually increase, and that in precipitates decrease correspondingly, and most of the precipitates are (Nb,Ti)C. Under different heating temperatures, the average size of the precipitates is different, and it shows an upward trend with the increase of the tested temperature.
    Effect of isothermal treatment on semi-solid microstructure of extruded AZ80A magnesium alloy
    Duan Xingwang, Li Peng, Li Kai
    2021, 46(10):  39-44.  doi:10.13251/j.issn.0254-6051.2021.10.007
    Abstract ( 56 )   PDF (556KB) ( 44 )  
    AZ80A magnesium alloy semisolid billet was prepared by strain induced melting activation (SIMA) method, and the effects of holding temperature and holding time on the semi-solid microstructure were studied. The results show that the average grain size and liquid fraction of the AZ80A magnesium alloy increase with the increase of the holding temperature and holding time, and the shape factor increases first and then decreases. The semi-solid microstructure is composed of α-Mg grains, liquid phase at grain boundary and intragranular “small liquid pools” formed by the enrichment of Al and Zn elements. The microstructure evolution can be divided into three stages: initial grain growth, grain spheroidization and separation, and finally grain coarsening. When using the SIMA method to prepare semi-solid AZ80A magnesium alloy, the suitable holding temperature is 550 ℃ and the holding time is 45 min, by which the average grain size, shape factor and liquid fraction of the semi-solid microstructure are 89 μm, 0.795 and 26.7%, respectively.
    Effect of heat treatment on anisotropic microstructure of additive manufacturing 316L stainless steel
    Dong Zhihao, Zheng Zhijun, Peng Le
    2021, 46(10):  45-52.  doi:10.13251/j.issn.0254-6051.2021.10.008
    Abstract ( 62 )   PDF (559KB) ( 23 )  
    316L stainless steel prepared by selective laser melting (SLM) was taken as the researching object. First, the porosity and microstructure of the printed parts were characterized, then the influence of heat treatment on anisotropy of the microstructure and hardness was explored. The results show that both the volume fraction and the area fraction of porosity of the printed parts are low (below 1%), and no obvious difference between the two. For the XY plane perpendicular to the printing direction, it is mainly composed of strip micro-melt pools passing across each other at angle of 67°. Each micro-melt pool consists of both columnar and cellular microconstituents. The former is mainly located at the boundary of the molten pool, with a length of about tens of microns and a width of about 400 nm. The latter is mainly located at the center of the molten pool with a size of about 400 nm. For the YZ plane parallel to the printing direction, it is mainly composed of fan-shaped microstucture containing columnar and cellular microconstituents. However, the distributions of these columnar and cellular microconstituents are more complex. The columnar microconstituent running through the multilayer molten pool, XY plane and YZ plane have obvious microstructure anisotropy. The appropriate heat treatment process can effectively decrease the anisotropy of the microstructure in the different planes. The XY plane can basically be homogenized after annealing at 800 ℃ for 2 h, while the YZ plane can be homogenized at 900 ℃ for 2 h. Additive manufacturing parts with micro-nano size structure have higher hardness than that of the traditional parts. In generally, the heat treatment can decrease the hardness in different directions, but the descender is greater in the vertical printing direction.
    Effect of induced anisotropy on magnetic properties of FeCoNiSiB amorphous alloy
    Liu Tiancheng, Pan Yun, Li Guangmin, Jiao Liguo, Cui Kesheng
    2021, 46(10):  53-57.  doi:10.13251/j.issn.0254-6051.2021.10.009
    Abstract ( 58 )   PDF (569KB) ( 21 )  
    Effects of isothermal tension annealing and transverse magnetic field annealing on anisotropy and magnetic properties of FeCoNiSiB amorphous alloy were investigated. The results show that the alloy exhibits higher DC tolerance property accompanied with higher core loss after isothermal tension annealing, while the alloy has excellent comprehensive soft magnetic properties including high DC tolerance and low core loss after transverse magnetic field annealing. During isothermal tension annealing process, the DC tolerance property of the alloy is improved with the increase of annealing temperature. After annealing at 550 ℃ for 5 min with tensile stress, the DC-bias field intensity H0.98 of the alloy is 195 A/m and the corresponding core loss Pcm is 7255 W/kg. However, after annealing at 450 ℃ with transverse magnetic field, the DC-bias field intensity H0.98 is improved to 374 A/m, and the corresponding core loss Pcm is only 200 W/kg. In addition, the 180° stripe magnetic domain structures are charactered after isothermal tension annealing and transverse magnetic field annealing, but the direction of magnetization vector in magnetic domain is parallel and perpendicular to the direction of magnetization respectively.
    Effect of boron content on microstructure and mechanical properties of Fe2B-Mo2FeB2-based cermets
    Wei Xiang, Peng Guangwei, Yu Hongbin, Liu Baogang, Wang Li, Kong Lingnan
    2021, 46(10):  58-64.  doi:10.13251/j.issn.0254-6051.2021.10.010
    Abstract ( 48 )   PDF (614KB) ( 20 )  
    Fe2B-Mo2FeB2-based cermets with 4 different boron contents were prepared by vacuum sintering process, and the effect of boron content on sintering characteristics, microstructure and mechanical properties of the cermets was investigated. The results show that all the specimens mainly consist of Fe2B, Mo2FeB2 and Fe3B phases. With the increase of boron content, the content of liquid phase L1 formed during the sintering process gradually decreases, and the optimal sintering temperature of the cermet gradually increases. Moreover, the hardness and transverse rupture strength of the cermets are also increased, and the maximum values of hardness and transverse rupture strength are 88.52 HRA and 685.74 MPa, respectively. The composite microstructure of Mo2FeB2 and Fe3B (or Fe2B phase) can extend the crack propagation path during the fracture process, and the pulling out of long rod-shaped Mo2FeB2 phase from Fe3B phase (or Fe2B phase) is beneficial to the improvement of transverse rupture strength of the cermets.
    PROCESS RESEARCH
    Effect of heat treatment on microstructure and properties of G115 steel casting
    Liu Xinyang, Chen Zhengzong, Zhou Yun, Bao Hansheng
    2021, 46(10):  65-73.  doi:10.13251/j.issn.0254-6051.2021.10.011
    Abstract ( 68 )   PDF (556KB) ( 22 )  
    Taking homogenizing annealed G115 steel casting as research subject, the effects of different (normalizing+tempering) treatment process on microstructure and mechanical properties of the steel casting were studied. The normalizing temperatures were respectively 1070 ℃ and 1100 ℃, both holding for 1 h then air cooling (AC). The tempering processes were single tempering (780 ℃×3 h, AC), and double tempering (780 ℃×3 h, AC then 750 ℃×3 h, AC), respectively. The results show that with the increase of normalizing temperature, both the room temperature strength and the 650 ℃ high temperature strength of the G115 steel casting increase somewhat, while the toughness decreases somewhat, and the plasticity does not change obviously. With the increase of tempering times, both the room temperature strength and the 650 ℃ high temperature strength decrease somewhat, while the toughness and plasticity do not change obviously. Laves phase, M23C6 and MX (NbC, VN) phases are the main precipitated phases in the G115 steel casting after normalizing and tempering, and the impact fracture is characterized by cleavage or quasi-cleavage fracture. With the increase of normalizing temperature, the width of martensite blocks increases and the arrangement is relatively neat. The prior austenite grain size is the effective grain size for grain boundary strengthening in the contribution value of the room temperature strength of G115 steel casting. In summary, the recommended heat treatment process is normalized at 1100 ℃ for 1 h, AC, then tempered at 780 ℃ for 3 h, AC.
