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  • PROCESS RESEARCH
    Heat treatment and space environment performance of high strength aluminum alloy parts by selective laser melting
    Jiang Chao, Jia Dongyong, Zhou Zhiyong, Tian Zheng, Guo Xingye, Wang Zhe, Han Xiuzhu
    2022, 47(7):  1-8.  doi:10.13251/j.issn.0254-6051.2022.07.001
    Abstract ( 128 )   PDF (678KB) ( 98 )  
    High-strength aluminum alloy specimens of aluminum-magnesium-scandium-zirconium system were prepared by adopting the additive manufacturing technologys of selective laser melting (SLM). The evolution of the microstructure and mechanical properties of the specimens during annealing and solution aging treatment were studied. In addition, high and low temperature cycle experiments were carried out on the specimens to simulate the temperature change of the space environment, and then the evolution of mechanical properties after high and low temperature cycles were studied. The results show that for the high-strength aluminum alloy prepared by the SLM, the annealing treatment can significantly improve its mechanical properties. After the high and low temperature cycle experiment simulating the space environment, mechanical properties of the specimens remain unchanged, so it meets the performance requirements under the space alternating temperature.
    Comparative analysis on properties of 8Cr4Mo4V steel for bearing after vacuum gas quenching and isothermal salt bath quenching
    Tong Rui, Yu Xingfu, Liu Yongbao, Xia Yunzhi, Su Yong, Jin Yingli
    2022, 47(7):  9-14.  doi:10.13251/j.issn.0254-6051.2022.07.002
    Abstract ( 129 )   PDF (600KB) ( 65 )  
    Properties of 8Cr4Mo4V steel for bearing after vacuum gas quenching and isothermal salt bath quenching were comparatively analyzed by microstructure observation and property test. The results show that the martensite in the 8Cr4Mo4V steel is obtained after vacuum quenching, while the mixed microstructure of martensite and bainite is obtained after isothermal salt bath quenching. There is carbide precipitation at the grain boundary of vacuum quenched steel, and the grain boundary characteristics are obviously shown after chemical etching. However, the amount of carbide precipitation at the grain boundary of isothermal salt bath quenched steel is less, and the grain boundary characteristics of the steel are not obvious. Then after tempering treatment, a large number of carbides precipitate in the steels, and that in the steel isothermal salt bath quenched are larger in size and quantity than that of vacuum quenched. The test results of hardness and wear resistance show that the hardness of the isothermal salt bath quenched steel is 61.78 HRC, higher by 1.5 HRC than that of the vacuum quenched steel (60.28 HRC). The friction and wear resistance of the isothermal salt bath quenched steel is higher than that of the vacuum quenched. Compared with that of vacuum quenching, the mechanical properties of the steel after isothermal salt bath quenching are better: the tensile strength is higher by 164 MPa and 50 MPa respectively at room temperature and at high temperature, the impact absorbed energy is increased by 46.9%, and the rotary bending fatigue strength is increased by 22%, from 860 MPa to 1050 MPa.
    Effect of step quenching process on microstructure of high-Cr cast iron roll
    Zhang Bohan, Li Haonan, Gao Pengchong, Qiao Guiying, Liu Jiebing, Xiao Furen
    2022, 47(7):  15-19.  doi:10.13251/j.issn.0254-6051.2022.07.003
    Abstract ( 132 )   PDF (600KB) ( 55 )  
    Step quenching process of high chromium cast iron roller was simulated by using LINSEIS L78 dilatometer. The effect of step quenching temperature on Ms point, microstructure and hardness was studied by means of thermal dilation, optical microscopy(OM), scanning electron microscopy (SEM) and X-ray diffraction (XRD). The results show that the step quenching has little effect on the phase transformation during step quenching process, but it reduces the Ms point comparing with the direct quenching, and the Ms point decreases with the decrease of step quenching temperature. As the step quenching temperature is 560 ℃, the Ms point decreases a little, while the hardness increases to 62.1 HRC. Moreover, the hardness further increases to 64.5 HRC after tempering at 450-500 ℃.
    Effect of high-temperature short-time solution treatment on microstructure and properties of ultra-high strength Al-Zn-Mg-Cu alloy forging
    Wang Shaohua, Zhong Liwei, Ma Zhifeng
    2022, 47(7):  20-26.  doi:10.13251/j.issn.0254-6051.2022.07.004
    Abstract ( 84 )   PDF (602KB) ( 50 )  
    Effect of high-temperature short-time solution treatment (temperature of 475-480 ℃ and time of 0-7 min) on microstructure and properties of high alloying Al-Zn-Mg-Cu alloy forging was studied by means of optical microscope, scanning electron microscope and room temperature tensile test. The results show that high-temperature short-time solution treatment can effectively improve the tensile strength and elongation of as-aged Al-Zn-Mg-Cu alloy forging. With the increase of temperature or time, the coarse retained second phase at the grain boundary gradually dissolves back into the aluminum matrix. When the temperature is too high or the time is too long, the equiaxed grains coarsen and the microstructure burns over. Through comparative analysis and combined with the actual production situation, it is determined that the most suitable high-temperature short-time solution treatment is 475 ℃ for 3 min, under which the minimum tensile strength of the forging is 680 MPa in the 45° direction and the lowest elongation is 4.7% in LT direction.
    Effect of cooling rate on microstructure and properties of microalloyed medium carbon non-quenched and tempered steel
    Tian Ziwei, Yao Yanxin, Liu Jiaxing, Wang Zhiyi, Hu Zhangquan, Jiang Bo
    2022, 47(7):  27-33.  doi:10.13251/j.issn.0254-6051.2022.07.005
    Abstract ( 76 )   PDF (600KB) ( 48 )  
    Heat treatment was adopted to simulate the coarse microstructure of microalloyed medium carbon non-quenched and tempered steel for crankshaft after closed-die forging with small deformation amount, the corresponding mechanical properties were tested, and the effects of cooling rate and microalloying elements Ti, Nb on microstructure and mechanical properties of the tested steels was studied. The results show that the comprehensive mechanical properties of V-Ti-Nb steel after furnace cooling are the best: the tensile strength, yield strength, elongation and impact absorbed energy are 960.6 MPa, 672.1 MPa, 17.5% and 22.9 J, respectively. With the increase of cooling rate, the tensile strength and yield strength are increased by nearly 120 MPa, the plasticity is decreased due to the existence of bainite, but the impact property is nearly unchanged due to the refinement of prior austenite grain size. With the addition of Ti and Nb, the yield strength is increased by 76.5 MPa due to the precipitation strengthening of (V, Ti, Nb)(C, N) and the refinement of pearlite interlamellar spacing, and in addition, the impact property of the V-Ti-Nb steel is improved mainly due to the refinement of both the pearlite interlamellar spacing and the prior austenite grain size.
    Microstructure and properties of low carbon high strength ship steel after solution and aging treatment
    Li Menghuan, Zhang Luyou, Xu Haiwei, Dong Xinxin, Yang Zixuan, Tian Yaqiang, Chen Liansheng
    2022, 47(7):  34-39.  doi:10.13251/j.issn.0254-6051.2022.07.006
    Abstract ( 74 )   PDF (600KB) ( 32 )  
    Microstructure and mechanical properties of a low carbon high strength ship steel after solid solution and different temperature aging treatments were studied by means of SEM, EDS, tensile test and low temperature impact test. The results show that the microstructure of the steel after solution treatment at 900 ℃ h for 30 min is composed of polygonal ferrite and bainite/martensite, and the yield strength and tensile strength are 505 MPa and 625 MPa respectively. With the increases of aging temperature, the strength of the steel increases first and then decreases, the tensile strength and yield strength are the highest when the aging temperature is 500 ℃, which are 783 MPa and 747 MPa respectively, the elongation after fracture is 11.5%, and the impact absorbed energy at -20 ℃ is 96 J.
