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  • PROCESS RESEARCH
    Effect of solution temperature on mechanical properties and corrosion resistance of super duplex stainless steel 2507
    Gu Guochao, Li Ruifen, Xin Zhenmin, Xiang Lixin, Xu Wenhua, Lü Yupeng
    2022, 47(6):  1-6.  doi:10.13251/j.issn.0254-6051.2022.06.001
    Abstract ( 181 )   PDF (3745KB) ( 326 )  
    Effect of solution temperature on microstructure, mechanical properties and corrosion resistance of 2507 super duplex stainless steel was investigated by using optical microscope, scanning electron microscopy, XRD, tensile test and electrochemical analysis. The thermodynamic equilibrium phase diagram of the 2507 duplex stainless steel was calculated by Thermo-Calc thermodynamic software and compared with the test results. The results show that σ phase can be eliminated by solution treatment at temperatures higher than 1050 ℃. With the increase of solution temperature, the content of ferrite phase increases, the content of austenite phase decreases, and the volume fraction ratio of α/γ increases. The duplex stainless steel has better comprehensive mechanical properties after solution treatment at 1050-1100 ℃ for 30 min and water cooling, of which the yield strength, tensile strength and elongation are more than 600 MPa, 840 MPa and 35%, respectively. The duplex stainless steel can obtain better corrosion resistance after solution treatment at 1050 ℃ for 30 min.
    Effects of solution and aging treatments on mechanical properties and microstructure of Al-Cu-Mn-Er cast alloy
    Wu Yang, Huang Hui, Shi Wei, Wen Shengping, Wu Xiaolan, Rong Li, Wei Wu
    2022, 47(6):  7-12.  doi:10.13251/j.issn.0254-6051.2022.06.002
    Abstract ( 156 )   PDF (4148KB) ( 170 )  
    Effects of different solution and aging treatments on microstructure and mechanical properties of Al-Cu-Mn-Er alloy were studied by optical microscope, scanning electron microscope, XRD, DSC test, hardness test and tensile test. The results show that the optimal process of solution and aging treatments of the as-cast alloy is solution treating at 540 ℃ for 12 h and aging at 185 ℃ for 6 h, under which there is no overheating or "overburning" phenomena, the solute atoms are fully diffused, and a large amount of residual phases generated during the casting process are redissolved into the matrix. Meanwhile, the alloy has the highest hardness value of 142.28 HV0.1, tensile strength of 370.37 MPa, yield strength of 300.34 MPa, and elongation of 6.50%.
    Thermal process matching of single crystal double casting guide vane of DD5 alloy
    Jia Xinyun, Chen Shengping, Zong Cui, Tan Yongning, Huang Zhaohui
    2022, 47(6):  13-18.  doi:10.13251/j.issn.0254-6051.2022.06.003
    Abstract ( 112 )   PDF (3606KB) ( 67 )  
    Thermal process sequence of single crystal double casting guide vane of DD5 alloy on microstructure and properties was studied. The results show that the microstructure of the DD5 alloy after standard heat treatment is composed of carbides, residual eutectic and regular γ' phase. Compared with that after standard heat treatment, the morphology and size of carbides welded before or after aging have no obvious change, while the size of γ' phase and γ matrix channel are not evenly distributed. The cubic shape degree of γ' phase decreases, the serrated γ'/γ phase interface can be seen, and the fine secondary γ' phase is precipitated in the γ matrix channel. Compared with that welding after aging, when welding before aging, the serrated degree of γ'/γ phase interface is slight and cubic shape degree of γ' phase is better, and the tensile properties at 870 ℃, stress rupture properties at 980 ℃/250 MPa and 1093 ℃/158 MPa are not influenced obviously. Considering the process arrangement of vane production, the optimum process sequence of the DD5 alloy guide vane is standard heat treatment first and then welding.
    Effect of warm rolling temperature on microstructure and mechanical properties of medium carbon steel
    Tian Yaqiang, Zhao Zhihao, Yang Zixuan, Xu Haiwei, Han Yun, Zheng Xiaoping, Li Hongbin, Chen Liansheng
    2022, 47(6):  19-24.  doi:10.13251/j.issn.0254-6051.2022.06.004
    Abstract ( 105 )   PDF (4003KB) ( 45 )  
    Effect of 650-730 ℃ warm rolling temperature on microstructure evolution and mechanical properties of a 0.46%C medium carbon steel was studied by means of TEM, SEM, room temperature tensile test. The results show that after 90% rolling deformation, a large amount of intragranular dislocations are introduced in the ferrite of the tested steel, the cementite lamella produces stress concentration, which causes the lamellar cementite to bend, kink, and shear into granules. With the decrease of warm rolling temperature, the dislocation multiplication is obvious, the spheroidization rate of cementite increases and the distribution becomes more and more uniform, the strength and the elongation increase overall. At the warm rolling temperature of 650 ℃, the cementite is greatly spheroidized, the tensile strength is 877 MPa, and the elongation after fracture is 16.0%, the tested steel has the best comprehensive mechanical properties. The tensile fracture results show that with the decrease of warm rolling temperature, the fracture mechanism of the tested steel changes from ductile and brittle mixed fracture to ductile fracture, and the ductility increases.
    Optimization of heat treatment process for F/M steel cladding pipes
    Jiang Mingzhong, Zhao Yong, Pan Qianfu, Wu Yu, Wang Xinmin, Jiang Wenlong
    2022, 47(6):  25-32.  doi:10.13251/j.issn.0254-6051.2022.06.005
    Abstract ( 102 )   PDF (9663KB) ( 31 )  
    Effects of different heat treatment processes on microstructure and room temperature mechanical properties of Fe-12Cr-1.5W-0.2V-0.15Ta F/M steel cladding pipes were studied by normalizing at 980-1150 ℃ and tempering at 600-730 ℃. The results show that, after normalizing at different temperatures, the microstructure of F/M steel cladding pipes is lath martensite, while with the increase of normalizing temperature, the coarse carbide particles will gradually dissolved into the matrix, and the grain size of the prior austenite coarsens from 40 μm at 1050 ℃ to 80 μm at 1150 ℃. After tempering at different temperatures, fine carbide nanoparticles precipitate in the martensite matrix, and the amount of carbide particles increases significantly with the increase of tempering temperature, but the size of carbide particles does not change obviously. After normalizing at 1100 ℃ for 60 min and tempering at 650 ℃ for 90 min, the cladding pipes have good microstructure and mechanical properties, original austenite grains do not grow obviously, and the average grain size of martensite laths is about 6.0 μm, the ratio of small angle grain boundary is 59.6%, the nano-phase precipitate along the original austenite grain boundary, and a large number of nano-phases precipitate at the interface of intragranular martensite, at this time, the pipes show good strong plastic matching, the tensile strength is 1024 MPa, the yield strength is 849 MPa and the elongation is 17.3%.
    Effect of holding time on inclusions in U75V heavy rail steel
    Fan Zhiming, Yang Jichun, Zhang Ying, Li Xiangchuan, Zhu Jun
    2022, 47(6):  33-38.  doi:10.13251/j.issn.0254-6051.2022.06.006
    Abstract ( 66 )   PDF (3177KB) ( 40 )  
    U75V heavy rail steel was smelted in a vacuum induction furnace, then the steel specimens were heated to 1100 ℃ in a box-type resistance furnace and held for 30, 60, and 90 min respectively, and the inclusions were analyzed by scanning electron microscope. The results show that in the steel without heat treatment there are three main types of inclusions MnS, Al2O3 and MnS-Al2O3. The elongated MnS inclusions tend to split with the prolongation of holding time. The average circularity of the MnS inclusions is 1.86 when the holding time is 90 min, and the circularity decreases by 1.52 compared with the specimen without heat treatment. When held for 30 and 60 min, the morphology and size of the Al2O3 inclusions change little, but the quantity decreases. When held for 90 min, the sharp edges and corners of some Al2O3 inclusions are obtused, and the circularity slightly decreases. After heated at 1100 ℃, the number of composite inclusions increases. With the extension of holding time, the distributions of MnS and Al2O3 in the MnS-Al2O3 inclusions change, and the Al2O3 in the outer layer tends to move inward. The Al2O3 is enriched inside the inclusions, and the content of Al2O3 in the outer coating is extremely low. The MnS-Al2O3 inclusions gradually form composite inclusions with Al2O3 as the core and MnS as outer coating, thereby reducing the damage to the steel matrix.