    Effect of solution and aging treatment on microstructure and properties of high manganese low nickel stainless steel
    Tang Peng, Yu Fengyang, Zhao Yanjun, Hu Zhiliu, Long Zhengliang
    2021, 46(10):  74-80.  doi:10.13251/j.issn.0254-6051.2021.10.012
    Abstract ( 79 )   PDF (553KB) ( 17 )  
    Effects of solution and aging temperature on microstructure and properties of a new type high manganese low nickel stainless steel were studied. The results show that the microstructure of annealed and solution treated high manganese low nickel stainless steel are composed of a single phase austenite. With the increase of solution temperature, the grain grows and precipitates dissolve into the matrix, which makes the strength and hardness of the material decrease continuously. After solution treated at 1050 ℃, all precipitates have been dissolved, meanwhile, the tensile strength is 1016 MPa, elongation and reduction of area are 67.43% and 53.6%respectively, and the plasticity is the best. Therefore, the best solution temperature of the high manganese low nickel stainless steel is 1050 ℃. Moreover, the precipitates in the high manganese low nickel stainless steel are mainly Cr carbon nitride and Mn sulfide after solution an aging treatmant. After aging at 750 ℃, the content of precipitates reaches the peak, and the strength and hardness reach the highest. Therefore, 750 ℃ is the most sensitive precipitation temperature of the high manganese low nickel stainless steel. When the aging temperature is above 750 ℃, the content of precipitates decreases, and the plasticity of the material is the best when aged at 850 ℃.
    Effect of cryogenic treatment on microstructure and thermal fatigue properties of H13 steel
    Zhang Xu, He Wenchao, Wei Xinhong, Li Jun, Guo Han, Li Shaohong
    2021, 46(10):  81-85.  doi:10.13251/j.issn.0254-6051.2021.10.013
    Abstract ( 98 )   PDF (551KB) ( 31 )  
    Effect of cryogenic treatment on microstructure and properties of the H13 hot-working die steel was studied by means of OM, SEM, TEM, XRD, microhardness tester and thermal fatigue testing machine, and compared with the conventional quenching and tempering process. The results show that, the addition of cryogenic treatment on the basis of conventional quenching and tempering process is beneficial to refine the grain microstructure of the tested steel and promote the transformation of retained austenite to martensite. In addition, under the condition of cryogenic treatment, the martensite lattice is easy to shrink at extremely low temperature, which promotes the carbon atom segregation at defects such as dislocations and the precipitation in form of carbides during the tempering process. These precipitated large number of fine and dispersed carbides can pin dislocations, play a certain role in alleviating the stress concentration caused by thermal cycling, and slow down the growth rate of thermal fatigue cracks. And the precipitation of fine and dispersed carbides after cryogenic treatment reduces the growth rate of carbides during thermal fatigue of the H13 steel, reduces the number of thermal fatigue cracks, and improves thermal fatigue properties.
    Effect of secondary aging temperature on microstructure and properties of 7B04-T74 aluminum alloy sheet
    Yao Ze, Zhong Liwei, Lu Yingfeng, Feng Zhaohui, Chen Junzhou
    2021, 46(10):  86-91.  doi:10.13251/j.issn.0254-6051.2021.10.014
    Abstract ( 71 )   PDF (552KB) ( 22 )  
    Effect of secondary aging temperature on microstructure and properties of the 2 mm thickness 7B04-T74 alloy sheet was studied by means of optical microscope, transmission electron microscope, tensile test, conductivity test, exfoliation corrosion test and fatigue limit test. The results show that when the secondary aging temperature gradually increases from 165 ℃ to 175 ℃, the grain structure characteristics of the 7B04-T74 alloy have no obvious change, the number of precipitates within the grain decreases but their size increases, and the precipitates at grain boundary are coarse and intermittent distribution. Tensile strength and yield strength of the 7B04-T74 aluminum alloy sheet at room temperature are significantly reduced, the elongation has no obvious change, the conductivity is significantly increased, and the exfoliation corrosion grade has no obvious change trend. By comparing the structure and properties of the 7B04 aluminum alloy at different secondary aging temperatures, it comes to the conclusion that the optimal secondary aging temperature for 2 mm thickness 7B04 alloy sheet from annealing state to T74 state is 173 ℃.
    Effect of aging temperature on microstructure and mechanical properties of TB15 titanium alloy
    Li Mingxiang, Hu Shengshuang, Chen Suming, Xiao Jun, Zhang Yingyun, Zhang Bingxian, Xu Yong
    2021, 46(10):  92-95.  doi:10.13251/j.issn.0254-6051.2021.10.015
    Abstract ( 66 )   PDF (556KB) ( 21 )  
    Effect of aging temperature on the microstructure and mechanical properties of TB15 titanium alloy was studied by means of OM, SEM and tensile testing. The results show that with the aging temperature increasing from 520 ℃ to 540 ℃, the tensile strength and yield strength of the TB15 titanium alloy first increase and then decrease, and the highest tensile strength and yield strength can be obtained at 530 ℃ of aging treatment. The plasticity of the alloy is low after aging treatment, which variation is opposite to the strengths. As the increase of aging temperature, the fracture toughness of the alloy increases gradually. After aging at different temperatures, a large number of secondary α lamellar phases are precipitated in the solid solution treated TB15 titanium alloy, and the equiaxed β microstructure transforms into lamellar α and β transformed microstructure.
    Effect of multi-stage aging on properties of 6061 aluminum alloy via CCD method
    Duan Wei, Jian Sicong, Wu Chaoqun, Xiao Yongtong, Lu Fengchi, Li Yu, Hu Zijian, Ming Liang
    2021, 46(10):  96-100.  doi:10.13251/j.issn.0254-6051.2021.10.016
    Abstract ( 47 )   PDF (569KB) ( 18 )  
    Central composite design (CCD) method was used to design the time parameters of solution and two stage aging processes for 6061 aluminum alloy, and a reliable mathematical model of the time parameters and tensile strength (r2=0.9078) was obtained in combination with the mechanical performance test results. Through calculation and analysis of variance, it can be seen that the two-step aging time has a significant effect on tensile strength and is negatively correlated with tensile strength. Based on this, the best heat treatment process consists of solid solution at 550 ℃ for 108 min, peak aging at 180 ℃ for 246 min and then two-step aging at 220 ℃ for 3 min, the tensile strength and elongation of the 6061 aluminum alloy under the process is 345 MPa and 13.5%, respectively.