    Effect of aging on microstructure and properties of rare earth Sc microalloyed titanium alloy
    Zhong Xiuyang, Deng Tongsheng, Zhu Zhiyun, Li Shang, Zhong Ming, Guo Tao
    2022, 47(7):  40-46.  doi:10.13251/j.issn.0254-6051.2022.07.007
    Abstract ( 76 )   PDF (607KB) ( 37 )  
    In order to improve the service life of titanium alloys at high temperatures, experimental research on high temperature creep of rare-earth scandium microalloyed titanium alloy materials was carried out. The Ti64-0.25Si-xSc (x=0, 0.3) alloys were aged at different temperatures for different time after solid solution treatment (950 ℃×0.5 h, AC), then the Vickers hardness and high temperature creep properties of the alloys were tested, the creep curves were fitted to a time hardening creep model ε=Aσntm, and the microstructure of the alloys were analyzed by OM and TEM. The results show that the creep properties of the alloys are the best when aged at 510 ℃ for 6 h, for the scandium addition can inhibit the grain growth, change the grain orientation distribution, and promote the formation of basket-weave structure; and the formation of Sc2O3 in the alloy can purify the matrix, which has a significant effect on improving the high temperature creep performance of the alloys. There are a large number of dislocation interaction, stacking and entanglement in the alloy microstructure, and the creep mechanism of the alloy is mainly the slip of dislocation.
    Effect of annealing treatment on microstructure and properties of Er-containing Al-6Mg-1Mn alloy
    Wei Xiaoyuan, Wei Wu, Guo Xiao, Cheng Zhiqiang, Wen Shengping, Shi Wei, Huang Hui
    2022, 47(7):  47-51.  doi:10.13251/j.issn.0254-6051.2022.07.008
    Abstract ( 75 )   PDF (603KB) ( 41 )  
    Mechanical properties and corrosion resistance of erbium-containing high magnesium aluminum alloy sheet were studied under different stabilization annealing process, and the stabilization annealing process was optimized to obtain the stabilization process window of erbium-containing high magnesium aluminum alloy sheet. The results show that the corrosion resistance of the hot extruded erbium-containing high magnesium aluminum alloy annealed at 260-270 ℃ reaches the insensitive zone with the extension of the stabilization annealing time. After sensitization treatment, the corrosion resistance of the alloy deteriorates to the insensitive zone and its corrosion resistance is improved. Combined with the observation and analysis of the corrosion depth after sensitization, the results show that the alloy has good corrosion resistance and mechanical properties under the optimized process of annealing at 260 ℃ for 16-24 h. The microstructure of the optimized alloy is analyzed by means of transmission electron microscope (TEM). No evidence of β phase precipitation continuously at grain boundary is observed, which proved that the alloy can offer good corrosion resistance.
    Effect of annealing temperature on microstructure and corrosion resistance of AlCrMnFeNiCu0.8 high-entropy alloy
    Hou Jinrui, Lu Ruoding, Bu Shaocong, Xu Shuailing, Fu Lihua, Tian Baohong
    2022, 47(7):  52-57.  doi:10.13251/j.issn.0254-6051.2022.07.009
    Abstract ( 70 )   PDF (604KB) ( 35 )  
    AlCrMnFeNiCu0.8 high-entropy alloy was prepared by vacuum arc melting and were treated by vacuum annealing at 200, 400, 600, and 800 ℃ for 4 h. The microstructure and crystal structure of the alloy were characterized by means of optical microscope (OM) and X-ray diffraction (XRD). The corrosion resistance of the alloy was analyzed by means of a standard three-electrode system CHI660D electrochemical workstation. The results show that the microstructure of the alloy is Cu-rich zone and Cu-poor zone, mainly composed of Fe-Cr solid solution, Al-Ni solid solution and Cu-rich solid solution. With the increase of annealing temperature, the BCC structure is stronger and FCC structure is weaker. After anneding at 400 ℃, the alloy has the most positive self-corrosion potential (-0.584 V) and the lowest self-corrosion current density (0.6618 μA·cm-2). After anneding at 600 ℃ and 800 ℃, the diffusion effect appears in the impedance map, which leads to the decrease of corrosion resistance of the alloy.
    Effect of cooling methods after ART annealing on work hardening behavior of 0.1C-7.2Mn steel
    Wang Sichao, Xu Haiwei, Xu Yong, Han Yun, Zheng Xiaoping, Li Hongbin, Tian Yaqiang, Chen Liansheng
    2022, 47(7):  58-62.  doi:10.13251/j.issn.0254-6051.2022.07.010
    Abstract ( 57 )   PDF (601KB) ( 29 )  
    Taking 0.1C-7.2Mn hot rolled and cold rolled medium manganese steel as the research object, the effect of different cooling methods after ART annealing on work hardening behavior of the medium manganese steel were studied by means of scanning electron microscope (SEM), X-ray diffraction (XRD) and room temperature tensile test. The results show that lath ferrite austenite structure is obtained in the hot rolled steel after ART annealing, and a large number of carbides precipitate in the air-cooled specimens, while water cooling inhibits carbides precipitation. The equiaxed ferrite and austenite micro structure is obtained in the cold rolled steel after ART annealing, and the air-cooled specimens shows continuous yield, and water cooling promots the equiaxed microstructure. Higher volume fraction of retained austenite is obtained in the hot rolled specimens, which show a excellent mechanical properties. The larger the volume fraction of retained austenite, the longer the TRIP effect during tensile deformation, providing higher and more sustained work hardening.
    Hot deformation behavior and hot processing map of as-HIPed FGH96 alloy
    Chen Leilei, Qu Zonghong, Wang Zeyu, Lai Yunjin, Liang Shujin
    2022, 47(7):  63-70.  doi:10.13251/j.issn.0254-6051.2022.07.011
    Abstract ( 71 )   PDF (603KB) ( 30 )  
    Compression experiments of hot isostatic pressed FGH96 alloy at different temperatures and strain rates were carried out by Gleeble-3800 thermal simulation compression testing machine. The high temperature hot deformation behavior of the FGH96 alloy at deformation temperatures of 1040, 1070, 1100 and 1130 ℃, strain rates of 0.001, 0.01, 0.1 and 1 s-1 and the maximum true strain of 0.7 were studied. The true stress-true strain curve was analyzed and the constitutive equation was established, and the hot processing maps were constructed by Origin software, and the optical hot processing parameters were determined combined with the effect of deformation temperature and strain rate on microstructure. The results show that the true stress-true strain curve of hot isostatic pressed FGH96 alloy shows typical dynamic recrystallization characteristics, and the peak stress increases with the decrease of deformation temperature and the increase of strain rate. Combined with constitutive equation, hot working diagram and microstructure, the optical hot processing area of the FGH96 alloy is 1060-1080 ℃ and 0.0001-0.004 s-1.
    Effect of hot isostatic pressing on microstructure of nickel-based superalloy K4125
    Zhang Mingjun, Li Yuan, Li Xianghui
    2022, 47(7):  71-75.  doi:10.13251/j.issn.0254-6051.2022.07.012
    Abstract ( 67 )   PDF (603KB) ( 36 )  
    Microstructure evolution of nickel-based superalloy K4125 was studied by hot isostatic pressing (HIP) with three different sets of parameters. The results show that the distribution areas of Hf, Mo and other elements in MC carbide are slightly different in the alloys prepared by three HIP. Ta, Mo, Co, Cr, Ti and Al are positive segregation elements, while W and Ni are negative segregation elements. Compared with other elements, the segregation degree of Ni, Co and Cr is smaller, and with the increase of HIP temperature and pressure, the segregation degree of all elements decreases, and the content of γ/γ′ eutectic decreases gradually. Meanwhile, the size of γ′ phase decreases significantly while its area fraction has no obvious change. In addition, the fragmentation of massive MC carbides, the precipitation of secondary MC carbides and the appearance of fine carbides at grain boundaries are observed in all the three HIP alloys. This phenomenon is intensified when the temperature and pressure are increased, and the contents of Ta and Ti in carbides decrease, while the decomposition tendency of TaC and TiC increases.