    Effect of rolling deformation on microstructure and properties of Mg-Zn-Y alloy
    Zhai Chuantian, Sun Youping, He Jiangmei, Meng Xiangchao, Wan Siyu
    2022, 47(6):  39-45.  doi:10.13251/j.issn.0254-6051.2022.06.007
    Abstract ( 74 )   PDF (4531KB) ( 36 )  
    Effect of different rolling deformation on microstructure, mechanical properties and damping properties of Mg-4Zn-2Y alloy and Mg-4Zn-4Y alloy was investigated by means of optical microscope, dynamic mechanical thermal analyzer, X-ray diffraction and scanning electron microscope. The experimental results show that the lamellar LPSO phase appears in the alloy after rolling. With the increase of rolling deformation, the change of damping property Q-10 that is independent of strain amplitude is basically the same, and the damping property Q-1h related to the strain amplitude decreases with the increase of rolling deformation. The damping mechanism of the Mg-4Zn-2Y alloy and Mg-4Zn-4Y alloy are the dislocation damping. With the increase of rolling deformation, the number of dimples in the fracture surface of the alloy increases, the dissociation surface decreases, thus the fracture mode changes from brittle fracture to ductile fracture. Under the same rolling deformation, the tensile strength of the Mg-4Zn-4Y alloy is higher than that of the Mg-4Zn-2Y alloy, but the damping capacity is lower than that of Mg-4Zn-2Y alloy.
    Effect of deep cryogenic treatment on microstructure and mechanical properties of TC4 titanium alloy during annealing
    Li Xiaochen, Wang Shiying, Hua Tianyu, Chen Zhidong
    2022, 47(6):  46-53.  doi:10.13251/j.issn.0254-6051.2022.06.008
    Abstract ( 85 )   PDF (5071KB) ( 44 )  
    TC4 dual-phase titanium alloy with 10%, 20% and 40% compression was subjected to 12 h cryogenic treatment at -196 ℃ by liquid nitrogen and then annealed at 500 ℃ for different time. The grain sizes were characterized by optical microscope, the volume fraction of α and β phases was measured by scanning electron microscope, the hardness and tensile properties were tested by Vickers hardness tester and electronic universal testing machine, respectively. Through the change of grain size and the structure of α phase and β phase, the changes of the hardness and tensile properties were explained. The results show that the grain size decreases first and then increases, and the volume fraction of β phase gradually decreases and transforms into α phase with the annealing time increases. When annealed for 1 h, the grain size decreases slightly, which is related to the smaller grains produced during the annealing process, and the continued cryogenic treatment after rolling makes more deformable, and more small grains are easily produced during the annealing process which is more conducive to promote the transition from β phase to α phase. So the alloy has excellent comprehensive mechanical properties when annealed at 500 ℃ for 1 h. When the annealing time exceeds 1 h, the volume fraction of α and β phases does not change significantly, and with the extension of the annealing time, the grain coarsening phenomenon is more obvious. Therefore, the strength and hardness of the material are lower than that when annealed for 1 h. It is concluded that annealing at 500 ℃ for 1 h is an ideal processing for the cold rolled TC4 titanium alloy after deep cryogenic treatment for 12 h, under which can obtain preferable comprehensive mechanical properties.
    Effect of partitioning temperature on microstructure and mechanical properties of 0.2C-2.96Mn-1.73Si steel
    Feng Shuming, Wan Decheng, Hu Jinpeng, Li Jie
    2022, 47(6):  54-58.  doi:10.13251/j.issn.0254-6051.2022.06.009
    Abstract ( 109 )   PDF (2071KB) ( 29 )  
    Multiphase structure composed of ultrafine ferrite, martensite and retained austenite was obtained in 0.2C-2.96Mn-1.73Si steel by intercritical heating quenching and partitioning (IQP) heat treatment. The effect of partitioning temperature on microstructure and mechanical properties of the tested steel was researched by means of SEM, XRD and tensile testing machine. The results show that with the increase of partitioning temperature, the tensile strength of the tested steel gradually decreases, and the yield strength and elongation first increase and then decrease. The content of retained austenite in the steel first increases and then decreases with the increase of partitioning temperature. The volume fraction of retained austenite is the highest when the partitioning temperature is 400 ℃, the tested steel has the highest uniform deformability because lasting work hardening can be provided by TRIP effect, and displays excellent comprehensive mechanical properties with ultimate tensile strength of 1444 MPa, elongation of 20.13% and the product of strength and elongation of 29 GPa·%.
    Effect of solution treatment on microstructure and properties of Cr23Ni7Mo2Cu0.6 duplex stainless steel
    Chen Jiajun, Zhu Zhiyuan, Li Jianqiang, Wang Shouqian
    2022, 47(6):  59-63.  doi:10.13251/j.issn.0254-6051.2022.06.010
    Abstract ( 100 )   PDF (3748KB) ( 35 )  
    Effect of solution treatment on microstructure and properties of Cr23Ni7Mo2Cu0.6 duplex stainless steel was studied by XSL-4-12 box heat treatment furnace, Zeiss metallographic microscope, HRS-150 digital Rockwell hardness tester and tensile test machine. The results show that the content of ferrite increases with the increase of solution temperature, and the area ratio of ferrite to austenite reaches 1∶1 between 930 ℃ and 960 ℃. The content of σ phase decreases with the increase of solution temperature, only a small amount of σ phase exists at phase boundary at 960 ℃, and the uneven distribution of austenite phase due to forging at 1020 ℃ is also improved. The hardness and tensile strength of the alloy decrease at first and then increase with the increase of solution temperature, reaching the minimum values of 94.4 HRB at 1020 ℃ and 547 MPa at 1050 ℃, respectively. The elongation increases at first and then decreases with the increase of solution temperature, reaching a peak value of 41.5% at 990 ℃. Considering the effects of hardness, plasticity, toughness and microstructure uniformity of the material on formability of the material during drawing and deformation of the steel wire, the optimal solution temperature of the Cr23Ni7Mo2Cu0.6 duplex stainless steel is 1020 ℃.
    Effect of pre-stretching amount on microstructure and properties of 2050 Al-Li alloy
    Yu Juan, Feng Zhaohui, Zhao Weiyi, Yao Yong, You Wen
    2022, 47(6):  64-68.  doi:10.13251/j.issn.0254-6051.2022.06.011
    Abstract ( 85 )   PDF (2672KB) ( 122 )  
    Effect of pre-stretching processing after solution treatment on tensile properties, intergranular corrosion resistance and microstructure of the artificial aged 2050 Al-Li alloy were studied by means of tensile test, intergranular corrosion test and transmission electron microscope(TEM). The results show that the yield strength and ultimate tensile strength at L and LT directions of the 2050 Al-Li alloy increase gradually with the increase of pre-stretching amount, and tend to be stable when the pre-stretching amount is over 4.0%, elongation decreases rapidly at first and then finally keep stable. With the increase of pre-stretching amount, the corrosion morphology changes from intergranular corrosion to pitting, and the pitting depth decreases gradually. The pre-stretching processing promotes the T1 phase precipitation in the grains and makes its distribution more dispersive and homogeneous, while the precipitation at grain boundary is restrained during the artificial aging, which consequently improves the tensile strength and the intergranular corrosion resistance. When the pre-stretching amount is 5.0%, the optimum tensile strength and intergranular corrosion resistance is obtained for the alloy.