    Effect of solid solution time on microstructure and crushing performance of Al-5.7Zn-0.7Mg aluminum alloy profiles
    Pan Renjie, Chen Kangmin, Guo Hui, Fan Shitong
    2021, 46(10):  101-107.  doi:10.13251/j.issn.0254-6051.2021.10.017
    Abstract ( 51 )   PDF (652KB) ( 21 )  
    Solid solution treatment at 470 ℃for different time and two-stage aging treatment for Al-5.7Zn-0.7Mg aluminum alloy thin-walled profiles were carried out to investigate the effects of grain microstructure and recrystallisation on the crushing performance such as average load (Fm), peak load (Fp), energy absorption (U) by means of optical microscopy (OM), electron backscattered diffraction (EBSD), quasi-static axial crushing test and room temperature tensile test, and the characteristics of crushing deformation and the causes of cracking of the alloy were studied. The results show that the recrystallization degree of the aluminum alloy profiles increases with the solution time increasing, while the strength decreases gradually, and the peak load, energy absorption and average load of the aluminum alloy thin-walled beam also decreases gradually. The peak load and absorbed energy of the aluminum alloy profiles after online water quenching are 406 kN and 33.3 kJ, respectively. After solid solution treated for 120 min, the peak load and energy absorption are 359 kN and 30.7 kJ, which reduced by 11.5% and 8% compared with onhine water quenching, respectively. When solid solution for a long time, the recrystallization degree of the aluminum alloy profiles increases significantly, and the recrystallized grains are generally with large-angle grain boundaries along which the cracks are more likely to propagate, and the specimens are more likely to crack.
    Effect of annealing temperature on microstructure and properties of 21Cr-0.3Cu ferritic stainless steel
    Yin Hongxiang, Zhang Qian, Wu Yi, Zhang Heng, Zhao Sa
    2021, 46(10):  108-111.  doi:10.13251/j.issn.0254-6051.2021.10.018
    Abstract ( 80 )   PDF (580KB) ( 19 )  
    Effect of annealing temperature on microstructure, mechanical properties, formability, and microtexture of the 21Cr-0.3Cu ultra-pure ferrite stainless steel was studied by means of optical microscope, tensile testing and backscattered electron diffraction. The results show that when the tested steel is annealed at 970 ℃, the grains are fine and uniform, and the structure is in a completely recrystallized state. When the annealing temperature is lower than 970 ℃, the recrystallization is incomplete; while when higher than 970 ℃, the recrystallized grains grow abnormally, and mixed grain microstructure appears in both the cases. When the tested steel is annealed at 970 ℃, the overall mechanical properties are the best, with a tensile strength of 473 MPa, a yield strength of 315 MPa, and an elongation of 35.7%. As the annealing temperature rises, the average plastic strain ratio rm first increases then decreases, getting the maximum value of 1.82 at 800 ℃. The change trend of the γ texture density is consistent with that of the value of average plastic strain ratio rm. When the annealing temperature is 970 ℃, the γ texture is reinforced obviously. At this time, its orientation density reaches the maximum value f(g)=20.56, and the forming performance is the best.
    Effect of normalizing process on microstructure and properties of 420 MPa grade steel plate for offshore wind power
    Yuan Rui, Pan Zhongde, Wu Huibin
    2021, 46(10):  112-116.  doi:10.13251/j.issn.0254-6051.2021.10.019
    Abstract ( 58 )   PDF (573KB) ( 27 )  
    Effect of different heat treatment processes, which are normalizing, strengthening normalizing, normalizing+400 ℃ tempering, on the microstructure and properties of 420 MPa steel plate for offshore wind power was studied by means of scanning electron microscope, laser confocal microscope, room temperature tensile test, low temperature impact test and other experimental methods. The results show that after normalization, the average grain size of the steel is refined from 8 μm to 6 μm compared with that as-rolled, the band microstructure is improved, the strength and low-temperature impact property are improved as the impact absorbed energy at -50 ℃ reaching to 120 J and the yield strength increasing to 442 MPa. After normalizing+400 ℃ tempering, the average grain size is 7 μm, the low-temperature impact property of the steel is greatly improved (the impact absorbed energy at -50 ℃ can reach 194 J), but the yield strength reduces to 422 MPa. After strengthening normalization and compared with that of normalizing, the microstructure is composed of ferrite+pearlite+a small amount of bainite, the average grain size is refined to 5.6 μm, the yield strength is increased to 460 MPa, the elongation after fracture and the low-temperature impact absorbed energy are somewhat reduced but can meet the EN10025 performance standard and achieve the best match of strength and toughness. It is proved that the strengthening normalization is the best heat treatment process for the production of 420 MPa grade offshore wind power steel.
    Effect of aging treatment on properties of Al-Mg-4.5Si-4.5Zn alloy
    Sun Yuejun, Zhong Li, Cui Zewen, Zhao Kangpei, Ding Daicun, Wang Lei
    2021, 46(10):  117-121.  doi:10.13251/j.issn.0254-6051.2021.10.020
    Abstract ( 50 )   PDF (577KB) ( 18 )  
    Effect of aging treatment after solid solution at 540 ℃ for 2 h and water quenching on the properties of Al-Mg-4.5Si-4.5Zn alloy was studied. The results show that with the increasing of aging temperature and aging time, the hardness of the alloy increases first and then decreases, and reaches the maximum value of 135.1 HBW when aging at 190 ℃ for 2 h.The tensile strength of the alloy increases first and then decreases with extending of aging time,and reaches the maximum value of 390.12 MPa when aging at 190 ℃ for 3 h. Based on the comprehensive properties, the optimal aging process for Al-Mg-4.5Si-4.5Zn alloy is aging at 190 ℃ for 3 h.
    Effect of heat treatment on microstructure and tensile properties of Inconel 718 alloy prepared by selective laser melting
    Zeng Qiang, Wu Ying, Xiao Huijin, Zhu Shaowei
    2021, 46(10):  122-126.  doi:10.13251/j.issn.0254-6051.2021.10.021
    Abstract ( 51 )   PDF (573KB) ( 19 )  
    Inconel 718 alloy was prepared by selective laser melting (SLM) process. The solution treatment at 1050 ℃ for 1 h, solution treatment at 1050 ℃ for 1 h and aging treatment at 720 ℃ for 8 h and 620 ℃ for 8 h were respectively applied on the SLM processed alloy. The effect of heat treatment process on the microstructure and mechanical properties of the SLM-Inconel 718 alloy were studied by combining with microstructure analysis, tensile properties analysis and fracture characteristics analysis. The results show that the density of dislocations is significantly reduced associated with Laves phase dissolving after solid solution treatment. Hence the strength-plasticity matching of the alloy is better than that of the as-SLM state. After aging, γ′ and γ″ strengthening phases precipitate out, which greatly increase the strength of the alloy while retaining a certain plasticity.