    Process optimization of CuIn5 alloy prepared by sparking plasma sintering
    Fan Shuaiqi, Li Haitao , Wang Xuesong, Zhang Leitao, Xu Jinfu, Dai Jiaoyan
    2022, 47(7):  76-80.  doi:10.13251/j.issn.0254-6051.2022.07.013
    Abstract ( 59 )   PDF (601KB) ( 24 )  
    Optimum parameters of spark plasma sintering (SPS) process of CuIn5 alloy were determined by orthogonal experiment. The effect of sintering temperature, sintering time and sintering pressure on density, hardness and electrical conductivity of the CuIn5 alloy was studied. The results show that the main factor affecting density and hardness of the CuIn5 alloy is sintering temperature, followed by sintering pressure, and sintering time has the least effect; the main factors affecting the conductivity of the CuIn5 alloy is sintering temperature, followed by sintering time and sintering pressure. The optimum process for preparing CuIn5 alloy by SPS process consists of sintering temperature of 850 ℃, sintering time of 5 min and sintering pressure of 50 MPa. The microstructure of CuIn5 alloy prepared by the best process is uniform and compact, In is dissolved in Cu to form a solid solution, the lattice constant is 0.362 865 nm, the lattice distortion is 0.38%, the density is 99.56%, the microhardness is 136.3 HV0.1, and the conductivity is 37.86%IACS.
    Magnetic field heat treatment process and soft magnetic properties of new Fe72.7Si17B6.8Nb2.6Cu0.9 nanocrystalline iron core
    Sun Hao, Song Wenle, Wang Lei, Xue Zhiyong, Zhan Huamao
    2022, 47(7):  81-85.  doi:10.13251/j.issn.0254-6051.2022.07.014
    Abstract ( 60 )   PDF (606KB) ( 25 )  
    In order to meet the requirement of low loss of iron core for high-frequency transformer, the heat treatment process of Fe72.7Si17B6.8Nb2.6Cu0.9 nanocrystalline iron core was studied, and the variation of dynamic and static soft magnetic properties of the iron core annealed without magnetic field for different time and with different magnetic field intensity was discussed. The results show that when no magnetic field is applied, the core loss is the lowest when the holding time is 60 min, which is P20 kHz/0.5 T=11.82 W/kg, and its static soft magnetic properties is in the optimal state when the holding time is 30 min, which is Hc30 min=1.86 A/m. After the transverse magnetic field is applied, the remanence and coercivity of the DC magnetic properties are significantly reduced, Hc40 mT=0.64 A/m, and the loss reaches the lowest when the applied magnetic field intensity is 50 mT, which is P20 kHz/0.5 T=10.53 W/kg. Eddy current loss plays a leading role in the core loss in the high frequency range. The high frequency loss of the new nanocrystalline iron core is greatly reduced after transverse magnetic field heat treatment, and its permeability is excellent.
    Effect of solution treatment on microstructure and properties of powder metallurgy GH4099 alloy
    Wang Hua, Wang Zeyu, Song Jiaming, Qu Zonghong, Lai Yunjin, Liang Shujin
    2022, 47(7):  86-91.  doi:10.13251/j.issn.0254-6051.2022.07.015
    Abstract ( 99 )   PDF (605KB) ( 28 )  
    Powder metallurgy GH4099 superalloy was prepared by plasma rotating electrode process (PREP) and hot isostatic pressing (HIP). The effect of solution treatment temperature on microstructure evolution and tensile properties at room temperature and high temperature was studied. The results indicate that the microstructure of the PM GH4099 alloy is uniform, the grain size is close to original particle size (~50 μm) and no component segregation. The large-sized primary γ′ phase and carbides are interlaced at the grain boundaries, and there are a large number of annealing twins inside the grains. With the increase of solution treatment temperature, the γ phase grains grow gradually, and the carbides at the grain boundaries transfer from discontinuous to continuous distribution. When the solution treatment temperature is 1140 ℃, the room/high temperature tensile properties equivalent to those of rolling/forging parts can be obtained, but the plasticity is low, the tensile fracture presents brittle cleavage fracture morphology, which is mainly related to the precipitation of carbides at prior particle boundaries during heat treatment.
    Effect of reverse phase transformation annealing temperature after quenching on microstructure and properties of 5%Mn cold rolled medium manganese steel
    Fan Lifeng, Kang Ze, Jia Liying, Xu Huimin, Gao Jun
    2022, 47(7):  92-97.  doi:10.13251/j.issn.0254-6051.2022.07.016
    Abstract ( 60 )   PDF (601KB) ( 30 )  
    Effect of annealing temperature on microstructure and mechanical properties of a 5%Mn cold rolled medium manganese steel after quenching at 930 ℃ for 20 min and then reverse phase transformation annealing respectively at 660, 665, 675 and 685 ℃ for 30 min were studied by means of OM, SEM and XRD. The results show that after high temperature quenching and reverse phase transformation annealing, the microstructure of the 5%Mn cold rolled medium manganese steel is composed of ultra-fine-grained ferrite, lath martensite and austenite. As the reverse phase transformation annealing temperature increases from 660 ℃ to 685 ℃, the austenite content increases first then decreases and reaches the maximum value at 665 ℃, the tensile strength increases continuously, the yield strength increases first then decreases and reaches the maximum value at 675 ℃, and the elongation increases first then decreases and reaches the maximum value at 665 ℃. In conclusion, the comprehensive mechanical properties are the best for the 5%Mn cold rolled medium manganese steel after quenching at 930 ℃ for 20 min and then reverse phase transformation annealing at 665 ℃ for 30 min, at which the volume fraction of austenite is 24.24%, the tensile strength is 980 MPa, the elongation is 23.68%, and the product of strength and plasticity is 23.21 GPa·%.
    Effect of heating arrival time lag on microstructure and properties of FV520B steel during vacuum aging
    Yu Huang, Wang Feiyu, Bao Cuimin, Wang Quanzhen, Chen Wei, Qu Deyi, Jiang Shenzhu, Ma Yulin
    2022, 47(7):  98-101.  doi:10.13251/j.issn.0254-6051.2022.07.017
    Abstract ( 100 )   PDF (600KB) ( 29 )  
    By real-time tracing of vacuum heat treatment temperature of FV520B steel, the heating time lag at different heating temperatures was analyzed and the effect of different holding time on the microstructure and mechanical properties aging at 600 ℃ for different time was studied. The results show that the time lag of vacuum heat treatment increases with the decrease of heating temperature. In the early stage of vacuum aging of the FV520B steel, due to the time lag, the temperature in the workpiece core does not reach the set heating temperature. With the extension of the holding time, the microstructure changes greatly, the content of retained austenite increases and the precipitated phase gradually precipitates. The yield strength decreases and the impact absorbed energy increases with the prolongation of holding time. The power consumption of vacuum furnace can be used to determine whether the workpiece temperature is uniform, which can be used to guide the design of heat treatment process parameters.
    Effect of finishing rolling temperature on microstructure and mechanical properties of Cu-alloyed Fe-18Mn-0.6C TWIP steel
    Zhang Wenwen, Dong Futao, Liu Yunshuang, Tian Yaqiang, Chen Liansheng
    2022, 47(7):  102-106.  doi:10.13251/j.issn.0254-6051.2022.07.018
    Abstract ( 47 )   PDF (581KB) ( 28 )  
    Effect of finishing rolling temperature (900 ℃ and 1000 ℃) on microstructure and mechanical properties of Cu-alloyed Fe-18Mn-0.6C TWIP steel was studied by means of XRD, OM, SEM, tensile test and impact test machine.The results show that the strength of TWIP steel is improved obviously with low temperature finishing rolling, but the elongation and product of strength and elongation are reduced.High temperature finishing rolling is more beneficial to improve plasticity and impact property at room temperature of the TWIP steel. Large-size austenite grains can be obtained with high temperature finishing rolling, which reduces the critical stress required by twinning and has higher strain strengthening ability.The dimples on the tensile fracture and impact fracture of the TWIP steel with high temperature are finishing rolling is larger and deeper than that of low temperature finishing rolling, which shows an excellent plasticity and toughness.