    Effect of cooling rate on microstructure and mechanical properties of Cr5 steel for backup roll
    Bai Xinghong, Zhao Xichun, Zhao Deli, Wang Dapeng, Nan Yujing
    2022, 47(6):  69-71.  doi:10.13251/j.issn.0254-6051.2022.06.012
    Abstract ( 77 )   PDF (2079KB) ( 40 )  
    Effect of cooling rate on microstructure and mechanical properties of Cr5 steel for backup roll was investigated by means of optical microscopy, Vickers hardness tester, tensile tester and Charpy pendulum impact tester. The results show that with the decrease of cooling rate, the pearlite content increases, the strength and hardness increase, the plasticity and toughness are similar. As the cooling rate reaches above 3 ℃/min, the volume fraction of pearlite in the microstructure is less than 30%, tensile strength ≥1025 MPa, yield strength ≥750 MPa, hardness ≥45 HS, impact absorbed energy ≥40 J. Production test result shows that heat treatment with strong air cooling can make the mechanical properties of the roll neck surface to a certain depth reach the effect of oil cooling, which fully meets the mechanical properties of the backup roll neck.
    Effect of vacuum annealing on coercivity and corrosion resistance of Al-coated NdFeB magnets
    Hu Fangqin, Shi Fengkai, Zhang Qingke, Zhao Yu, Xiao Tao
    2022, 47(6):  72-77.  doi:10.13251/j.issn.0254-6051.2022.06.013
    Abstract ( 63 )   PDF (3040KB) ( 38 )  
    Al coatings were deposited on the surface of sintered NdFeB by using arc ion plating and then subjected to vacuum annealing. Effect of different annealing processes on microstructure, magnetic properties and corrosion resistance of Al/NdFeB was investigated by means of scanning electron microscopy, permanent magnet material measurement system, electrochemical workstation and salt spray test chamber. The results show that the coercivity first increases and then decreases with the increase of annealing temperature, the highest coercivity of 22.41 kOe is obtained when annealed at 550 ℃ for 1 h, increasing by 7.6%, while the corrosion resistance decreases compared with the untreated magnet. With the increase of annealing time, the coercivity first decreases and then increases. When annealed at 550 ℃ for 5 min, the coercivity is 22.16 kOe, and the self-corrosion current density is 1-2 orders of magnitude lower than that of the matrix NdFeB. The specimens annealed at 550 ℃ for 5 min have higher coercivity and better corrosion resistance.
    Effect of heat treatment on low temperature brazing of copper and aluminum
    Xu Xinquan, Fang Zhou, Liu Xinkuan, Wang Ziyan
    2022, 47(6):  78-84.  doi:10.13251/j.issn.0254-6051.2022.06.014
    Abstract ( 67 )   PDF (2947KB) ( 24 )  
    Effect of heat treatment temperature and holding time on strength of Al/Sn-Bi/Cu joints brazed at low temperature was studied. The microstructure of the joint interface and the fracture surface morphology were analyzed by means of optical microscope and scanning electron microscopy. The results show that with the increase of heat treatment temperature, the shear strength of welded parts shows an increasing trend. With the increase of heat treatment time, the shear strength of Al/Sn-Bi/Cu joints increases first and then decreases. During brazing, copper and aluminum elements enter the brazing layer, mainly exist in the form of Cu-Al solid solution, and accumulate with the prolongation of heat treatment time. Heat treatment makes the coarse and brittle Sn-Bi eutectic structure in the brazing seam finer and reduces the coverage area to increase the strength of the joint. The aggregation and growth of Cu-Al solid solution decrease the strength of the joint.
    Effect of deformation on microstructure and properties of low-carbon microalloyed steel
    Yan Xiang, Li Defa, Guan Jisheng, Yang Zhizheng
    2022, 47(6):  85-88.  doi:10.13251/j.issn.0254-6051.2022.06.015
    Abstract ( 49 )   PDF (2089KB) ( 23 )  
    Effect of online quenching and tempering process and conventional quenching and tempering process on microstructure and properties of a low-carbon microalloyed hull structural steel was comparatively investigated, and the strengthening and toughening mechanisms were discussed. The results show that compared with conventional quenching and tempering process, when the online quenching and tempering process is adopted, the deformation structure generated by the controlled rolling improves the phase transformation driving force and nucleation rate during the online quenching and cooling process, and fine bainitic lath is obtained. It is beneficial to the formation of nano-scale precipitates and high-density dislocations, thereby improving the strength of the low-carbon microalloyed steel and ensuring good low-temperature toughness. The overall performance (Rp0.2=599 MPa,KV2(-40 ℃)=272 J/cm2,A=24.5%) meets the requirements of the 590 MPa class hull steel.
    Effect of solution treatment on microstructure of carbide in K447A superalloy
    Wu Wenjin, Li Xianghui, Li Xuechen, Chen Jingyang, Tang Xin
    2022, 47(6):  89-92.  doi:10.13251/j.issn.0254-6051.2022.06.016
    Abstract ( 190 )   PDF (2512KB) ( 24 )  
    Microstructure and precipitation behavior of carbides in K447A alloy under different solution treatments were analyzed by scanning electron microscopy(SEM). The results show that primary carbides in the as-cast K447A alloy are of the MC type, in the form of blocks, skeletons and Chinese characters, and are distributed between dendrites and grain boundaries. After heat treatment, primary MC carbides are broken, and a layer of γ' phase coating layer is formed on the surface. During heat treatment, the composition of the primary MC carbides changes, and the primary carbides such as TaC, TiC, and WC are decomposed, and HfC is least affected. After heat treatment, a large number of fine and dispersed granular secondary MC carbides dominated by HfC precipitate in the interdendritic and residual eutectic regions near the primary MC carbides. When solution-treated at 1185 ℃ for 2 h and aged at 870 ℃ for 20 h, the amount of secondary MC precipitation is the largest.
    Effect of solution treatment on microstructure and hardness of TC4 alloy
    Han Haoyuan, Yang Tao, Qiu Juan, Yang Gang, Yu Wanhua, Zhai Yuewen, Zhou Leyu
    2022, 47(6):  93-97.  doi:10.13251/j.issn.0254-6051.2022.06.017
    Abstract ( 111 )   PDF (4050KB) ( 32 )  
    TC4 alloy was subjected to different solution treatments, and effects of solution temperature, holding time and cooling method on microstructure and hardness of the alloy were studied. The results show that with the increase of solution temperature, microstructure of the TC4 alloy transforms from equiaxed structure to dual-state structure to full martensite structure, and the hardness gradually increases. When the high temperature equilibrium state is reached, the extension of holding time has little effect on microstructure and hardness of the TC4 alloy. When the solution temperature is 925 ℃ and 975 ℃, respectively, as the cooling rate decreases, the α phase diffuses and grows during the cooling process. The β transformation structure changes from α' martensite to secondary α+β lamella structure, and the hardness respectively reduces from 359-389 HV0.2 under water-cooling condition to 318-327 HV0.2 under air-cooling condition. After furnace cooling, a fully equiaxed structure is obtained, the hardness is lower, about 300 HV0.2.
    Effect of quenching oil temperature on microstructure and properties of 40CrMnMo steel drill pipe
    Zhong Bin, Chen Yiqing, Li Lin, Gao Peng, San Hongyu, Ai Fangfang, Tian Xiumei
    2022, 47(6):  98-102.  doi:10.13251/j.issn.0254-6051.2022.06.018
    Abstract ( 93 )   PDF (3348KB) ( 29 )  
    Effect of quenching oil temperature on microstructure and cross-section hardness of the quenched 40CrMnMo steel drill pipe, the mechanical properties and the impact absorbed energy of the tempered state was studied by means of hardness test, microstructure observation, tensile property and impact property test. The results show that the quenching oil temperature has a significant effect on microstructure and hardness of the drill pipe, and further affects the mechanical properties, yield ratio and impact absorbed energy after tempering. With the increase of quenching oil temperature, the cooling rate increases firstly and then decreases, the optimum medium temperature is 30-50 ℃, at which the specimen has good hardenability, uniform microstructure and fine grains. After tempering, the specimen has good mechanical properties, high yield ratio, high impact property and good toughness, and good comprehensive property.