    Effect of scanning interval on microstructure of IN718 alloy formed by SLM
    Zheng Junnan, Jin Tounan, Fang Xiaoying, Ma Tiejun, Li Wei
    2021, 46(10):  127-132.  doi:10.13251/j.issn.0254-6051.2021.10.022
    Abstract ( 52 )   PDF (577KB) ( 19 )  
    IN718 alloy was prepared byusing selective laser melting(SLM) technology, and the compactness, phase composition, grain morphology and orientation of IN718 alloy was analyzed by means of X-ray microscope, X-ray diffractometer, scanning electron microscope and electron backscattered diffraction techniques. The results show that the phaseof the IN718 alloy formed by SLM is composed of face-centered cubic structure γ-Ni phase and body-centered tetragonal γ″ phase, and columnar crystal grains formed along building direction. When the laser scanning interval is 100 μm, the density of the alloy reaches the highest. When the laser scanning interval is 90 μm, a strong <001> texture is formed along the building direction
    Heat treatment process for improving cryogenic toughness of Cr-Ni-Co-Mo maraging stainless steel
    Ji Yurui, Yang Zhuoyue, Tan Honglin, Ding Yali
    2021, 46(10):  133-136.  doi:10.13251/j.issn.0254-6051.2021.10.023
    Abstract ( 82 )   PDF (572KB) ( 21 )  
    Heat treatment processes to improve the cryogenic toughness of Cr-Ni-Co-Mo maraging stainless steel were investigated, including preheating at 600 ℃+low temperature solution treatment at 750 ℃, and direct solution treating once or twice at 750 ℃ without preheating respectively, all after solution treatment at 1000 ℃. The volume fractions of martensite, retained austenite and reversed austenite phases were determined respectively, and the tensile strength at room temperature and -196 ℃, the notched tensile strength and impact toughness at -196 ℃ were analyzed. The results show that compared with the conventional heat treatment, more retained austenite exists in the steel after adding low temperature solution treatment at 750 ℃. Moreover, more reversed austenite is formed after subsequently aging at 500 ℃, which can significantly improve the cryogenic toughness. Further comparative analysis shows that the process of direct solution treatment at 750 ℃ is relatively simple, which can lead to the highest tensile strength at both room temperature and -196 ℃, the highest notch tensile strength at -196 ℃, and lower notch sensitivity at -196 ℃. Therefore, the direct solution treatment at 750 ℃ has advantage over other treatments.
    Heat treatment process based on 07MnNiMoDR steel heat treatment process window
    Liu Feng, Pang Yuhua, Luo Yuan, Sun Qi, Wang Hai, Liu Dong
    2021, 46(10):  137-143.  doi:10.13251/j.issn.0254-6051.2021.10.024
    Abstract ( 55 )   PDF (575KB) ( 19 )  
    Relationship between quenching and tempering prcesses and grain size and polygonal ferrite content of the 07MnNiMoDR steel was studied, and the austenite size window and tempered polygonal ferrite content window during quenching and tempering were established, and a more precise heat treatment process was determined. The results show that the austenite grain size increases with the increase of austenitizing temperature and holding time, and there is an optimal range of uniformity. The reasonable quenching process is heating at (940±10) ℃ and holding for (80±10) min. When the temperature rises, polygonal ferrite appears at about 650 ℃, of which content increases with the increase of tempering temperature and holding time. The reasonable tempering process is heating at (665±5) ℃ for (165±15) min. The optimal heat treatment process consists of quenching at 940 ℃ for 80 min and tempering at 660 ℃ for 180 min. The final performance test results show that the elongation, impact absorbed energy and yield strength are increased by 40.88%, 206.25% and 12.1%, respectively, compared with the national standard.
    Effect of quenching process on microstructure and mechanical properties of H13E steel
    Ai Yunlong, Liu Zhe, Chen Weihua, Zhu Zhentao, Luo Guihai, Liang Bingliang
    2021, 46(10):  144-150.  doi:10.13251/j.issn.0254-6051.2021.10.025
    Abstract ( 53 )   PDF (573KB) ( 19 )  
    Effects of quenching process on microstructure and mechanical properties of the H13E steel, a modified H13 by adjusting alloying elements, were studied. The results show that the austenite grain size increases monotonically with the increase of quenching temperature. The average austenite grain size increases by about 40 μm when the temperature is increased from 1020 ℃ to 1080 ℃. The maximum hardness is 61.6 HRC at 1060 ℃, which is 3 to 5 HRC higher than that of the traditional H13 steel, and the impact property value can be more than 16 J. When the holding time is 20-50 min, the austenite grain growth rate slows, the average austenite grain size increases by only about 7 μm, and the hardness decreases by only about 0.2 HRC. Under the same conditions, the martensite of H13E steel after oil cooling is finer, and the mechanical properties are better than those of the H13E steel after air cooling. Considering the comprehensive mechanical properties, the optimal quenching process for the H13E steel is holding at 1060 ℃ for 20-30 min, then oil cooling.
    Effect of single pass large deformation cold rolling and annealing treatment on microstructure and properties of 2205 duplex stainless steel
    Guo Yu, Chen Ji, Yang Meitong
    2021, 46(10):  151-154.  doi:10.13251/j.issn.0254-6051.2021.10.026
    Abstract ( 52 )   PDF (573KB) ( 30 )  
    Effects of single-pass cold rolling with large deformation and annealing treatment on microstructure and properties of the 2205 duplex stainless steel were studied by means of microscopic observation, X-ray diffraction, Vickers microhardness and potentiodynamic polarization curve measurement. The results show that due to the single-pass cold rolling with large deformation, severely elongated grains are significantly broken to form fibrous microstructure and high-density dislocations pile-up, which significantly increases the hardness of the tested material by about 1.5 times, and the self-corrosion current density is 2% lower than that of the original specimen due to the grain refinement, the corrosion resistance of which in 3.5%NaCl solution is slightly improved. The cold-rolled specimen annealed at 500 ℃ for 4 h can refine the microstructure to about 300 nm, the corrosion resistance of which can significantly improve, and the self-corrosion current density reduces by 33% compared with original specimen. When the annealing temperature is increased to 700 ℃, the degree of dislocation annihilation in the two-phase microstructure is not uniform, the σ phase will precipitate at the phase boundary, and the hardness will be further increased, but it is not good for the corrosion resistance, and the self-corrosion current density decreases by 3% compared with original specimen.