    Development and application of hot forming steel CR300MB for high-end vehicle
    Chen Bo, Zhany Jiguo, Hua Yongxing, Yin Shuchun, Wu Lei, Liang Zhenwei, Sun Kuo
    2022, 47(7):  107-113.  doi:10.13251/j.issn.0254-6051.2022.07.019
    Abstract ( 100 )   PDF (583KB) ( 25 )  
    After smelting, continuous casting, hot rolling, pickling and cold rolling, the cold-rolled coil of CR300MB steel was produced. In order to develop the hot forming steel CR300MB for high-end vehicle, the spesimens cut from the cold-rolled CR300MB steel coil were simulated by continuous annealing and batch annealing process. The results show that the mechanical properties of the two kinds of specrmens simulated by continuous annealing and batch annealing can satisfy the requirement of the high-end vehicle enterprise standards, however, for the specrmens simulated by continuous annealing, the yield strength and tensile strength are too high and the elongation is too low compared with that of the imported material, and the grains are coarse, most of them are elongated rolling deformed grains and there is banded segregation, while the mechanical properties of the specrmens simulated by batch annealing are closer to that of the imported material, and the grains are fine and most of them are equiaxed. Comprehensive analysis shows that the mechanical properties and microstructure of the specrmens simulated by 680 ℃ batch annealing process are the best, and the batch annealing process with annealing at 680 ℃ and holding for 10 h is adopted to develop the CR300MB cold rolled hot forming steel. The yield strength, tensile strength and elongation of the CR300MB steel before hot stamping meet the standard requirements, and the microstructure and mechanical properties are better than that of the specrmens simulated by batch annealing, basically reaching the level of the imported material. The developed CR300MB steel adopts the hot stamping process of heating temperature 930 ℃ with holding time 300 s, holding pressure 8000 kN with holding time 10 s to trial produce the parts for a high-end automotive company and gets success. The mechanical properties, microstructure and decarburization layer depth of the parts are qualified, which shows that the development and application of the CR300MB hot forming steel for high-end vehicle is successful.
    Effect of solution treatment on microstructure and mechanical properties of Fe-30Mn-10Al-1C low density steel
    Fu Xibin, Meng Shaobo, Liu Wensheng, Zhang Ke, Li Zhaodong, Cao Yanguang, Zhang Xiaofeng, Yong Qilong
    2022, 47(7):  114-119.  doi:10.13251/j.issn.0254-6051.2022.07.020
    Abstract ( 65 )   PDF (586KB) ( 27 )  
    Effect of solution temperature on microstructure and mechanical properties of hot-rolled Fe-30Mn-10Al-1C low density steel was studied by means of OM, SEM, TEM and tensile test. The reasons for microstructure evolution and mechanical properties change were clarified. The results show that the Fe-30Mn-10Al-1C low-density steel is austenitic single-phase structure after hot rolling and solution treatment. A large number of annealing twins appear after solution treatment. The average grain size increases from 34 μm to 138 μm when the temperature is increased between 950-1050 ℃. With the increase of solution temperature, micron κ carbide disappears gradually. However, due to the extremely low nucleation barrier and high degree of subcooling, a large amount of nano-κ carbides are still formed after solution treatment. The tensile strength and yield strength of the as-rolled tested steel are the highest, reaching 1188 MPa and 1123 MPa, respectively, but the elongation is the lowest (33%). With the increase of solution temperature, the tensile strength and yield strength of the tested steel gradually decrease, and the elongation continuously increases. At 1050 ℃, the tensile strength and yield strength are 853 MPa and 726 MPa, respectively, and the elongation reaches 61%.
    Effect of heat treatment on microstructure and properties of 4Cr5MoSiV1 steel for needle valve body
    Han Jungang, Shao Zhiwen, Song Yunkun, Chen Xiaohu, Ding Boyuan, Gu Jiaojiao
    2022, 47(7):  120-124.  doi:10.13251/j.issn.0254-6051.2022.07.021
    Abstract ( 96 )   PDF (233KB) ( 35 )  
    Quenching+low temperatural tempering and quenching+medium temperature tempering were applied to the 4Cr5MoSiV1 steel, and the effect of the two typical heat treatment processes on microstructure, Vickers hardness and mechanical properties was analyzed. The results show that with the increase of tempering temperature, the microstructure of the needle valve body changes from tempered martensite to tempered troosite. Meanwhile, the Vickers hardness decreases from 639.4 HV0.1 to 584.4 HV0.1, while the tensile strength, yield strength and elongation increase by 12.7%, 12.8% and 26.6%, respectively.
    Influence of heat treatment on microstructure and properties of Mo-containing bearing steel
    Xu Rongchang, Wang Yi, Sun Zonghui, Li Hui
    2022, 47(7):  125-128.  doi:10.13251/j.issn.0254-6051.2022.07.022
    Abstract ( 96 )   PDF (582KB) ( 41 )  
    Phase change law and influence of heat treatment on microstructure and properties of Mo-containing bearing steel were investigated. The microstructure was characterized by using SEM and XRD, the CCT curves were drawn, the micro-hardness, mechanical properties and wear resistance were tested. The results indicate that Mo contained in the tested steel postpones the transformation of pearlite, and only martensite transformation occurs while the cooling rate is higher than 4 ℃/s. When quenched and low-temperature tempered, the tensile strength and micro-hardness is 1850 MPa and 785 HV, respectively, while 2160 MPa and 735 HV when austempered. The volume fraction of retained austenite is 12.68% when quenched and low-temperature tempered, while 3.88% when austempered. The reduction of the retained austenite content contributes to the dimensional stability of the bearing steel.
    Effect of tempering temperature on microstructure and properties of heat-resistant steel
    Kuang Chengyang, Ma Yulin, Wang Chenyu, He Jiayong, Lu Kun
    2022, 47(7):  129-133.  doi:10.13251/j.issn.0254-6051.2022.07.023
    Abstract ( 91 )   PDF (585KB) ( 35 )  
    Morphology and distribution of carbides in a heat-resistant steel with 0.01%boron after tempering at 200-650 ℃ and their effect on mechanical properties were studied by means of optical microscope (OM), scanning electron microscope (SEM), transmission electron microscope (TEM), Brinell hardness test and tensile test. The results show that as the tempering temperature increases, the average size of carbides gradually increases, and its shape gradually changes from flake at low tempering temperature to block at high tempering temperature. The hardness, tensile strength and yield strength of the heat-resistant steel increase first and then decrease with the increases of tempering temperature, and the elongation increases from 6% to 12%. With the increases of tempering temperature, the tensile fracture of the heat-resistant steel changes from brittle fracture to ductile fracture, and its morphology changes from river pattern to dimples.
    Effect of partitioning process on friction and wear properties of 5CrMnNiMo ultra-high strength steel
    Suo Zhongyuan, Du Yang, Fu Liming, Shan Aidang
    2022, 47(7):  134-137.  doi:10.13251/j.issn.0254-6051.2022.07.024
    Abstract ( 58 )   PDF (582KB) ( 26 )  
    Wear properties of 5CrMnNiMo ultra-high strength steel were studied by means of friction and wear tester under load of 50 N, wear speed of 0.5 m/s and dry friction and wear condition. The effect of partitioning processes on its wear resistance was discussed by means of SEM, EDS, XRD and EBSD. The results show that when the partitioning time is short (isothermal partitioning for 5 min), the wear resistance is controlled by hardness and the wear rate is low. With the extension of partitioning time to 6 h (non-isothermal partitioning) and 24 h (isothermal partitioning), the hardness decreases from 800 HV0.2 to 460 HV0.2 and 390 HV0.2, and the wear rate increases slightly. The wear mechanism is changed from mainly abrasive wear+oxidation wear, supplemented by adhesive wear to mainly adhesive wear, supplemented by abrasive wear. The long-term partitioning promotes the increase of austenite content which brings stronger TRIP effect in the friction and wear process, which enhances the wear resistance.