    Effect of forming speed on mechanical properties and fracture morphology of 7050 aluminum alloy forgings
    Zhao Tiansheng, Fang Yu, Sun Yubin
    2022, 47(6):  103-106.  doi:10.13251/j.issn.0254-6051.2022.06.019
    Abstract ( 84 )   PDF (2486KB) ( 36 )  
    Effect of forming speed on microstructure, mechanical properties and fracture morphology of the 7050 aluminum alloy forgings was studied by metallographic microscope (OM), scanning electron microscope (SEM) and room temperature tensile test. The results show that with the increase of forming speed, the sectional morphology of grains of the alloy forgings gradually changes from round to elongated, with local coarsening. The tensile strength and yield strength increase first and then decrease with the increase of forming speed, and the elongation gradually decreases with the increase of forming speed. When the forming speed is 2 mm/s, the tensile strength and yield strength reach 608 MPa and 560 MPa respectively, and the elongation is 12.7%. When the forming speed is 2 mm/s and 8 mm/s, respectively, the fracture modes of the tensile specimens are mainly transgranular fracture, accompanied by a small amount of second-phase coarse particles and intergranular fracture. With the decrease of forming speed, the dimples increase in number and gradually in depth. The optimal selection of the forming speed for the hot forging die in real production is 2-8 mm/s.
    Effect of solution treatment on high temperature mechanical properties of austenitic stainless steel 07Cr18Ni11Nb
    Shu Wei, Wang Liying
    2022, 47(6):  107-110.  doi:10.13251/j.issn.0254-6051.2022.06.020
    Abstract ( 106 )   PDF (3312KB) ( 30 )  
    Effect of solution treatment on high temperature mechanical properties of austenitic stainless steel 07Cr18Ni11Nb was investigated. The results show that the high temperature yield strength at 500 ℃ and 600 ℃ decreases with the increase of solution treatment temperature, but the high temperature tensile strength at 500 ℃ and 600 ℃ has no obvious change. When the solution treatment temperature is ≤1100 ℃, the austenite grain size remains basically unchanged. When the solution treatment temperature is more than 1100 ℃, the austenite grain size grows gradually, and when the solution treatment temperature reaches 1200 ℃, the austenite grain size increases to over 100 μm. The austenite grain boundary is still an important factor to the strengthening effect when the tensile test is under 600 ℃. The smaller the grain size, the higher the yield strength at high temperature.
    Effect of solution cooling method on mechanical properties of GH4220 alloy bolts
    Fan Kailun, Song Wenjun, Dai Aili, Yu Chuankui, Pei Lieyong, Liu Yongde, Liu Wencheng
    2022, 47(6):  111-114.  doi:10.13251/j.issn.0254-6051.2022.06.021
    Abstract ( 63 )   PDF (1073KB) ( 23 )  
    Cooling method of GH4220 alloy bolts in the cooling stage of solution treatment at 1220 ℃ was changed from the air cooling of the standard heat treatment system to slow cooling (cooling to 1100 ℃ within 24 min and holding for 1 min, and then air cooling), the grain boundary morphology and mechanical properties of the alloy were observed by means of SEM and computer-controlled electronic universal testing machine. The results show that compared with the standard heat treatment system, the grain boundary after the slow cooling treatment has obvious zigzag characteristics, and the grain boundary changes from a straight grain boundary to a curved grain boundary. The room temperature (950 ℃) tensile strength is increased by 13.8% from 1004 MPa under the standard heat treatment system to 1143 MPa. Similarly, the high temperature tensile strength is increased by 11.3% from 478 MPa under the standard heat treatment system to 532 MPa. The high temperature (940 ℃) stress lasting fracture time increases significantly, from 38.2 h under the standard heat treatment system to 51.7 h, which rises by 35%.
    Effect of annealing temperature on microstructure and properties of T4 tinplate
    Wang Bin, Wei Baomin
    2022, 47(6):  115-118.  doi:10.13251/j.issn.0254-6051.2022.06.022
    Abstract ( 85 )   PDF (2361KB) ( 41 )  
    Taking 0.19 mm T4 cold-rolled tinplate as the research object, annealing and over-aging annealing simulation tests were carried out by using a Gleeble-3500 thermal simulator, and the effect of annealing temperature on microstructure and properties of the T4 tinplate was analyzed. The results show that the recrystallization start temperature of the tested tinplate is about 575 ℃, and the recrystallization end temperature is 640-670 ℃. When the over-aging annealing temperature is 560 ℃, the tested steel is in the initial stage of recrystallization. When the over-aging annealing temperature is higher than 575 ℃, the recrystallization degree becomes more sufficient with the increase of annealing temperature. The recrystallization nucleation is accomplished when the over-aging annealing temperature reaches 640 ℃, and the distortion-free new grains are gradually formed. Besides that, the hardness of the annealed T4 tinplate decreases with the increasing of over-aging annealing temperature, the hardness decreases significantly (by 49 HV) from 540 ℃ to 640 ℃ due to recrystallization but only by 9 HV from 640 ℃ to 670 ℃.
    Effect of high pressure heat treatment on microstructure and hardness of 35CrMo steel
    Yang Xiaoyu, Li Xiaoxiao, Tong Jing, Hu Shukai
    2022, 47(6):  119-122.  doi:10.13251/j.issn.0254-6051.2022.06.023
    Abstract ( 119 )   PDF (3385KB) ( 21 )  
    Microstructure and hardness of 35CrMo steel treated by high pressure heat treatment combined with high temperature tempering were analyzed and tested by metallographic microscope, scanning electron microscope, transmission electron microscope and hardness tester, and compared with the traditional quenching and tempering process. The results show that after high pressure heat treatment and high temperature tempering, 35CrMo steel can precipitate dispersed granular carbides, the hardness of the 35CrMo steel is effectively improved. After 3 GPa pressure, high pressure heat treatment at 860 ℃ for 20 min and tempering at 550 ℃ for 60 min, the hardness of the 35CrMo steel is 45 HRC, which is 7.14% higher than that treated by the traditional quenching and tempering with the same process.
    Effect of simulated normalizing temperature on microstructure and properties of Q355E steel forgings
    He Chunjing, Pang Qinghai, Li Jie, Yin Litao, Nie Xinlin
    2022, 47(6):  123-127.  doi:10.13251/j.issn.0254-6051.2022.06.024
    Abstract ( 89 )   PDF (2996KB) ( 26 )  
    Simulated normalizing treatment of the center material of a 300 mm×300 mm section Q355E steel forging was carried out by using a simulated program-controlled heat treatment furnace. Effect of simulated normalizing temperature on the microstructure and properties of Q355E steel forgms for thick section wind-electron flange was studied by optical microscope, scanning electron microscope, tensile and impact testing machines. The results show that with the increase of simulated normalizing temperature in range of 780-900 ℃ and then tempered at 580 ℃, the impact absorbed energy at -50 ℃ of the specimens increases first and then decreases, and the average size of ferrite decreases from 14.73 μm to 12.07 μm and then increases to 15.02 μm, and the average size of pearlite increases from 3.69 μm to 10.51 μm. When the simulated heat treatment temperature is 820 ℃ and 840 ℃, the microstructure of ferrite and pearlite is uniform and fine, and pearlite is distributed in strip and near equiaxed shape, the impact absorbed energy at -50 ℃ is 183.8 J to 211.1 J, and the shear section ratio of the specimens is more than 50%. For 300 mm×300 mm section Q355E steel forgings, normalizing treatment at 820-840 ℃ can be selected to obtain excellent and stable low temperature impact absorbed energy.