    Welding and heat treatment process of 12Cr2Mo1VR/20MnMoNb dissimilar steel joint in auxiliary equipment of power plant
    Yin Runbang, Lin Baosen, Mo Qipeng, Li Zhiwei, Zheng Zhou, Tan Hong, Chen Jianbin, Wang Jiongming
    2021, 46(10):  155-162.  doi:10.13251/j.issn.0254-6051.2021.10.027
    Abstract ( 49 )   PDF (573KB) ( 21 )  
    For the 12Cr2Mo1VR/20MnMoNb dissimilar steel joints in the auxiliary equipment of the power station, the transition method of the ferrite surfacing layer was designed by studying the joint characteristics, high temperature allowable stress of the materials (including welding materials), heat treatment temperature, chemical composition and mechanical properties at room temperature, so to solve the problem that the directly connected dissimilar steel joints could not be heat treated. The welding and heat treatment processes of 12Cr2Mo1VR/20MnMoNb dissimilar steel weld are proposed as follows based on experimental analysis: First, the F62P0-EB2R-B2R transition layer is surfacing on the 12Cr2Mo1VR groove surface, and the surfacing layer is heat-treated at (690±10) ℃, then the surfacing layer and the 20MnMoNb steel are butted with F69P0-H10Mn2NiMoA welding material and treated at (660±10) ℃. Or both sides of the butt weld are treated at different temperatures: the surfacing layer side is treated at (660±10) ℃(or (665±15) ℃) and the tube sheet side is treated at (620±10) ℃(or (620±15) ℃).
    Influence of pre-annealing before solution on microstructure and properties of 6111 aluminum alloy
    Li Dalin, Zhu Pengcheng, Wang Ping, Lü Zhengfeng, Zhang Shanshun
    2021, 46(10):  163-167.  doi:10.13251/j.issn.0254-6051.2021.10.028
    Abstract ( 59 )   PDF (577KB) ( 22 )  
    Influence of pre-annealing before solution treatment on microstructure and mechanical properties of cold rolled and T4P state 6111 aluminum was investigated. The mechanical properties were tested, the LDR value was calculated, and microstructure was characterized by means of optical microscopy and scanning electronic microscopy (SEM). The texture was tested by using XRD. The results indicate that pre-annealing temperature has little effect on yield strength, but the tensile strength decreases from 245 MPa to 230 MPa after annealing at 300 ℃ for 2 h. The elongation decreases sharply when pre-annealing temperature is higher than 100 ℃. The n and r value increase first and then decrease with the increase of pre-annealing temperature. n value reaches the peak(0.289) at 200 ℃ and r value reaches the peak (0.958) at 100 ℃. LDR value reaches the peak value of 2.005 after 200 ℃×2 h pre-annealing. The grain size of T4P state alloy after pre-annealing at 300 ℃ for 2 h ranges from 60 μm to 150 μm. The volume fraction of Cube texture of T4P state alloy after pre-annealing at 200 ℃ for 2 h reaches the peak value of 13.5%.
    Effect of tempering temperature on microstructure and properties of ultra low carbon 7%Mn steel
    Yang Yuehui, Yuan Shaoqiang, Liang Guoli, Wang Zhu
    2021, 46(10):  168-172.  doi:10.13251/j.issn.0254-6051.2021.10.029
    Abstract ( 77 )   PDF (629KB) ( 21 )  
    Microstructure and mechanical properties of the ultra low carbon medium manganese steel after quenching and tempering at different temperatures were studied, and the amount of reversed austenite in the tested steel before and after low temperature treatment (-60 ℃, -80 ℃ and -100 ℃) was measured by means of XRD. Based on this, the effect of reversed austenite content and thermal stability on mechanical properties of the tested steel was analyzed. The results show that higher temperature tempering promotes the formation of reversed austenite, in which the austenite stabilizing elements are quickly enriched. Meanwhile the austenite obtained at higher tempering temperature is more distributed between the coarsened martensitic laths, which makes the austenite have high stability. Due to the more reversed austenite in the tested steel, the TRIP effect is more significant in the process of deformation, which promotes the improvement of low temperature toughness and plasticity of the tested steel.
    Effect of parameter in secondary heating stage of high temperature annealing process on formation of bottom layer on HiB steel
    Xu Pingsan, Guo Yue, Dai Fangqin, Zeng Xican, Hu Shoutian, Liu Min
    2021, 46(10):  173-177.  doi:10.13251/j.issn.0254-6051.2021.10.030
    Abstract ( 71 )   PDF (573KB) ( 21 )  
    Effects of annealing temperature and dew point temperature in the secondary heating stage of high temperature annealing process on formation of magnesium silicate on surface of the HiB oriented silicon steel were studied. The results show that the quality of the forsterite film is better when the final temperature of the secondary heating stage of high temperature annealing is in the range of 1100-1170 ℃, but when water vapor remains in the annealing atmosphere during the secondary heating stage of the high temperature annealing, the quality of the forsterite film on the surface of the HiB oriented silicon steel is poor, and the higher the water vapor content is (meaning the higher the dew point temperature is), the thinner the thickness of the forsterite film, and the worse the quality of the forsterite film is.
    Influence of intermediate high-temperature tempering process on microstructure and properties of carburized 15MnNi4MoA steel
    Gao Zhizhe, Chen Xiaoyan, Cheng Fuchao, Li Jiakang, Su Shengrui, Wang Yongjin
    2021, 46(10):  178-181.  doi:10.13251/j.issn.0254-6051.2021.10.031
    Abstract ( 61 )   PDF (629KB) ( 20 )  
    Effect of heat treatment process on microstructure and properties of the carburized 15MnNi4MoA steel was studied. Three different post-carburizing heat treatment processes were designed, i.e.: quenching+low temperature tempering, once high temperature tempering+quenching+low temperature tempering and twice high temperature tempering+quenching+low temperature tempering, and the mechanical properties and microstructure of the tested steel after heat treatment were compared and analyzed. The microstructure and impact fracture morphologies of the tested steel after heat treatment were observed by means of scanning electron microscope. At the same time, the Vickers-hardness and impact absorbed energy (U-notch) at room temperature of the specimens under different heat treatment processes were tested. The results show that after heat treatment, the microstructure of the all specimens has little difference, which is martensite+retained austenite. The specimen treated by twice high temperature tempering treatment has a finer martensite structure and better mechanical properties. The core hardness is reduced to 358 HV, the surface hardness is increased to 664 HV, and the impact absorbed energy at room temperature reaches 143 J.
    Effect of heat treatment on mechanical properties and low temperature toughness of 3.5Ni steel with different carbon content
    Liu Haisheng, Li Jing, Wang Huigang, Yang Yuehui, Liu Jinxu, Wu Huibin
    2021, 46(10):  182-186.  doi:10.13251/j.issn.0254-6051.2021.10.032
    Abstract ( 60 )   PDF (570KB) ( 22 )  
    Effect of heat treatment on mechanical properties and low temperature toughness of two types of 3.5Ni steel with different carbon contents was studied by means of tensile testing and low temperature impact testing, and the microstructure of the steel was observed by means of optical microscope and SEM. The heat treatment of the two types of 3.5Ni steel hot-rolled plates were normalizing (860 ℃ for 1 h, air cooling) and quenching and tempering (860 ℃ for 1 h, water quenching and then tempering at 580, 610 and 640 ℃ for 1 h). The results show that the 3.5Ni steel with high carbon content has low strength and high absorbed plasticity after hot rolling, but low impact absorbed energy at -100 ℃. After normalizing treatment, the overall properties of the tested steel are decreased, while after quenching and tempering treatment, the strength and low temperature impact absorbed energy are significantly improved, while the plasticity is slightly reduced. The 3.5Ni steel with low carbon content has excellent tensile properties and low temperature impact properties after hot rolling, but the tensile properties and low temperature toughness have no significant improvement after heat treatment.