    Effect of forging and heat treatment on microstructure and wear resistance of wear-resistant steel
    Zhang Heng, Zhang Di, Liu Xinyu, Wang Xiaodong, Gao Zhanyong, Chen Lin
    2022, 47(7):  138-143.  doi:10.13251/j.issn.0254-6051.2022.07.025
    Abstract ( 65 )   PDF (584KB) ( 27 )  
    Effect of forging deformation and heat treatment process on microstructure, hardness and wear resistance of a new wear-resistant steel was studied, and the content of martensite+retained austenite in the steel was quantitatively analyzed by color metallography method. The results show that the wear-resistant steel microstructure under different deformations are all bainite/martensite multiphase, and the thickness of the bainitic lath is reduced from 524 nm to 292 nm as the deformation increases from 30% to 70%, while the volume fraction of martensite +retained austenite increases from 25.4% to 41.1%. After holding at 330 ℃(above the Ms) for 5 min and then 260 ℃ isothermal transformation, and compared with that of direct 260 ℃ isothermal transformation without 330 ℃ holding, the thickness of bainite lath decreases by 357.2 nm, the wear loss decreases by 0.02 g, and the average friction factor decreases from 0.311 to 0.212.
    Effect of aging on microstructure and bending properties of 7022 aluminum alloy
    Yin Jian, Jin Kang, Li Cheng, Dong Qi, Shen Zhi, Zhang Bo
    2022, 47(7):  144-150.  doi:10.13251/j.issn.0254-6051.2022.07.026
    Abstract ( 84 )   PDF (586KB) ( 39 )  
    Effect of aging treatment on microstructure and mechanical properties of 7022 aluminum alloy was studied by means of scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) analysis, X-ray diffraction (XRD), electron backscatter diffraction (EBSD), tensile and bending test. The results show that the 7022 aluminum alloy matrix after solution treatment still contains a large amount of black insoluble second phases and these phases are mainly composed of α-Al, MgZn2, Al2CuMg and Al7Cu2Fe phases. As the aging progresses, the Al2CuMg and Al7Cu2Fe phases gradually dissolve, and the Mg(Zn, Cu, Al)2 phase, which is similar in properties to the MgZn2 phase, precipitates, and the grains grow gradually, resulting in an obvious precipitation strengthening effect. The bending strength of the specimen is mainly affected by the number and size of the second phase particles and grain size. Under the aging condition at 110 ℃ for 10 h, the alloy with dispersed fine second phase particles and suitable grain size has better bending strength and tensile strength, and the values are 21.7 MPa and 608 MPa, respectively.
    Microstructure and properties of new type bainitic leaf spring steel
    Jang Wenmiao, Hu Zhihua, Luan Daocheng, Zhang Xu, Ling Junhua, Yin Zhiming, Li Yuan, Zhou Xinyu, Wang Zhengyun
    2022, 47(7):  151-155.  doi:10.13251/j.issn.0254-6051.2022.07.027
    Abstract ( 68 )   PDF (588KB) ( 26 )  
    Aiming at the problems of automobile weight reduction and environmental protection, a new type of bainitic leaf spring steel for automobiles was designed and developed, and the microstructure and mechanical properties were studied. The results show that the carbide-free bainitic microstructure of the steel can be obtained by normalizing. XRD test results show that its phase composition is dominated by α phase; The steel has excellent comprehensive mechanical properties and corrosion resistance, with yield strength of nearly 1200 MPa, tensile strength of 1400 MPa, impact absorbed energy of 73.2 J or more at room temperature, and excellent match of strength and toughness.
    Effect of quenching and tempering process on microstructure and properties of Cr26 hypereutectic high chromium cast iron
    Zhang Kai, Zhang Jianping, Zhong Ning, Lu Shangwen
    2022, 47(7):  156-162.  doi:10.13251/j.issn.0254-6051.2022.07.028
    Abstract ( 73 )   PDF (582KB) ( 31 )  
    Effect of quenching and tempering process on the microstructure, hardness, impact absorbed energy and wear resistance of Cr26 hypereutectic high chromium cast iron was studied by means of XRD, OM, SEM, hardness test, impact test and wear test. The results show that the microstructure of the Cr26 hypereutectic high chromium cast iron quenced at 980-1100 ℃ and tempered at 250-600 ℃ is mainly martensite matrix, M7C3 carbide and a small amount of austenite. The primary carbides are hexagonal, while the eutectic carbides and tempered secondary carbides are short rods. The total carbide content increases slightly with the increase of quenching temperature. With the increase of tempering temperature, the hardness decreases first and then increases, decreasing again when the tempering temperature exceeds 500 ℃, meanwhile, the impact absorbed energy increases first and then decreases, increasing again when the tempering temperature exceeds 350 ℃. For the different quenching temperatures, the tempering temperature corresponding to the maximum wear resistance is different. When quenched at 980 ℃ and 1050 ℃, the maximum wear resistance appears tempered at 250 ℃,while quenched at 1100 ℃,the maximum wear resistance appears tempered at 350 ℃.
    Recrystallizing annealed microstructure evolution of severe cold rolled FeCoCrNiMn high entropy alloy
    Guo Chunyan, Liu Yubao, Yang Pengfei, Li Yuan, Lü Weidong , Gao Rizeng, Zhang Yang, Hou Fusheng
    2022, 47(7):  163-167.  doi:10.13251/j.issn.0254-6051.2022.07.029
    Abstract ( 73 )   PDF (584KB) ( 26 )  
    Crystal structure, hardness, microstructure evolution and recrystallization behavior of the FeCoCrNiMn high-entropy alloy after severe cold rolling with reduction ratio of 95% and then annealing at 550-800 ℃ for 1 h were studied by means of X-ray diffractometer (XRD), Vickers hardness tester, optical microscope and electron backscatter diffraction (EBSD). The results show that the crystal structure of the FeCoCrNiMn high-entropy alloy always maintains an fcc structure during the cold rolling-annealing process. The beginning temperature of recrystallization is 600 ℃, and the finishing temperature is 750 ℃. As the annealing temperature increases, the hardness of the high-entropy alloy decreases first and then tends to be gentle, and microstructure gradually changes from fibrous deformed grains to randomly oriented recrystallized grains.
    Microstructure and properties of grade E steel after quenching and tempering treatment
    Wang Hao, Tian Changliang, Wang An, He Jianchao, Qin Zuoxiang
    2022, 47(7):  168-176.  doi:10.13251/j.issn.0254-6051.2022.07.030
    Abstract ( 82 )   PDF (581KB) ( 37 )  
    Through the optimization of quenching and tempering heat treatment process of grade E steel, the internal reason for the increase of low temperature impact properties was obtained. The microstructure of the steel was studied by optical microscope, and the tensile properties and -40 ℃ impact properties of grade E steel after different heat treatments were studied by tensile testing machine. The results show that uniform sorbite structure is obtained after quenching at 910 ℃ and tempering, and the impact properties is the best. Through the observation of the impact fracture and the study of the precipitation behavior of carbides in steel, the results show that the toughness of the grade E steel quenched and tempered is related to the morphology and distribution of carbides. When tempering temperature is below 550 ℃, carbides mainly precipitate at lath boundary and grain boundary, the impact properties of low temperature is low. When tempering temperature is above 550 ℃, carbides mainly precipitate in the grain and are coarse grained and the ferrite is equiaxed, the impact properties is high.