    Effect of quenching process on microstructure and properties of powder metallurgy martensitic stainless steel
    Liu Shaozun, Che Hongyan, Li Ou, Liang Chen, Gui Shun, Wang Tiejun
    2022, 47(6):  128-132.  doi:10.13251/j.issn.0254-6051.2022.06.025
    Abstract ( 81 )   PDF (2875KB) ( 33 )  
    Effect of quenching process on microstructure and mechanical properties of a powder metallurgy ultra-high-carbon stainless steel was studied. After quenching between 900-1200 ℃ and then tempering at 200 ℃, the types of carbide of high carbon and chromium powder metallurgical stainless steel are mainly M7C3 and a small portion of MC, with the increase of quenching temperature, the solid solution carbon content in martensite increases, leading to an increase of the hardness and flexural strength. After quenching at 1150 ℃ and the following low-temperature tempering, the mechanical properties reach the best, with hardness of 59 HRC, impact absorbed energy of 18.9 J, flexural strength of 3079 MPa; the carbides are uniformly distributed in the matrix, of which the average size and volume fraction of M7C3 and MC phase are about 2 μm with 17% and 0.5 μm with 2%, respectively. The volume fraction of retained austenite is 35% after quenching at 1200 ℃, resulting in a decrease in hardness.
    Influence of quenching cooling process on microstructure and properties of quenched and tempered F460 steel thick plate
    Feng Zan, Tuo Chende, Ouyang Fan
    2022, 47(6):  133-137.  doi:10.13251/j.issn.0254-6051.2022.06.026
    Abstract ( 98 )   PDF (3665KB) ( 30 )  
    Microstructure and properties of 120 mm thick F460 steel quenched and tempered plate with the same quenching and tempering temperature and different quenching cooling rates were compared to find the best heat treatment process of the tested steel. The steel plate quenched with the 2 ℃/s cooling rate has the highest strength after tempering, but the impact property is poor. After rationally reducing the quenching cooling rate, the strength of the steel plate after tempering decreases to a certain extent, but the impact toughness is significantly improved. Further reducing the quenching cooling rate further reduces the strength of the steel plate after tempering, but the improvement of impact property is limited. The microstructure analysis shows that when the steel plate is quenched at 2 ℃/s cooling rate, the microstructure after tempering is ferrite and bainite, and bainite is mainly in the microstructure. When the cooling rate is reduced, the structure of the steel plate after tempering is ferrite and degenerate pearlite. The increase of ferrite content is conducive to the improvement of toughness of the steel plate. The pearlite structure formed after tempering from retained austenite is relatively small, which can effectively ensure the strength of the steel plate. By analyzing the continuous cooling transformation curve of the steel plate, the steel plate begins to undergo ferrite transformation firstly and solute elements migrate to austenite during cooling. When the cooling rate of steel plate is fast, the carbides in ferrite migrate less, and austenite transforms into martensite or bainite at lower temperature. When the cooling rate of steel plate is slow, carbides migrate into austenite, which improves the stability of austenite and retains it to room temperature to form retained austenite. Retained austenite is transformed into pearlite in the subsequent high-temperature tempering process. The ferrite structure formed by massive transformation and the fine pearlite formed during tempering are conducive to the strength toughness matching of the steel plate.
    Effect of HIP temperature on microstructure and mechanical properties of TC4 titanium alloy prepared by SLM
    Lü Zhoujin, Li Haofeng, Che Lida, Wu Zhanfang, Zhai Yiduo, Cui Xiaomin, Li Xiangyang
    2022, 47(6):  138-142.  doi:10.13251/j.issn.0254-6051.2022.06.027
    Abstract ( 75 )   PDF (3408KB) ( 28 )  
    Using optical microscope (OM), scanning electron microscope (SEM) and electronic universal testing machine, the effect of hot isostatic pressing (HIP) temperature on the microstructure and mechanical properties of the TC4 titanium alloy formed by laser selective melting (SLM) was investigated. The results show that the cross section microstructure of the TC4 titanium alloy by SLM is composed of equiaxed primary β grains, the longitudinal section microstructure is composed of columnar primary β grains with epitaxial growth. The inside of the grains is dominated by acicular α' martensite phases with different orientations, nano-dot β phase nucleates and grows between the primary martensite. The structure of the TC4 titanium alloy is composed of α phase and β phase when HIP is performed at temperature of the α+β phase region. With the increase of HIP temperature, the lath α-phase coarsens into short rod, the content of β phase increases and coarsens, the tensile strength and yield strength of TC4 shows a decreasing trend, section shrinkage also shows a decreasing trend. When HIP at 910 ℃ with a pressure of 110 MPa for 2 h, the TC4 titanium alloy obtains the best matching of strength and toughness.
    Application of vacuum low pressure carburizing heat treatment on heavy duty gears
    Zhu Pengkai, Xu Shen, Chen Xuyang, Zhang Xiaotian, Li Yang
    2022, 47(6):  143-147.  doi:10.13251/j.issn.0254-6051.2022.06.028
    Abstract ( 79 )   PDF (2454KB) ( 26 )  
    The changes of microstructure and properties of 20CrMnTiH steel synchronizer gear hub after vacuum low pressure carburizing heat treatment were studied and compared with that by atmosphere carburizing heat treatment process. The results show that there is almost no intergranular oxidation and non-martensitic structure after vacuum carburizing heat treatment, and the control of intergranular oxidation is much better than that of atmosphere carburizing heat treatment. High pressure gas quenching is superior to oil quenching in heat treatment distortion control of the gear hub.
    MICROSTRUCTURE AND PROPERTIES
    Thermal deformation behavior and mechanical properties of low Ni type LNG steel
    Dang Yuzhen, Cai Xiaohui, Chen Qiyuan, Liu Zhenyu
    2022, 47(6):  148-154.  doi:10.13251/j.issn.0254-6051.2022.06.029
    Abstract ( 80 )   PDF (3092KB) ( 23 )  
    High-temperature austenite dynamic recrystallization and static recrystallization behaviors of a low Ni type LNG steel were studied through single-pass and double-pass compression tests, and through hot rolling tests under different rolling processes by two-stage controlled rolling and ultra-rapid cooling technologies, and then hot deformation behavior and mechanical properties of the low Ni type LNG steel were studied through thermal simulation and hot rolling test. The results show that dynamic recrystallization of austenite is easy to occur at high temperature (1000-1050 ℃) and low strain rate (0.1-0.5 s-1), the critical conditions for the occurrence of recrystallization are determined, and a dynamic recrystallization kinetic model is established. The static softening phenomenon of the tested steel is obvious and static recrystallization is easy to occur at higher temperature (800-1050 ℃) and longer pass interval (60 s). According to the results of the thermal simulation test, the hot rolling test process is formulated, and the recrystallization behavior of high temperature austenite is controlled by controlling the finishing rolling temperature and the finishing rolling temperature, so as to refine the grains and improve the impact properties of the low Ni steel. When the finishing rolling temperature is 920 ℃ and the finishing rolling temperature is 770 ℃, the impact absorbed energy at low temperature of the low Ni steel is 180.1 J, the gield strength is 595.1 MPa, and the tensile strength is 717.8 MPa.
    Precipitation characteristics of inhibitors in tin-oriented silicon steel during high temperature secondary recrystallization annealing
    Yang Lilin, Guo Xiaoyu, Zhang Niandi, Han Qiang, Li Tao
    2022, 47(6):  155-160.  doi:10.13251/j.issn.0254-6051.2022.06.030
    Abstract ( 73 )   PDF (2025KB) ( 20 )  
    The precipitation behavior of inhibitor during high temperature secondary recrystallization annealing of tin-oriented silicon steel was studied by means of transmission electron microscopy (TEM), and the inhibitory effect of the inhibitor on primary recrystallization was analyzed. The results show that in addition to the conventional AlN and MnS precipitates, the precipitates also have a small amount of Sn. AlN and MnS precipitates are the main inhibitors, which have strong inhibitory effect. The Sn has an auxiliary inhibition effect, controlling the size and quantity of AlN precipitates and contributing to the distribution of main inhibitors. These inhibitors begin to precipitate at 600-700 ℃, significantly grows at 900 ℃, and the average size reaches the maximum at 1020 ℃. With the increase of annealing temperature, the size of the inhibitor increases, while the volume fraction and distribution density increase first and then decrease. When the annealing temperature reaches 1000 ℃, the average size of precipitates is about 50.3 nm, the maximum volume fraction is about 3.81%, and the distribution density is about 5.9×1014 particle/cm3. The inhibition force is comprehensively determined according to the test and Zener factor. Zener factor increases with the increase of annealing temperature, reaches the maximum 139 at 900 ℃, and the distribution density of precipitates reaches the maximum of 8.9×1014 particle/cm3. At 1020 ℃, the Zener factor is almost zero and the secondary recrystallization process is completed.