    Effect of electron beam welding on microstructure and properties of quenched and tempered 15CrMnMoVA high strength steel
    Yang Shiliang, Li Lihang, Dai Hao, Li Zhiyong, Zhao Tong
    2021, 46(10):  187-192.  doi:10.13251/j.issn.0254-6051.2021.10.033
    Abstract ( 59 )   PDF (570KB) ( 22 )  
    In order to achieve high-quality joint of aviation high-strength steel with high hardening tendency, electron beam welding process was carried out with the 15CrMnMoVA high-strength steel as the research object. For the electron beam welding joints with different structures, the microstructure characteristics and microhardness distributions were analyzed, and the mechanical properties were tested and analyzed, and the effect of electron beam welding process on the microstructure and mechanical properties of the joint was discussed. The results show that net basket martensite is formed in the weld center of the tested steel, and its microhardness is a typical saddle distribution. The tensile properties of electron beam welded joints with different lock bottom structures are basically equivalent to that of the base metal, but their fatigue properties are obviously different. When the lock bottom length is 1.5 mm, the fatigue properties of welded joints are better.
    Hot forming technology of high strength steel sheet with tailored properties by partial cooling pretreatment
    Lu Yumei, Yan Shaobo, Wang Kaijun, Li Xianjun, Zhang Wenliang, Liu Junjie, Yang Tao
    2021, 46(10):  193-198.  doi:10.13251/j.issn.0254-6051.2021.10.034
    Abstract ( 50 )   PDF (631KB) ( 22 )  
    Compared with traditional hot forming technology, the technology with tailored properties can make different regions of the same part have different strength and plastic toughness, so as to improve the ductility of some regions of the part absorbing the collision kinetic energy, and prevent collision intrusion.A new hot forming process of high strength steel with tailored properties by partial cooling pretreatment was proposed as well designing a customized zone cooling platform with dry compressed air as the medium. The temperature distribution and variation of the plate under partial cooling with the jet pressure of 0.3-0.7 MPa and the influence of return air structure on the cooling capacity and transition zone width of the platform were studied. The results show that when the jet pressure is 0.3 MPa and the air return structure is added, when the air cooling zone temperature is reduced to 410 ℃ (Ms), the hard zone temperature is slowly cooled to 750 ℃ (above Ar3). After tempering at 800 ℃ and quenching, the soft zone comprises low-strength and high-plasticity ferrite and lamellar pearlite microstructure, and the hard zone comprises high-strength and low-plasticity lath martensite microstructure. These show that the high strength steel plate with tailored properties can be obtained with the new hot forming process and the customized zone cooling platform.
    Effect of post-weld tempering temperature on microstructure and room temperature mechanical properties of G115 steel deposited metal
    Qi Xiangqian
    2021, 46(10):  199-203.  doi:10.13251/j.issn.0254-6051.2021.10.035
    Abstract ( 89 )   PDF (575KB) ( 22 )  
    G115 steel filler rod was welded on a steel test plate, and then the post-weld tempering for the plate was carried out at 760, 780, 800 and 820 ℃, respectively. The mechanical properties and microstructure of the weld-deposited steel plate under different tempering temperatures were analyzed. The results show that the best tempering temperature of the G115 steel deposited on the plate is 800 ℃. With the increases of the tempering temperature, the precipitation phase M23C6 has a growing-up trend. The impact fracture of the steel plate tempered at 760-820 ℃ is characterized by dimple fracture and quasi-cleavage fracture. Spherical second phase particles are observed in the dimples which formed during the deoxidation reaction in welding metallurgy process.
    Effect of cryogenic treatment on residual stress of YG8 cemented carbide/42CrMo steel brazed joints
    Yuan Ruize, Yan Xianguo, Chen Zhi, Guo Rui, Lan Dongsheng, Su Hang, Yao Yongchao
    2021, 46(10):  204-208.  doi:10.13251/j.issn.0254-6051.2021.10.036
    Abstract ( 64 )   PDF (637KB) ( 22 )  
    Welding process model and cryogenic treatment process model of YG8 cemented carbide/42CrMo steel brazed joint were established through ANSYS simulation software, and the residual stress distribution on the joint surface was analyzed and compared with the brazed joint after cryogenic and tempering treatments. The results show that cryogenic treatment can cause the formation of residual compressive stress on the 42CrMo steel side of the brazed joint, and the influence of cryogenic temperature on the residual compressive stress is more obvious than the number of cryogenic treatments. The optimal cryogenic process is treating at -160 ℃ for three times, and the simulation result is not much different from the experimental one, indicating that the established models have a certain degree of reliability.
    Process optimization for improving toughness of 20Cr13 steel used for valve parts
    Lü Chaojun, Wang Jianbo, Zhang Tiande, Tang Lina, Wu Guohua
    2021, 46(10):  209-211.  doi:10.13251/j.issn.0254-6051.2021.10.037
    Abstract ( 57 )   PDF (640KB) ( 22 )  
    Effect of different quenching and tempering temperatures on the impact property of the 20Cr13 steel at room temperature and -40 ℃ was studied by means of metallographic microscope and scanning electron microscope. The results show that when the quenching temperature is the same, as the tempering temperature rises from 500 ℃ to 700 ℃, the tensile strength of the specimen decreases gradually, impact properties first decreases and then increases. When the quenching temperature drops from 1030 ℃ to 1000 ℃, at the same tempering temperature, the tensile strength of the specimen changes little, but the impact properties at room temperature and -40 ℃ improves.
    Microstructure transformation of door impact beam on induction hardening
    Xia Xiaoyu, Xiao Jinya, Wei Hanwei, Wang Shen
    2021, 46(10):  212-217.  doi:10.13251/j.issn.0254-6051.2021.10.038
    Abstract ( 60 )   PDF (638KB) ( 23 )  
    Domestic made BR1500HS high-strength steel automobile door impact beam was studied by using high-frequency induction heat treatment technology, when the impact beam obtained a complete hardened microstructure under the different feeding speed between 70-120 mm/s, the relationship between heating voltage and feeding speed of the impact beam was explored. The results show that with the decrease of feeding speed, the heating voltage required for through quenching also decreases, and the demarcation line is used to distinguish whether it is completely hardened. The high-frequency induction hardening of the impact beam adopts a heating voltage range of 30 V above the dividing line, and its mechanical properties can fully meet the properties requirements of the automobile factory.