    MATERIALS RESEARCH
    Electron microscopy characterization for microstructure of Al-bearing high-boron high-speed steel
    Dong Yanchao, Ma Tiejun, Fu Hanguang, Jin Tounan, Yuan Naibo, Jin Tounan
    2022, 47(7):  177-182.  doi:10.13251/j.issn.0254-6051.2022.07.031
    Abstract ( 53 )   PDF (588KB) ( 28 )  
    Microstructure and boron carbide type of Al-bearing high-boron high-speed steel (BHSS) were analyzed by a combination of several microscopy characterization techniques including scanning electron microscopy (SEM), X-ray diffraction (XRD), energy dispersive spectroscopy (EDS), electron backscatter diffraction (EBSD) and transmission electron microscopy (TEM). The results show that the microstructure of as-cast Al-bearing high-boron high-speed steel is ferrite and network boron carbide, and the type of boron carbide includes Fe2B (Cr-rich), FeMo2B2 (Mo-rich) and Fe3C (Cr-Mo). After heat treatment, the matrix microstructure is martensite, and the network boron carbide is broken and spheroidized, and the type of boron carbide includes Fe2B (Cr-rich), (Fe, Cr)23C6 (Cr-Mo), and FeMo2B2 (Mo-rich). The rupture of network boron carbide after heat treatment is due to the decomposition of Fe3C (Cr-Mo) into (Fe, Cr)23C6 (Cr-Mo) and FeMo2B2(Mo-rich). The crystal structure of boron carbide obtained by TEM analysis is consistent with the conclusion of EBSD.
    Effect of cooling rate on martensitic transformation initiation temperature and hardness of super high strength martensitic steel
    Li Chunhui, Li Xiaoyuan, Yu Wenchao, Wang Maoqiu, Wu Run
    2022, 47(7):  183-189.  doi:10.13251/j.issn.0254-6051.2022.07.032
    Abstract ( 64 )   PDF (585KB) ( 34 )  
    Martensite transformation initiation temperature (Ms temperature) of martensitic steel with cooling rate of 20-70 ℃/s was measured by thermal expansion method, and its effect on hardness of the tested steel was studied. The results show that the increase of cooling rate enhances the strength of austenite, improves the thermal stability of austenite, and then decreases the initiation temperature of martensite transformation. At the same time, a higher cooling rate is more likely to cause lattice distortion, increase the dislocation density, increase the degree of undercooling and refine the effective grain size, which increases the hardness of the tested steel.
    Microstructure transformation characteristic of 4330M steel during continuous cooling process
    Shen Hui, Liu Yunpeng, Si Tingzhi
    2022, 47(7):  190-196.  doi:10.13251/j.issn.0254-6051.2022.07.033
    Abstract ( 46 )   PDF (593KB) ( 27 )  
    Continuous cooling transformation test of 4330 M steel was carried out by Gleeble-3500 thermal simulation test machine, and the microstructure transformation characteristic during continuous cooling process between cooling rate of 0.8-10 ℃/s was studied. The CCT curves of the steel were determined by means of thermal dilatometry method, hardness test and color metallography. The results show that the CCT curves of the 4330M steel contain ferrite, bainite and martensite transformation region, but there is no pearlite transformation region. With the increase of cooling rate, supercooled austenite is decomposed into ferrite+granular bainite, granular bainite+lower bainite+martensite and full martensite in turn. The critical cooling rate of martensite transformation is ascertained to be about 3 ℃/s. The orientation relationship of ferrite and cementite in lower bainite is (110)α∥(102)Fe3C and [111]α//[201]Fe3C. Combined the Vickers hardness test and quantitative analysis of color metallography, a hardness-volume fraction model is established to predict the hardness of 4330M steel as HBW=-0.07-4.69fF+4.02fGB+4.63fLB+4.82fM.
    Effect of rare earth Ce on CCT curves of H13 steel
    Xu Qihao, Yang Lilin, Xia Ming, Qin Chen, Zhao Liping
    2022, 47(7):  197-202.  doi:10.13251/j.issn.0254-6051.2022.07.034
    Abstract ( 77 )   PDF (582KB) ( 29 )  
    Effect of rare earth element Ce on continuous cooling transformation (CCT) curves of hot work die steel H13 was studied by measuring the CCT curves of the H13 steels without Ce and with 0.026%Ce. The results show that the addition of 0.026%Ce into the H13 steel can purify molten steel, improve microstructure, refine grains and eliminate undissolved carbides. Meanwhile, the addition of 0.026%Ce causes the transformation curve of pearlite and bainite to shift to the left, advances the pearlite phase transformation and bainite transformation, enlarges the transformation area of pearlite (A+P+C) and bainite (A+B+C), and reduces the transformation area of martensite (A+M+C) correspondingly. The hardness of the H13 steel increases with the addition of Ce, and also increases with the increase of cooling rate.
    Microstructure and mechanical properties of Fe-15Mn-8Al-0.25C low density steel based on FactSage
    Wang Yinghu
    2022, 47(7):  203-210.  doi:10.13251/j.issn.0254-6051.2022.07.035
    Abstract ( 62 )   PDF (643KB) ( 26 )  
    Solidification and cooling path, phase transformation and precipitates of Fe-(10-20)Mn-(5-10)Al-(0-0.5)C low density steel were simulated by FactSage software. The vertical sections of this system were calculated by using the FSstel database of FactSage software. Based on these vertical sections, the influence of Mn, Al and C on phase transformation and precipitates was analyzed during solidification and a diagram of the phase-transformation path of the Fe-15Mn-8Al-0.25C low density steel was obtained during equilibrium solidification. The results indicate that the equilibrium phases of the Fe-15Mn-8Al-0.25C steel calculated by thermodynamics include liquid, ferrite, austenite and κ-carbide. The full-phase transformation path of the Fe-15Mn-8Al-0.25C steel cooled from 1600 ℃ to 600 ℃ is as follows: liquid→liquid+ferrite→liquid+ferrite+austenite→ferrite+austenite→ferrite+austenite+κ-carbide. The increase of C and Mn content can expand the austenite phase zone of the Fe-15Mn-8Al-0.25C steel, and the increase of Al element can reduce the austenite phase zone. The precipitation temperature of κ-carbide increases with the increase of Al and C content, and Al and C can promote the precipitation of κ-carbide precipitation. The tensile strength of the Fe-15Mn-8Al-0.25C steel aged at 800 ℃ for 3 h is 602 MPa, the yield strength is 520 MPa, the elongation after fracture is 28.6%, the tensile strength aged at 800 ℃ for 5 h is 729 MPa, the yield strength is 685 MPa, and the elongation after fracture is 22.4%. With the increase of aging time, the strength of the tested steel increases and the elongation after fracture decreases. The density of the Fe-15Mn-8Al-0.25C steel is 6.99 g/cm3, which is 10.4% weight lighter than common steel.
    Helium ion irradiation damage behavior in a reduced activation steel
    Xia Lidong, Huo Xiaojie, Zhang Chi, Gao Dali, Wu Changjiang, Zhang Shijun
    2022, 47(7):  211-215.  doi:10.13251/j.issn.0254-6051.2022.07.036
    Abstract ( 63 )   PDF (638KB) ( 28 )  
    Irradiation damage behavior of a reduced activation steel was studied by carrying out helium ion irradiation at different temperatures, and the irradiation-induced defect microstructure and hardening effect were observed and analyzed by means of transmission electron microscope (TEM) and nanoindenter respectively. The results show that the defect microstructure induced by irradiation mainly includes bubbles and coarsening of M23C6 precipitate. Bubbles aggregate on grain boundaries, the bubble density increases with the increase of irradiation intensity, and the bubble size increases while the density decreases with the increase of irradiation temperature. The hardness of the reduced activation steel increases after irradiation, while the temperature rising weakens this effect. Irradiation hardening is related to size and density of defect microstructure, and the high density of small bubbles contributes mainly to hardening. As the irradiation temperature rises, the bubble density decreases sharply, which weakens irradiation hardening.