    Continuous cooling transformation and phase transformation kinetics of 17-4PH stainless steel
    Wu Keyuan, Liu Yunpeng, Li Kongzhai, Xu Liangle
    2022, 47(6):  161-167.  doi:10.13251/j.issn.0254-6051.2022.06.031
    Abstract ( 69 )   PDF (3240KB) ( 36 )  
    Continuous cooling transformation behavior, austenite stabilization and martensite phase transformation kinetics of the 17-4PH stainless steel were investigated by means of thermal dilatometry method, X-Ray, SEM and TEM. The results show that only martensite transformation occurs at the cooling rate range of 0.05-5 ℃/s, and the Ms and Mf are 116 ℃ and 35 ℃, respectively. It is found that the austenite stabilization occurs at cooling rate range of 0.05-0.3 ℃/s, but this phenomenon disappears when the cooling rate ≥0.5 ℃/s. In the cooling rate range of 0.05-5 ℃/s, a small amount of NbC are precipitated in the tested steel. While when the cooling rate ≤0.08 ℃/s, a certain amount of dispersed nano-sized ε-Cu particles are precipitated in the tested steel. Based on experimental data, the Koistinen-Marburger equation is finally established to predict the martensite transformation kinetics of the 17-4PH stainless steel.
    Thermo-physical properties of tempered AerMet100 steel
    Jiao Qingyang, Zhao Dong, Wang Xinyu, Li Shijian
    2022, 47(6):  168-172.  doi:10.13251/j.issn.0254-6051.2022.06.032
    Abstract ( 60 )   PDF (2493KB) ( 19 )  
    Aermet100 steel is an advanced secondary hardening Ni-Co-Cr structural steel. The change of its density, thermal strain, elastic modulus, Poisson's ratio, thermal conductivity and flow stress with temperature were obtained by experiment, and the Ac1 and Ac3 for austenite transformation during heating, the Ms for martensite transformation and martensitic transformation coefficient Km during cooling were obtained. Finally, based on the data of thermo-physical properties of the tempered AerMet100 steel, the simulation of gear quenching process was carried out by using SYSWELD finite element analysis. The results show that the room temperature microstructure of tempered AerMet100 steel consists of tempered martensite and residual austenite. In the heating process, the austenite reaction enthalpy is 42 600 J/kg, other thermal-physical parameters change non-linearly in the range of Ac1-Ac3, and different test states and heating rates leads to different values of Ac1 and Ac3. The Ms of the tempered AerMet100 steel quenched at different cooling rates is basically the same as about 213 ℃, and the Km value is 0.011 736. The SYSWELD finite element simulation analysis results show that the thermal physical properties obtained from the test can be used for the heat treatment process simulation of the steel.
    Low yield ratio control strategy for thin 12MnNiVR storage tank steel plate
    Zhang Yuefei, Wang Kun, Zhang Xuefeng, Zou Yang, Du Qunchao
    2022, 47(6):  173-177.  doi:10.13251/j.issn.0254-6051.2022.06.033
    Abstract ( 87 )   PDF (2512KB) ( 20 )  
    Effect of microstructure of quenched and tempered 12MnNiVR storage tank steel with different specifications on the yield ratio was analyzed by means of mechanical property test and microstructure observation with optical microscope and transmission electron microscopy. The test results show that the main microstructure of 12MnNiVR steel plate after quenching is martensite and part of acicular ferrite/bainitic ferrite, and the volume fraction of acicular ferrite in 18 mm thin steel plate is 10%-15%, while that in 33.5 mm heavy steel plate can reach more than 40%. By optimizing the quenching cooling rate, quenching temperature, tempering temperature and other process parameters for the thin steel plate, the volume fraction of acicular ferrite in the structure can be increased, so that the yield ratio of the thin steel plate can be reduced.
    MATERIALS RESEARCH
    Effect of vanadium on microstructure and properties of high chrome alloy casting infiltration layer
    Yue Jianguo, Liu Wangyang, Chen Chong, Wei Shizhong, Diao Xiaogang
    2022, 47(6):  178-185.  doi:10.13251/j.issn.0254-6051.2022.06.034
    Abstract ( 98 )   PDF (8432KB) ( 27 )  
    Some high chromium alloy casting infiltration composite layers with various vanadium contents were prepared on the surface of ZG45 steel by vaccum evaporative pattern casting process. Effect of different vanadium contents on microstructure of the layers was studied by using scanning electron microscopy (SEM), energy spectrometer (EDS)and X-ray diffraction (XRD), while that on the hardness and wear resistance was researched by using Rockwell hardness tester and the impact wear experiment machine. The results show that the structure of the casting infiltration layer is mainly composed of α-Fe and α-Fe+M7C3+VC eutectic structure. The alloying elements in the transition layer are distributed in gradient, and C, Cr, V elements are diffused from the casting infiltration layer to the matrix. The distribution of C, Cr, V elements coincide with the distribution of carbides. With the increase of vanadium content, the grain is gradually refined, the amount of eutectic carbides is gradually increased, the amount of VC is also increased, and the hardness and wear resistance of the casting infiltration layer is improved. After heat treatment, a large amount of secondary carbides is precipitated. With the increase of V content in the casting infiltration layer, the secondary hardening effect is significantly improved.
    Effects of composition and heat treatment process on properties of 12MDV6 cast steel for nuclear power main equipment supporting
    You Shenshen, Yu Haihua
    2022, 47(6):  186-191.  doi:10.13251/j.issn.0254-6051.2022.06.035
    Abstract ( 65 )   PDF (2657KB) ( 32 )  
    By comparing effects of different compositions and heat treatment processes on the mechanical properties of 12MDV6 cast steel for nuclear power main equipment supporting, a reasonable heat treatment process and composition control were proposed by tensile test, impact test, metallographic test and composition test. The results show that the tempering temperature has a great influence on the tensile properties, and the appropriate tempering temperature is 690 ℃. The strength increases with increasing of the carbon content and alloying elements, but alloying elements have no obvious influence on elongation. The unqualified low temperature impact property is mainly caused by the high content of Al, macrosegregation of Al composition causes fluctuations in low temperature impact absorbed energy. In order to meet the requirements of impact property, the Al content should be controlled below 0.018%.
    Effect of carbon content and cooling rate on quenching residual stress of steel parts
    Li Yang, Zhang Jianwei, Zhu Pengkai, Yang Yang
    2022, 47(6):  192-195.  doi:10.13251/j.issn.0254-6051.2022.06.036
    Abstract ( 105 )   PDF (3027KB) ( 35 )  
    Relationship between surface residual stress and carbon content as well as the cooling rate of SAE8620, SAE8625 and SAE8627 steel bars with diameter of ø12 mm and the length of 50 mm after quenching was studied. The results show that the residual stress is compressive stress and the value is about 200-600 MPa. The value of compressive stress decreases with the increase of carbon content and the cooling rate,while the relationship between compressive stress value and core hardness is just the opposite. The higher the cooling rate is, the smaller the residual compressive stress is for the same core hardness of the same carbon content test piece. Thus, adopting lower cooling rate is beneficial to increase the residual compressive stress on the surface.