    Wear resistance of 20Cr13 steel with high hardness
    Wang Fan, Mu Lei, Ge Rongfan, Li Fangzhong, Li Yunyin
    2021, 46(10):  218-220.  doi:10.13251/j.issn.0254-6051.2021.10.039
    Abstract ( 186 )   PDF (645KB) ( 31 )  
    20Cr13 stainless steel was quenched and tempered at different temperatures to obtain different hardness, and the corresponding friction and wear properties of the 20Cr13 steel were studied. The results show that when the tempering temperature ≥580 ℃, the hardness of the steel >40 HRC, the friction coefficient K is consistent with the hardness, and the wear resistance is poor. When the tempering temperature ≤550 ℃, the hardness >40 HRC, friction coefficient K deviates from the trend of hardness and tends to a constant value, the wear volume V is not affected by the hardness, and the wear resistance is high.
    SURFACE ENGINEERING
    Comparative test on different nitriding methods for martensitic stainless steel
    Fang Mengsha, Zhang Jin, Lian Yong
    2021, 46(10):  221-225.  doi:10.13251/j.issn.0254-6051.2021.10.040
    Abstract ( 90 )   PDF (643KB) ( 31 )  
    Plasma nitriding, liquid nitriding and gas nitriding were used to modify the surface of corrosion-resistant and heat-resistant martensitic heat-stable stainless steel 1Cr12Ni2WMoVNb. The hardness, microstructure, phase change and brittleness of the stainless steel under the three different nitriding methods were studied, and the corrosion resistance and high temperature wear resistance of the steel nitrided by the three nitriding methods were compared. The results show that the surface hardness of the steel can be greatly improved by this three nitriding methods, and the microstructure of the nitriding layer is roughly the same, but the surface phase is different, the surface phase after plasma nitriding is mainly Fe4N and a small amount of CrN phase, after liquid nitriding is Fe3O4 and ε phase, and after gas nitriding is Fe3O4, Fe4N and a small amount of ε phase. The high temperature wear resistance, especially when the temperature is in the range of 500-600 ℃, can be greatly improved by this three nitriding methods, but the corrosion resistance is all reduced.
    Influence of nitriding time in QPQ technology on microstructure and friction properties of alloy cast iron
    Wang Qinjuan, Lin Shaoyang, Chen Zhongshi, Liu Dong
    2021, 46(10):  226-231.  doi:10.13251/j.issn.0254-6051.2021.10.041
    Abstract ( 59 )   PDF (638KB) ( 21 )  
    Influence of nitriding time in QPQ technology on the microstructure and friction properties of an alloy cast iron was studied by means of OM, SEM, hardness test, friction and wear test methods. The results show that after QPQ treatment, the nitriding layer formed on the surface of the alloy cast iron is mainly composed of Fe2-3N, Fe2O3 and FeO. There is a linear relationship between the square of the nitriding layer thickness and the nitriding time. Under the condition of nitriding salt bath at 580 ℃, the activation energy of nitrogen diffusion in the alloy cast iron is 70.07 kJ/mol. Within the nitriding time range of 90-150 min, with the increase of the nitriding time, the surface hardness value of the nitriding layer decreases from 522 HV0.05 to 441 HV0.05, while when the nitriding time is extended to 180 min, the surface hardness value rises back to 455 HV0.05. Compared with the untreated specimen, the QPQ-treated specimen has a smaller friction coefficient, and after the QPQ treatment, the furrows on the surface of the specimen become significantly shallower, the metal peeling at the surface is also significantly improved. As the nitriding time increases, the thickness of the nitriding layer increases and the material is stabilized. The QPQ specimen after 180 min nitriding has the best comprehensive properties, with surface hardness value of 455 HV0.05 and friction coefficient of 0.32.
    Microstructure and properties of laser clad layer on high strength stainless steel
    Chen Yiwu, Wu Xinxiang, Zhou Lihua, Fu Tianzuo, Zhao Jing, Li Sheng
    2021, 46(10):  232-236.  doi:10.13251/j.issn.0254-6051.2021.10.042
    Abstract ( 64 )   PDF (638KB) ( 27 )  
    In response to the need for repair and remanufacturing of nuclear equipment parts, the laser cladding technology was used to prepare the clad layer of high-strength and tough martensitic stainless steel for improving the surface properties of nuclear equipment parts, and then the clad layer specimens were tempered at 300 ℃ and 500 ℃ for 2 h. The microstructure and properties of the specimens were tested by means of OM, SEM, microhardness tester, universal tensile testing machine and other equipment. The results show that the original specimen has the tensile strength of 1719 MPa, percentage elongation after fracture of about 15% and the hardness of 550 HV0.2, the wear resistance of which is poor. When the tempering temperature is 300 ℃, the reverse transformed austenite appears, resulting in the decrease of hardness and the tensile strength to 500 HV0.2 and 1662 MPa, respectively, while the elongation after fracture exceeds 15%, the wear resistance of parts is improved. When the tempering temperature increases to 500 ℃, the content of reverse transformed austenite decreases and the carbides gradually precipitate, the secondary hardening occurrs, the hardness increases to 530 HV0.2, the tensile strength decreases to 1582 MPa, the elongation after fracture decreases to 14%, and the wear resistance of parts is equivalent to the original specimen. The overall corrosion resistance of the clad layer of high-strength and tough martensitic stainless steel is better than that of the 1Cr13 steel, and has good corrosion resistance.
    Microstructure and properties of laser carbon alloyed layer on 45 steel surface
    Li Haitao, Zhang Leitao, Xia Huiyun, Dai Jiaoyan, Xu Jinfu
    2021, 46(10):  237-241.  doi:10.13251/j.issn.0254-6051.2021.10.043
    Abstract ( 70 )   PDF (648KB) ( 25 )  
    Carbon alloyed layer was prepared on the surface of 45 steel by laser alloying process. The microstructure and properties of the alloyed layer under the optimal process were studied by means of OM, XRD and microhardness tester. The microstructure characteristics and efficiency of gas carburizing and laser carbon alloying were compared. The results show that the effect of each parameter on hardness of the alloyed layer is as follows: laser power > lap rate > scanning speed. With the increase of laser power, scanning speed and lap rate, the hardness of the alloyed layer increases first and then decreases. When the laser power is 1.5 kW, the scanning speed is 500 mm/min and the lap rate is 40%, the hardness of the alloyed layer is the highest, the thickness of alloyed layer is capable of reaching 600 μm, the microstructure is composed of acicular martensite, carbide (M7C3, Fe3C) and a small amount of residual austenite, and the average hardness is about 617 HV0.3, the thickness of HAZ is 400 μm, microstructure is composed of martensite and retained austenite, and the average hardness is about 432 HV0.3, the microstructure of matrix is composed of ferrite and pearlite, the hardness is about 201 HV0.3. Compared with the traditional gas carburizing process, laser carbon alloying has the advantages of fine structure, high efficiency, green and environmental protection. It is an important development direction in the future.