    Investigation on TiAl-V-Cr alloy sheet and its superplasticity
    Liu Hongwu, Gao Fan, Feng Xiangzheng, Li Zhenxi, Wang Qingfeng
    2022, 47(7):  216-220.  doi:10.13251/j.issn.0254-6051.2022.07.037
    Abstract ( 71 )   PDF (643KB) ( 28 )  
    TiAl alloys have low density, high modulus, flame retardancy and excellent elevated temperature performances, and have become a new generation of high-temperature structural material. The superplasticity of V and Cr alloyed TiAl alloy sheet was studied, and the microstructure was characterized by EBSD, SEM and TEM. The results show that the microstructure of the sheet is mainly composed of equiaxed γ grains, irregular B2 grains, and little massive α2 phases, with the average grain size of about 3.5 μm. When tensile deformed at 950 ℃/1×10-4 s-1, the alloy sheet exhibits excellent superplasticity, the elongation reaches 345%. By using this characteristic, typical test pieces of complex structure for aviation engine tail nozzle are manufactured successfully.
    SURFACE ENGINEERING
    Microstructure evolution and electrochemical properties of S30408 stainless steel treated by ultrasonic impact treatment
    Wang Zhenfei, Yang Xinjun
    2022, 47(7):  221-226.  doi:10.13251/j.issn.0254-6051.2022.07.038
    Abstract ( 65 )   PDF (641KB) ( 30 )  
    Gradient nanostructure was constructed on the surface of S30408 austenitic stainless steel by using ultrasonic impact treatment (UIT), and the effect of different ultrasonic impact time on surface nanostructure and corrosion resistance of the steel was studied by means of XRD, hardness test, optical microscope, scanning electron microscope and electrochemical test. The results show that after ultrasonic impact treatment, a certain depth of hardened layer is produced on the surface of the material, and the residual compressive stress is introduced. Moreover, both hardness and residual compressive stress increase with the increase of ultrasonic impact time, and reach the maximum 740.12 MPa and 82.22 HRB respectively when the ultrasonic impact time is 300 s. Gradient microstructure is observed on the surface of the steel after ultrasonic impact treatment, which can be divided into nanocrstalline layer, severe plastic deformation layer and matrix. The ultrasonic impact process refines the surface grains and induces martensite transformation, as the grain size is the smallest and the martensite transformation is the largest when the ultrasonic impact time is 300 s, which are 14.82 nm and 39.80%, respectively. The effect of ultrasonic impact treatment on corrosion resistance of the S30408 stainless steel is the result of the joint action of grain size, residual stress, martensitic transformation content, surface defects and so on. When the ultrasonic impact time is 180 s, the corrosion resistance of the specimen is the best, and the self-corrosion current density is 1.22 μA/cm2.
    Development of QPQ technology in China
    Luo Defu
    2022, 47(7):  227-233.  doi:10.13251/j.issn.0254-6051.2022.07.039
    Abstract ( 100 )   PDF (636KB) ( 51 )  
    In response to the call of the country to improve the green low-carbon circular development economic system, the development of QPQ technology in China was reviewed, and the current situation of China's QPQ technology in the direction of green and low-carbon was introduced. Futhermore, the development direction of green QPQ technology is prospected and some suggestions are put forward.
    Properties of rare earth modified Fe-based composite coating on Cr12MoV steel surface by laser cladding
    Dong Xiaochuan, Pan Gaofeng, Li Yang, Wu Runmou, Zhou Zheng, Zhang Xiaoyan
    2022, 47(7):  234-240.  doi:10.13251/j.issn.0254-6051.2022.07.040
    Abstract ( 70 )   PDF (638KB) ( 36 )  
    CMC PMagic2L coating was prepared on the Cr12MoV steel surface by laser cladding technology, and the modified Fe-base composite coating was formed by adding rare earth oxide CeO2. The effect of adding rare earth oxide CeO2 on microstructure and properties of the coating was studied by means of optical microscope, scanning electron microscope, microhardness tester and friction and wear testing machine. The results show that CeO2 can improve the grain refinement of clad layer and enlarge the width of heat affected zone. The hardness of clad layer increases with the increase of CeO2 content. Compared with the coating without CeO2, although the thickness of the heat affected zone increases, but the average hardness of the clad layer in modified Fe-based composite coating with 1%CeO2 increases by 22.1%, the wear resistance is also significantly improved, and the wear volume is reduced by 43.66%. The clad layer has compact structure, which can effectively achieve the purpose of surface strengthening of the die.
    Microstructure of Ti-Cu alloying layer on Ti6Al4V titanium alloy surface prepared by laser alloying
    Xie Yanxiang, Li Lin, Ye Fangxia, Fu Fuxing, Li Lei, He Binfeng, Liu Mingxia
    2022, 47(7):  241-244.  doi:10.13251/j.issn.0254-6051.2022.07.041
    Abstract ( 44 )   PDF (641KB) ( 27 )  
    A continuous and compact Ti-Cu alloying layer with thickness of about 120 μm was prepared on Ti6Al4V alloy surface by laser alloying. The element distribution and microstructure of the Ti-Cu alloying layer were analyzed. The results show that the distribution of Cu element in the Ti-Cu alloying layer is gradient with the depth. Microstructure near the surface of the Ti-Cu alloying layer is mainly composed of columnar crystals with a small amount of block crystals, the upper middle region is mainly composed of undeveloped dendritic crystals and some cellular crystals with different growth orientations, the lower middle region is mainly cellular crystals with different growth orientations, and the interface between the layer and the substrate is mainly composed of fine planar crystals. The Cu and Ti elements in the Ti-Cu alloying layer not only form solid solutions, but also form intermetallic compounds Ti2Cu, Ti3Cu, Cu3Al4, and metal-ceramic Cu3TiO4, Al2TiO5.
    Microstructure and high temperature oxidation resistance of Cr-coated Zr-4 alloy prepared by magnetron sputtering and multi-arc ion plating
    Zou Yang, Liu Shihong
    2022, 47(7):  245-252.  doi:10.13251/j.issn.0254-6051.2022.07.042
    Abstract ( 74 )   PDF (640KB) ( 33 )  
    In order to compare the microstructure and high temperature oxidation resistance of Cr-coated Zr-4 alloy prepared by magnetron sputtering and multi-arc ion plating, Cr-coated Zr-4 alloy were prepared by DC magnetron sputtering and multi-arc ion plating, respectively. And the high temperature oxidation resistance was studied in air atmosphere. The results show that the Cr-coated Zr-4 alloy specimen prepared by magnetron sputtering has smooth surface, and the Cr coating grows preferentially along the (211) crystal plane, while there are a lot of droplets on the surface of the Cr-coated Zr-4 alloy specimen prepared by multi-arc ion plating, and the Cr coating grows preferentially along the (110) crystal plane. The results of high-temperature oxidation experiments show that the oxidation mass gain of the Cr-coated Zr-4 alloy specimen prepared by magnetron sputtering is about half of that of the multi-arc ion plating. The oxidized microstructure shows that the specimen prepared by magnetron sputtering still has a residual Cr coating with a thickness of about 4 μm, and the O atoms only diffuse to a distance of about 8 μm from the surface, while the Cr coating of the specimen prepared by multi-arc ion plating was completely oxidized, and a large number of O atoms diffused into the Zr-4 alloy matrix at a depth of about 1 mm from the surface of the specimen. Therefore, the Cr-coated Zr-4 alloy prepared by magnetron sputtering has better high temperature oxidation resistance.