    SURFACE ENGINEERING
    Preparation and thermal stability of VNbMoTaWCo-nitride diffusion barrier layer
    Li Rongbin, Zhang Xia, Jiang Chunxia
    2022, 47(6):  196-201.  doi:10.13251/j.issn.0254-6051.2022.06.037
    Abstract ( 85 )   PDF (3684KB) ( 26 )  
    VNbMoTaWCoNx films (x=N2 flow rate) were prepared by DC magnetron sputtering in different N2 flow parameter. At N2 flow ratio of 20%, a Cu/VNbMoTaWCoN20/Si triple-layer stack structure was prepared by depositing a 15 nm thick VNbMoTaWCoN20 film on the cleaned silicon substrate and depositing a 50 nm thick Cu film on the top. The sheet resistance, phase structure, roughness and surface morphology of the Cu/VNbMoTaWCoN20/Si structure samples before and after annealing at 500 ℃ were analyzed and characterized by four probe resistance tester (FPP), X-ray diffractometer (XRD), atomic force microscope (AFM), field emission scanning electron microscope (SEM), and then the thermal stability and diffusion barrier properties of the VNbMoTaWCoN20 film were studied. The results indicate that when the N2 flow ratio is 20%, the VNbMoTaWCoN20 film before annealing is amorphous with some locally dispersed nanocrystals, and with flat and smooth film surface, with the best density and the smallest roughness. After the Cu/VNbMoTaWCoN20/Si triple-layer stack structure is annealed at 500 ℃ for 8 h, though agglomeration occurs on the surface of the Cu film, but no Cu-Si compound is found, and the sheet resistance of the film is still maintained at a low value 0.065 Ω/sq. The amorphous structured VNbMoTaWCoN20 film as diffusion barrier layer annealed at 500 ℃ for 8 h showes excellent thermal stability and diffusion barrier properties.
    Microstructure and properties of CrAlSiN coating deposited on TC4 titanium alloy
    Wu Yiruo, Xie Feng, Zhang Yuexia, Zhang Yujun, Liu Manhong, Hu Hanjie, Chen Quanlong, Zhou Zhiming
    2022, 47(6):  202-207.  doi:10.13251/j.issn.0254-6051.2022.06.038
    Abstract ( 83 )   PDF (3807KB) ( 25 )  
    In order to improve surface hardness and wear resistance of TC4 titanium alloy, the surface modification on the alloy was carried out by a combination of plasma nitriding and multi-arc ion plating technology. Microstructure, hardness, wear resistance and corrosion resistance of the TC4 titanium alloy, nitrided layer and CrAlSiN coating were studied by means of scanning electron microscopy, Vickers microhardness tester, three-position profiler, high-speed reciprocating friction and wear tester and electrochemical workstation. The results show that after nitriding treatment, surface hardness of the TC4 alloy is increased by about 2 times. The average hardness of the CrAlSiN coating prepared on this basis is as high as 3222 HV0.025, and there are a few large particles and pits on the coating surface. The average friction coefficient of the CrAlSiN coating is 0.22, and the wear mechanism is mainly adhesive wear. The material of the grinding pair adheres to the surface of the coating, and the coating is almost wear-free, and the wear resistance is significantly improved. The self-corrosion potential of the CrAlSiN coating is -0.542 V, which is 0.205 V higher than that of the TC4 titanium alloy substrate (-0.747 V), indicating that the electrochemical corrosion resistance of the CrAlSiN coating deposited on the basis of nitrided layer is significantly improved.
    Effect of thermal spraying process on properties of NiCrFeAl/hBN composite coating
    Zhou Zimin, Xiong Shengjian, Chen Haohui, Li Zhang, Wang Changliang, Guo Mengqiu, Cui Xiufang, Jin Guo
    2022, 47(6):  208-215.  doi:10.13251/j.issn.0254-6051.2022.06.039
    Abstract ( 82 )   PDF (2500KB) ( 34 )  
    In order to improve the mechanical properties of oxyacetylene flame sprayed NiCrFeAl/hBN composite coating, L9(34) orthogonal test method was used and taking the surface Rockwell hardness and bonding strength as the main judgment indexes, the influence order of the three main parameters (oxygen-fuel ratio, spraying speed, spraying spacing) of oxyacetylene flame spraying were analyzed, and the performance of the coating prepared by the optimal process was verified. The results show that the spraying spacing is the main factor affecting the performance of the coating, and the optimal process parameters are O2/C2H2 of 26/20, spraying speed of 600 mm/s, spraying spacing of 12 mm, which lead to more uniform internal structure of the coating, better melting bonding, smooth surface, less unmelted particles, and the average bonding strength of the coating is up to 10.3 MPa, the average surface Rockwell hardness is 54.9 HR15Y.
    Influence of thermal barrier coatings on multiaxial thermo-mechanical fatigue properties of single crystal superalloy
    Gao Dong, Qian Lingyi, Guo Yunshan, Huang Aihua
    2022, 47(6):  216-221.  doi:10.13251/j.issn.0254-6051.2022.06.040
    Abstract ( 63 )   PDF (2571KB) ( 40 )  
    Y2O3(7%-8%, mass fraction)-ZrO2 thermal barrier coatings were deposited on the surface of CMSX-4 single crystal alloy hollow test tube by electron beam physical vapor deposition process, then thermo-mechanical fatigue (TMF) and thermal gradient mechanical fatigue (TGMF) tests of the tube with/without coatings were investigated at 500-1000 ℃ under mechanical strain control. The results indicate that the thermal barrier coatings can improve the fatigue life of the single crystal alloy to a certain extent, and the fatigue life of the in-plane (IP) coated specimens is slightly higher than that of the out-plane (OP) coated specimens at the same strain amplitude. Furthermore, the fracture analysis results indicate that there is significant difference in the fatigue fracture between the IP-TMF coated specimens and the OP-TMF coated specimens. Obvious fatigue striation can be observed on the fracture surface of the OP-TMF coated specimens, and creep and oxidation have little effect on the fracture, while the fracture of the IP-TMF coated specimens is obviously related to the creep and oxidation of the material.
    Single-track forming control method for in-situ synthesis of WC by laser cladding
    Xiao Shihong, Lian Guofu, Huang Xu, Feng Meiyan
    2022, 47(6):  222-231.  doi:10.13251/j.issn.0254-6051.2022.06.041
    Abstract ( 69 )   PDF (4217KB) ( 26 )  
    Central composite design of response surface method was adopted to establish a mathematical model between the laser power, scanning speed, gas flow rate, WC powder ratio and the width, height, and cross-sectional area of the clad layer. The validity of the mathematical model was established by the analysis of variance and model verification. The clad width is proportional to the laser power, but inversely proportional to the scanning speed, gas flow rate and powder ratio. The clad height and cross-sectional area is proportinal to the laser power, but inversely proportional to the rising of scanning speed and powder ratio. Finally, the process parameters were optimized with the target of maximizing the clad width and cross-sectional area and minimizing the height. An experimental validation indicates that the error rates between the predicted and actual values for the clad width, height and cross-sectional area are 9.439%, 5.153% and 4.835%, respectively. The average error rate is less than 6.5%, further verifying the accuracy of the established model. The research results provide a theoretical reference for the prediction, control and optimization of process parameters of the forming quality of in-situ synthesis WC by laser cladding.
    Research of impact of shot peening on stainless steel surface
    Zhang Junshuang, Liu Fengling, Tang Tao, Chen Long, Lan Wei
    2022, 47(6):  232-239.  doi:10.13251/j.issn.0254-6051.2022.06.042
    Abstract ( 89 )   PDF (3781KB) ( 29 )  
    Surface hardness, magnetic properties and residual stress of stainless steel were analyzed from the shot peening strengthening method, and the influence of shot peening parameters on stainless steel materials was reviewed, the mechanism of shot peening is revealed, and the effect of shot peening on the residual stress in stainless steel was analyzed. The relationships between material properties and hardness, and the effects of shot peening time and shot size on the surface properties of stainless steel are introduced in detail, and the development direction of shot peening on stainless steel surfaces treatment is prospected.