    NUMERICAL SIMULATION
    Numerical simulation of temperature field of parts with large aspect ratio during high pressure gas quenching process
    Chen Xuyang, Lu Wenlin, Du Chunhui, Wang Tong
    2021, 46(10):  242-247.  doi:10.13251/j.issn.0254-6051.2021.10.044
    Abstract ( 63 )   PDF (645KB) ( 25 )  
    Aiming at the problem of quenching uniformity and deformation control of large aspect ratio parts, it was studied by numerical simulation that how it works on the temperature field of large aspect ratio parts during high pressure gas quenching process. The results show that the higher the quenching pressure, the faster the flow rate and the stronger the heat transfer capacity, the faster the cooling speed of the workpiece. The static alternating flow pattern with up-down alternating blowing has no obvious effect on cooling rate of the workpiece, but it is beneficial to improve the temperature uniformity. The shorter the interval between up-down alternating blowing, the more uniform the temperature field of the workpiece.
    TEST AND ANALYSIS
    Fault mode and fault tree analysis of WZC double chamber vacuum furnace system
    Li Yong, Zhou Xinyu
    2021, 46(10):  248-251.  doi:10.13251/j.issn.0254-6051.2021.10.045
    Abstract ( 72 )   PDF (648KB) ( 27 )  
    Fault mode and fault tree analysis of the WZC double chamber vacuum oil quenching gas cooling furnace system were carried out in the ways of subsystems and subcomponents. The failure modes and fault tree models of the furnace liner, vacuum system, mechanism and electronic control system were established respectively, the corresponding basic events were summarized, and the minimum cut set of each fault tree was obtained by using Fusel method.
    Inspection diagnosis and process improvement on end face defects of 17-4PH steel turbo shaft
    Liu Song, Han Yanchun
    2021, 46(10):  252-256.  doi:10.13251/j.issn.0254-6051.2021.10.046
    Abstract ( 86 )   PDF (640KB) ( 20 )  
    Defects were found at the end face of 17-4PH steel turbo shaft after solution and aging treatment, machining forming and hard chrome plating by using magnetic particle indication, and the characteristics and causes of which were analyzed by means of chemical composition analysis, microstructure and fracture morphologies observation, hardness and residual stress testing, magnetic particle indication, and diagnosed by combining with the inspection results of the production process. The results show that the defects are hydrogen embrittlement microcracks occurred during the hard chrome plating process, and the causes of which are mainly the higher hardness and the higher residual stress of the 17-4PH steel turbo shaft. Using underaging treatment at 430 ℃ for 1 h can appropriately reduce the hardness and residual stress of the 17-4PH steel turbo shaft, and avoid the generation of hydrogen embrittlement cracks on the end face.
    Analysis on cause of cold bending fracture of HRB400 hot-rolled ribbed bar
    Guo Ran, Wang Fuming, Sun Lijuan
    2021, 46(10):  257-261.  doi:10.13251/j.issn.0254-6051.2021.10.047
    Abstract ( 102 )   PDF (638KB) ( 27 )  
    In view of the fact that the HRB400 hot-rolled ribbed steel bars produced by steel mills often break in cold bend operations during winter, the cause of cold bending fracture of HRB400 hot-rolled ribbed bar was analyzed by means of scanning electron microscope equipped with energy dispersive spectrometer (SEM-EDS),Thermo-Calc thermodynamic software and optical microscope (OM). The effects of non-metallic inclusion, P content, V/N ratio and metallographic microstructure on fracture of the steel were discussed. The results show that the fracture of the tested steel belongs to brittle fracture, and the cracked large size inclusion is the source of the cracks. The high content of P in the steel increases the ductile-brittle transition temperature and the existence of free nitrogen intensifies the temperature further. Due to the low temperature in winter in northwest China, the working temperature of the steel is likely to be lower than the ductile-brittle transition temperature, which makes the reinforcement in a brittle state. The existence of widmanstatten microstructure increases the brittleness of the steel and provides the possibility for crack propagation. Due to the low temperature in northwest and northeast China, higher requirements should be put forward for the HRB400 hot-rolled ribbed bar used in northwest and northeast China, and new standards should be set for P, S, O and N contents in order to meet the needs of working and using temperature higher than ductile-brittle transformation temperature in winter.
    Failure analysis of fastening bolts of one steam turbine valve cover
    Zheng Jianjun, Fan Ziming, Liu Xiao, Qiao Xin, Gao Yunpeng
    2021, 46(10):  262-266.  doi:10.13251/j.issn.0254-6051.2021.10.048
    Abstract ( 54 )   PDF (641KB) ( 27 )  
    Fracture cause of the 20Cr1Mo1VTiB steel fastening bolts used for medium pressure control valve of No.4 steam turbine of a power plant was studied by means of macroscopic morphology and microstructure observation, chemical composition analysis, mechanical properties test and impact fracture morphology observation. The results show that the fracture of the fastening bolts is mainly related to the creep damage caused by long time running at high temperature. The allowable working temperature (570 ℃) of the bolt is only slightly higher than the design temperature (566 ℃) of the steam turbine, which causes an insufficient margin. Besides, the stress concentration at the nut bottom end of the first thread is always relatively high where forms creep holes under the combined action of long-term high temperature and low-speed stress concentration, and decreases the impact property, then finally causes creep damage and fracture. Accordingly, it is suggested to upgrade the material grade of the medium pressure control valve fastening bolt and the corresponding gasket.
    Analysis on formation mechanism of spot defects on surface of electrogalvanized steel sheet
    Chen Yingying , Yan Fei
    2021, 46(10):  267-269.  doi:10.13251/j.issn.0254-6051.2021.10.049
    Abstract ( 72 )   PDF (636KB) ( 20 )  
    Microstructure and composition of a kind of spot-like defects on the surface of electrogalvanized steel sheet were analyzed by SEM, and its formation mechanism was discussed. The results show that the surface defects of the electrogaivanized steel sheet are locally rolled, and a large number of small black spots are adhered to the defect parts. The composition of the defects is mainly composed of C, O, Mg, S, Ca, Si, Mn, etc. Through production line investigation and further tracing of characteristic elements, it is found that the defects come from the base sheet. The root cause of the defects is the foreign matters adhering to the base sheet surface, which come from their accumulation in the water quenching tank and the inner wall of the water pipe connected with it. The surface quality of the base sheet can be controlled by cleaning the inner wall of water quenching tank and connected water pipe, so that the defects are eliminated.
    Crack failure cause analysis of diesel engine crankshaft
    Zhang Huaiqing, Yu Jinwen, Wang Qingquan, Fang Guijing, Guan Huihuan, Wang Yiming, Wei Cong
    2021, 46(10):  270-274.  doi:10.13251/j.issn.0254-6051.2021.10.050
    Abstract ( 56 )   PDF (639KB) ( 26 )  
    Failure reason of cracks in a QT900-2 nodular cast iron diesel engine crankshaft was analyzed by means of chemical composition analysis, microstructure analysis, macro and micro morphology analysis of the cracks, hardened layer depth measurement and mechanical performance testing. The results show that the diesel engine is scratched first, resulting in the secondary quenching on the surface and re-tempering in the subsurface layer of the crankshaft, causing a large internal stress on the surface of the journal, which is the main reason for the induced crack failure, and the existence of carbides and looseness at surface layer is the internal factor of crack formation.