    Effect of plasma nitriding on microstructure and high temperature wear resistance of 304L stainless steel
    Cao Zhen, Li Ji, Luo Ping, Li Jiahui, Li Jiongli, Wang Xudong
    2022, 47(7):  253-258.  doi:10.13251/j.issn.0254-6051.2022.07.043
    Abstract ( 62 )   PDF (637KB) ( 29 )  
    An experimental study on plasma nitriding with different temperatures was carried out on the 304L stainless steel thermowell for incinerator as the research object. Microstructure and properties of the 304L stainless steel thermowell before and after plasma nitriding were analyzed by OM, SEM, microhardness tester and the wear resistance at 400 ℃ was studied. The results show that surface hardened layer over 1300 HV is formed after plasma nitriding of the 304L stainless steel. With the increase of nitriding temperature, the surface hardness is improved and the thickness of hardened layer is increased significantly. The wear and high temperature oxidation resistance of the 304L stainless steel are improved by plasma nitriding.
    Salt bath vanadium-nitrocarburizing process of AZ31B magnesium alloy
    Zhou Liuyan, Liu Liguo, Ma Hui, Chen Dongxu
    2022, 47(7):  259-263.  doi:10.13251/j.issn.0254-6051.2022.07.044
    Abstract ( 59 )   PDF (638KB) ( 27 )  
    In order to improve the surface hardness, friction and wear properties and corrosion resistance of AZ31B magnesium alloy, a high hardness carbonitriding layer was prepared on the AZ31B magnesium alloy surface by salt bath vanadium-nitrocarburizing process. The surface microhardness, cross-section morphology, phase composition of the nitrocarburizing layer, and the wear resistance and corrosion resistance were analyzed by means of digital microhardness tester, optical microscope, X-ray diffractometer, X-ray energy spectrometer, friction and wear test and electrochemical test. The results show that a layer mainly composed of high hardness metal compounds such as VC and VN is formed on the AZ31B magnesium alloy surface after salt bath vanadium-nitrocarburizing treatment. The maximum surface hardness of the vanadium-nitrocarburizing layer is up to 283.1 HV0.05, which is increased by 280% and 62% respectively compared with that of the untreated and the carbonitriding treated. Comparing with the untreated alloy, the friction coefficient and wear mass loss of the alloy after vanadium-nitrocarburizing are reduced by about 30% and 50% respectively, the self-corrosion potential is increased by 60 mV and the self-corrosion current density is reduced by an order of magnitude, which showing that the salt bath vanadium-nitrocarburizing process can significantly improve the surface hardness, friction and wear properties and corrosion resistance of AZ31B magnesium alloy.
    Composite process of shot peening and plasma multi-elements cycle penetrating of 40Cr steel for drill guide rail
    Zhou Fujia, Liu Xiaohua
    2022, 47(7):  264-268.  doi:10.13251/j.issn.0254-6051.2022.07.045
    Abstract ( 46 )   PDF (643KB) ( 25 )  
    Taking 40Cr alloy steel commonly used for guide rail of drilling rig as the research object, the strengthening mechanism of shot peening and plasma multi-elements cycle penetrating was investigated. The results show that the surface hardness of the specimen treated by the composite process is 912 HV0.2, and the infiltrated layer depth is 315 μm. It is superior to single process of plasma multi-elements cycle penetrating. Shot peening can increase the diffusion coefficient by increasing the diffusion channel and decreasing the diffusion energy. Cyclic nitriding makes the concentration gradient between the surface and the diffusion layer change periodically, which provides a driving force for the phase interface reaction and internal diffusion. The results show that the combination of shot peening and plasma multi-elements cycle penetrating has a synergistic effect, which can effectively improve the surface properties of drill guide rail.
    Microstructure evolution after carburizing and quenching of 16MnCr5 steel high power diesel engine camshaft
    Fang Guoliang, Wang Maolin
    2022, 47(7):  269-271.  doi:10.13251/j.issn.0254-6051.2022.07.046
    Abstract ( 84 )   PDF (637KB) ( 28 )  
    Microstructure and hardness along the radial direction of the 16MnCr5 low carbon alloy steel camshaft after carburizing and quenching and low temperature tempering process were studied by means of OM, SEM, XRD and hardness test. The results show that the 940 ℃ carburazing period is suitable for 16MnCr5 steel. Microstructure of the camshaft changes significantly along the radial direction, as the surface structure is high-carbon acicular martensite and 10% retained austenite with hardness reaching 750 HV and effective hardened layer depth of above 1.5 mm, and the matrix structure is a mixed structure of bainite and low carbon martensite.
    PIP treatment modification of diaphragm compressor
    Long Liwei, Du Guixiang, Liao Yunting, Jin Yingrong, Luo Defu
    2022, 47(7):  272-276.  doi:10.13251/j.issn.0254-6051.2022.07.047
    Abstract ( 52 )   PDF (641KB) ( 34 )  
    With the programmable ion permeation(PIP) treatment technology and according to the specific situation of fatigue cracking caused by tensile stress on the diaphragm surface, a compound permeation layer with nitrogen supersaturated solid solution was prepared. The results show that a infiltrated layer with hardness of over 1000 HV0.1, compressive stress higher than 280 MPa and depth is about 16 μm on the surface of the 316L stainless steel diaphragm after PIP treatment. It ensures that no surface tensile stress present in the working process of the diaphragm, so that the working life of the diaphragm is prolonged.
    TEST AND ANALYSIS
    Failure analysis on piston connecting rod mechanism of diesel engine
    Jiao Li, Shang Haikun, He Jianfeng, Wang Guoliang, Feng Tao, Wang Jia, Hu Yutao
    2022, 47(7):  277-282.  doi:10.13251/j.issn.0254-6051.2022.07.048
    Abstract ( 68 )   PDF (638KB) ( 38 )  
    A malfunction of piston connecting rod mechanism of diesel engine occurred during use. After dismantling, various degrees of fractures were found that on the cylinder, piston and connecting rod. The comprehensive analysis was carried out by means of macro and micro examination of the fracture, chemical composition and microstructure analysis in combination with the production process. The results show that the connecting rod was the failure maker, and the cylinder and piston belong to secondary fracture in this cascading failure. The folding defects on the surface of the connecting rod caused by improper shot peening process, which induces the initial fatigue damage because of the stress concentration. Meanwhile the undesirable microstructure weakens the strength of the connecting rod in a certain degree. The connecting rod high cycle fatigue fracture and the cylinder and piston damage one by one under the action of cyclic stress and the inertia force.
    Distortion control of carburizing quenching for new energy vehicle motor shaft bar groove
    Ouyang Zhifang, Chen Junjian, Hu Weifang
    2022, 47(7):  283-285.  doi:10.13251/j.issn.0254-6051.2022.07.049
    Abstract ( 73 )   PDF (639KB) ( 30 )  
    Distortion of the shaft bar groove of a new energy vehicle motor during heat treatment could not meet the dimensional accuracy requirements. By reducing the carburizing potential, increasing the quenching oil temperature, optimizing the quenching process and anti-distortion processing with a 20 μm conicity, the distortion of the motor shaft bar groove is successfully controlled within the range of dimensional accuracy requirements, and the distortion is not significant increase in small batch production, which indicates that the improved process can be applied to batch production.
    Fracture cause analysis of QBe2 beryllium bronze connector
    Wei Caili, Zhang Shenjie, Du Gangfeng
    2022, 47(7):  286-288.  doi:10.13251/j.issn.0254-6051.2022.07.050
    Abstract ( 69 )   PDF (642KB) ( 47 )  
    A batch of connector made of QBe2 fractured in the course of service was fratured. Reason for fracture was analyzed by the methods such as microscopic morphology observation, chemical composition analysis, microstructure observation and hardness test; and contral mensuren was proposed. The results show that overheating of the connector caused in thermocouples fail lead to coarse grain in solution and aging treatment. The strength of the grain boundary becomes lower than the matrix, and lead to the fracture of connector when it is subjected to external force. Therefore, it is recommended to regularly monitor and maintain the thermocouple to ensure the normal operation of the equipment.