    Effect of gas nitriding on oxidation behavior of F92 steel in air at 700 ℃
    Wang Bo, Huang Yijun, Xiong Dingbiao, Zhao Weiwei, Lou Yumin, Zhao Ningning
    2022, 47(6):  240-248.  doi:10.13251/j.issn.0254-6051.2022.06.043
    Abstract ( 66 )   PDF (5494KB) ( 22 )  
    High temperature oxidation behavior of as-delivered and nitrited F92 steel was studied in static air at 700 ℃ by using scanning electron microscope (SEM), energy dispersive spectrometer (EDS), X-ray diffraction (XRD) and the influence of gas nitriding on oxidation behavior of the F92 steel was elucidated. The results show that an expanded ferrite phase supersaturated with nitrogen and CrN phase are formed on the surface of the nitrided specimen. Thin and dense (Cr, Fe, Mn)2O3 and MnCr2O4 oxide layers are formed on the surface of the as-delivered F92 steel with good protection. In addition, there are two kinds of nodular oxides on the surface of as-received F92 steel, one is composed of continuous Fe2O3, and the other is independent composed of outer Fe2O3 and inner Cr-rich (Cr, Fe, Mn)3O4. Nitriding aggravates the oxidation of F92 steel, and an internal oxidation zone is observed inside the matrix. The oxide film on the surface of the nitrided specimen has a double-layer structure, in which the outer layer is Fe2O3 and the inner layer is Cr-rich Fe-Cr oxide. The expanded nitrogen supersaturated ferrite phase and CrN phase formed during the nitriding process of F92 steel and the CrN precipitation phase precipitated during the oxidation process reduce the activity of chromium and hinder the formation of protective chromium-rich oxides, resulting in a decrease of antioxidant property.
    NUMERICAL SIMULATION
    Numerical simulation on thermal insulation effect of heat shield for vacuum furnace
    Wang Shuobin, Cong Peiwu, Lu Wenlin, Du Chunhui, Chen Xuyang
    2022, 47(6):  249-252.  doi:10.13251/j.issn.0254-6051.2022.06.044
    Abstract ( 79 )   PDF (1645KB) ( 26 )  
    Vacuum furnace with metal furnace bladder is mainly used to process some metal products which require a high vacuum atmosphere. The heat shield of the furnace is relatively expensive to manufacture and difficult to modify. Through simulation on the thermal insulation effect of the metal heat shield of the WZDGQ-40 vacuum furnace, the temperature field of each heat shield was obtained. The results show that when the distance of the two middle heating belts is adjusted to 200 mm, the temperature of the outer layer of the furnace is reduced by 80 ℃, which means that reasonable heating belt width and heating belt spacing can improve the thermal insulation effect of the furnace, and that the simulation can provide a certain reference value for the manufacture of this type of equipment in the future.
    Influence of laser shock wave propagation characteristics on dynamic plastic deformation of micro-dimple on E690 steel surface
    Wang Zhimin, Huang Chunling, Cao Yupeng
    2022, 47(6):  253-258.  doi:10.13251/j.issn.0254-6051.2022.06.045
    Abstract ( 70 )   PDF (3070KB) ( 21 )  
    Influence of laser shock times and shock wave propagation characteristics on dynamic plastic deformation of micro-dimple during multiple shocks was studied by using the software ABAQUS to analyze the propagation law of stress waves in E690 high-strength steel and the dynamic plastic strain of the micro-dimple on the steel surface. Then the accuracy of the simulation was verified by designed experiments. The results show that the attenuation of the stress wave caused by the shock pressure in the depth direction of the material shows the characteristics of first fast and then slow. The attenuation speed of the stress wave during the third shock and fourth shock is basically close. Affected by the synergistic effect of surface waves and longitudinal waves during the dynamic propagation of shock waves, the overall plastic deformation depth of the micro-dimple surface decreases along the center of the spot radially to the surroundings. Comparing the test results and simulation results of plastic deformation in the depth direction of micro-dimple after shocking for 1-4 times, the maximum error is 4.80%, indicating that the simulation model is accurate and reliable. Simultaneously, as the times of shock increase, the increasing trend of hardness slows down, and the micro-dimple surface appears hardening saturation after four shocks.
    Numerical simulation and system optimization of temperature field in silicon carbide vacuum sintering furnace
    Xiong Li, Zhang Dengchun, Song Shichu, Chen Lin
    2022, 47(6):  259-265.  doi:10.13251/j.issn.0254-6051.2022.06.046
    Abstract ( 87 )   PDF (3115KB) ( 26 )  
    In order to improve the heating efficiency and temperature uniformity of the heating system of silicon carbide vacuum sintering furnace, the ZSD4.5-1150C vacuum high temperature sintering furnace was used as a reference model, the Ansys Fluent software and DO radiation model were used to simulate the transient temperature distribution of vacuum sintering furnace under no-load condition, and compared with the measured data, the maximum error was within 10%. On this basis, effects of heating rate, diameter of heating tube and distance between heating tubes and effective heating zone on temperature distribution characteristics, and heating efficiency of the heating system were further studied, and the heating system was optimized. The results show that the heating efficiency and temperature uniformity of the heating system can be effectively improved by appropriately increasing the heating rate and the diameter of the heating tube. But the distance between the heating tubes and effective heating zone has little effect on the performance of the heating system. The specific optimization scheme is the heating rate of 9 K/min, the diameter of the heating tube of ø45 mm, and the distance between the heating tubes and the effective heating area of 50 mm. After the optimization, the heating time of the system is reduced by 60 min, the heating efficiency is increased by 30%, and the temperature uniformity meets the process requirements.
    TEST AND ANALYSIS
    Abnormal microstructure analysis of G12MnMo7-4 steel and quenching and tempering process optimization
    Chang Youyu, Song Zhongming, Li Fuyan, Gou Chunlin
    2022, 47(6):  266-269.  doi:10.13251/j.issn.0254-6051.2022.06.047
    Abstract ( 75 )   PDF (3242KB) ( 25 )  
    Reasons for abnormal microstructure of quenched and tempered G12MnMo7-4 steel castings were analyzed by means of optical microscope (OM), scanning electron microscope (SEM), universal testing machine and micro Vickers hardness tester. And the quenching and tempering process was optimized. The results show that G12MnMo7-4 steel is a low-carbon alloy steel, due to high quenching temperature, overheating abnormal structure appears in some parts. After treated by improved quenching and tempering process (870 ℃×3 h rapid quenching+580 ℃×3 h tempering), the microstructure is fine tempered sorbite with good comprehensive properties, which meets the requirements of product technical conditions.
    Analysis of bright spot defect on surface of 590 MPa low-alloy high-strength galvannealed steel sheet
    Zhao Chuanxiang
    2022, 47(6):  270-273.  doi:10.13251/j.issn.0254-6051.2022.06.048
    Abstract ( 89 )   PDF (2022KB) ( 37 )  
    Morphology and element content of bright spot defect on the surface of 590 MPa galvannealed high-strength steel sheet were investigated by SEM and EDS. The results show that the surface oxides produced by the selective oxidation of alloying elements can be reduced completely by the dissolved Al in the Zn bath when the oxides are small enough in the high-strength low-alloy steel. Compared with the normal position, a complete and dense Fe2Al5Znx inhibitory layer is not formed at the position of the precipitate particles. In the subsequent hot-dip galvanizing process, the Zn-Fe reaction and diffusion at this position are fast, and the coating grows thicker. During skin pass rolling, the compressed sheet-like structures formed at this position are connected with each other, and their macroscopic feature is the surface bright spot defect. By reducing the dew point in the furnace, the external oxidation of alloy elements on the surface of low-alloy high-strength steel can be inhibited, thereby preventing the occurrence of bright spot defects on the surface of the coating.
    Cause analysis and countermeasure of low surface hardness of SPCC steel after gas nitrocarburizing
    Gao Xiaohui
    2022, 47(6):  274-276.  doi:10.13251/j.issn.0254-6051.2022.06.049
    Abstract ( 109 )   PDF (1149KB) ( 33 )  
    SPCC steel met the technical requirements in trial production, but the surface hardness was extremely low after mass production. After analyzing the incoming materials, manufacturing processes, and testing various process elements, the reasons were determined, and the problem of ultra-low surface hardness was resolved through consultation with customers. According to the verification and detection of the possible reasons, it is finally determined that the low hardness is caused by the mismatch between the product surface structure and the hardness testing method, that is, the turning tool cutting pattern on the product surface affects the accuracy of the inspection equipment. The correspondingly improved hardness testing is carried out by direct polishing without cutting and inlaying, and the detection position is only selected at the “wave peak” position.